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Literature DB >> 21750826

Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ).

Christian Wäckerlin¹, Cristian Iacovita, Dorota Chylarecka, Petra Fesser, Thomas A Jung, Nirmalya Ballav.

Abstract

Sublimation of alkali halides (NaCl and LiCl) onto a pre-assembled hydrogen-bonded layer of TCNQ on Au(111) resulted in the formation of 2D ionic layers via a direct charge-transfer reaction without involvement of the substrate. The presented approach allows for the fabrication of different ionic layers, decoupled from the substrate and offering new, potentially interesting properties.

Entities: Chemical

Year: 2011 PMID： 21750826 DOI： 10.1039/c1cc12519b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

8 in total

1. Synthesis and characterization of redox-active charge-transfer complexes with 2,3,5,6-tetracyanopyridine (TCNPy) for the photogeneration of pyridinium radicals.

Authors: Eva Wöss; Uwe Monkowius; Günther Knör
Journal: Chemistry Date: 2012-12-11 Impact factor: 5.236

2. A Comparative Computational Study of the Adsorption of TCNQ and F4-TCNQ on the Coinage Metal Surfaces.

Authors: Roberto Otero; Rodolfo Miranda; José M Gallego
Journal: ACS Omega Date: 2019-10-04

3. Achieving current rectification ratios ≥ 10⁵ across thin films of coordination polymer.

Authors: Anupam Prasoon; Barun Dhara; Debashree Roy; Shammi Rana; Sujit Bhand; Nirmalya Ballav
Journal: Chem Sci Date: 2019-09-05 Impact factor: 9.825

4. Thermodynamic Driving Forces for Substrate Atom Extraction by Adsorption of Strong Electron Acceptor Molecules.

Authors: Paul Ryan; Philip James Blowey; Billal S Sohail; Luke A Rochford; David A Duncan; Tien-Lin Lee; Peter Starrs; Giovanni Costantini; Reinhard J Maurer; David Phillip Woodruff
Journal: J Phys Chem C Nanomater Interfaces Date: 2022-03-28 Impact factor: 4.126

5. Exploiting Cooperative Catalysis for the On-Surface Synthesis of Linear Heteroaromatic Polymers via Selective C-H Activation.

Authors: Xunshan Liu; Adam Matej; Tim Kratky; Jesús I Mendieta-Moreno; Sebastian Günther; Pingo Mutombo; Silvio Decurtins; Ulrich Aschauer; Jascha Repp; Pavel Jelinek; Shi-Xia Liu; Laerte L Patera
Journal: Angew Chem Int Ed Engl Date: 2021-12-14 Impact factor: 16.823

Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ).

1. Synthesis and characterization of redox-active charge-transfer complexes with 2,3,5,6-tetracyanopyridine (TCNPy) for the photogeneration of pyridinium radicals.

2. A Comparative Computational Study of the Adsorption of TCNQ and F4-TCNQ on the Coinage Metal Surfaces.

3. Achieving current rectification ratios ≥ 10⁵ across thin films of coordination polymer.

4. Thermodynamic Driving Forces for Substrate Atom Extraction by Adsorption of Strong Electron Acceptor Molecules.

5. Exploiting Cooperative Catalysis for the On-Surface Synthesis of Linear Heteroaromatic Polymers via Selective C-H Activation.

6. Fine-tuning of two-dimensional metal-organic nanostructures via alkali-pyridyl coordination.

7. Two-Dimensional Ketone-Driven Metal-Organic Coordination on Cu(111).

8. Re-evaluating how charge transfer modifies the conformation of adsorbed molecules.