Literature DB >> 21701727

An organocatalytic ionic liquid.

Zsolt Kelemen1, Oldamur Hollóczki, József Nagy, László Nyulászi.   

Abstract

The carbene concentration in 1-ethyl-3-methylimidazolium-acetate ionic liquid is sufficiently high to act as a catalyst in benzoin condensation, hydroacylation and also in oxidation of an alcohol by using CO(2) and air. This observation reveals the potential of ionic liquid organocatalysts, uniting the beneficial properties of these two families of compounds.

Entities:  

Year:  2011        PMID: 21701727     DOI: 10.1039/c1ob05639e

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  8 in total

1.  Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators.

Authors:  Henrik Sundén; Linda Ta; Anton Axelsson
Journal:  J Vis Exp       Date:  2015-11-27       Impact factor: 1.355

Review 2.  Fast Track to Acetate-Based Ionic Liquids: Preparation, Properties and Application in Energy and Petrochemical Fields.

Authors:  Jing Ma; Yutong Wang; Xueqing Yang; Baohe Wang
Journal:  Top Curr Chem (Cham)       Date:  2021-01-05

3.  1-Ethyl-3-methylimidazolium acetate as a highly efficient organocatalyst for cyanosilylation of carbonyl compounds with trimethylsilyl cyanide.

Authors:  Bakhtar Ullah; Jingwen Chen; Zhiguo Zhang; Huabin Xing; Qiwei Yang; Zongbi Bao; Qilong Ren
Journal:  Sci Rep       Date:  2017-02-15       Impact factor: 4.379

Review 4.  Ionic liquids: a brief history.

Authors:  Tom Welton
Journal:  Biophys Rev       Date:  2018-04-26

Review 5.  Ionic liquids--promising but challenging solvents for homogeneous derivatization of cellulose.

Authors:  Martin Gericke; Pedro Fardim; Thomas Heinze
Journal:  Molecules       Date:  2012-06-15       Impact factor: 4.411

Review 6.  NHC in Imidazolium Acetate Ionic Liquids: Actual or Potential Presence?

Authors:  Isabella Chiarotto; Leonardo Mattiello; Fabiana Pandolfi; Daniele Rocco; Marta Feroci
Journal:  Front Chem       Date:  2018-08-28       Impact factor: 5.221

7.  Predictive energetic tuning of C-Nucleophiles for the electrochemical capture of carbon dioxide.

Authors:  Haley A Petersen; Abdulaziz W Alherz; Taylor A Stinson; Chloe G Huntzinger; Charles B Musgrave; Oana R Luca
Journal:  iScience       Date:  2022-03-03

8.  Significant cation effects in carbon dioxide-ionic liquid systems.

Authors:  Oldamur Hollóczki; Zsolt Kelemen; László Könczöl; Dénes Szieberth; László Nyulászi; Annegret Stark; Barbara Kirchner
Journal:  Chemphyschem       Date:  2013-01-02       Impact factor: 3.102

  8 in total

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