Literature DB >> 21814698

The Th=C double bond: an experimental and computational study of thorium poly-carbene complexes.

Wenshan Ren1, Xuebin Deng, Guofu Zi, De-Cai Fang.   

Abstract

The first thorium poly-carbene complexes [(Ph(2)P=S)(2)C](2)Th(DME) (2) and [{[(Ph(2)P=S)(2)C](3)Th}Li(2)(DME)](n) (3) have been prepared and structurally characterized. DFT calculations reveal that the Th=C bond is polarized toward the nucleophilic carbene carbon atom, which is further verified by the experimental observation that the Th=C bond shows a nucleophilic behavior with Ph(2)CO.

Entities:  

Year:  2011        PMID： 21814698     DOI： 10.1039/c1dt11149c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  10 in total

1.  A terminal neptunium(V)-mono(oxo) complex.

Authors:  Michał S Dutkiewicz; Conrad A P Goodwin; Mauro Perfetti; Andrew J Gaunt; Jean-Christophe Griveau; Eric Colineau; Attila Kovács; Ashley J Wooles; Roberto Caciuffo; Olaf Walter; Stephen T Liddle
Journal:  Nat Chem       Date:  2022-02-10       Impact factor: 24.427

2.  Uranium versus Thorium: Synthesis and Reactivity of [η5 -1,2,4-(Me3 C)3 C5 H2 ]2 U[η2 -C2 Ph2 ].

Authors:  Deqiang Wang; Wanjian Ding; Guohua Hou; Guofu Zi; Marc D Walter
Journal:  Chemistry       Date:  2021-03-16       Impact factor: 5.236

3.  Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2017-03-09       Impact factor: 14.919

4.  Emergence of the structure-directing role of f-orbital overlap-driven covalency.

Authors:  Erli Lu; Saira Sajjad; Victoria E J Berryman; Ashley J Wooles; Nikolas Kaltsoyannis; Stephen T Liddle
Journal:  Nat Commun       Date:  2019-02-07       Impact factor: 14.919

5.  Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides.

Authors:  Jingzhen Du; Carlos Alvarez-Lamsfus; Elizabeth P Wildman; Ashley J Wooles; Laurent Maron; Stephen T Liddle
Journal:  Nat Commun       Date:  2019-09-13       Impact factor: 14.919

6.  Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV).

Authors:  John A Seed; Lisa Vondung; Ralph W Adams; Ashley J Wooles; Erli Lu; Stephen T Liddle
Journal:  Organometallics       Date:  2022-05-18       Impact factor: 3.837

7.  (2,2'-Bipyridine-κ(2) N,N')[bis-(diphenyl-thio-phosphino-yl)meth-yl]lithium(I) benzene monosolvate.

Authors:  Wenshan Ren; Suchada Chantrapromma; Hoong-Kun Fun
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-02-20

8.  Thorium-phosphorus triamidoamine complexes containing Th-P single- and multiple-bond interactions.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2016-09-29       Impact factor: 14.919

9.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group.

Authors:  Danil E Smiles; Guang Wu; Nikolas Kaltsoyannis; Trevor W Hayton
Journal:  Chem Sci       Date:  2015-04-30       Impact factor: 9.825

10.  Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis.

Authors:  Adrien T Normand; E Daiann Sosa Carrizo; Corentin Magnoux; Esteban Lobato; Hélène Cattey; Philippe Richard; Stéphane Brandès; Charles H Devillers; Anthony Romieu; Pierre Le Gendre; Paul Fleurat-Lessard
Journal:  Chem Sci       Date:  2020-10-26       Impact factor: 9.825
  10 in total

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