| Literature DB >> 21809891 |
Daishi Fujita1, Asana Takahashi, Sota Sato, Makoto Fujita.
Abstract
Thermodynamically controlled platinum(II) spherical complexes were synthesized via temporary labilization of inert Pt(II)-pyridine bonds by the addition of the strong hydrogen-bond donor 2,2,2-trifluoroethanol (TFE), which weakens the pyridine-metal interaction. The platinum complex was stably trapped after removal of TFE and showed higher acid durability than its palladium counterpart.Entities:
Year: 2011 PMID: 21809891 DOI: 10.1021/ja2059236
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419