Literature DB >> 21667943

Concise total synthesis and stereochemical revision of all (-)-trigonoliimines.

Sunkyu Han1, Mohammad Movassaghi.   

Abstract

The concise and enantioselective total syntheses of (-)-trigonoliimines A, B, and C are described. Our unified strategy to all three natural products is based on asymmetric oxidation and reorganization of a single bistryptamine, a sequence of transformations with possible biogenetic relevance. We revise the absolute stereochemistry of (-)-trigonoliimines A, B, and C.

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Year:  2011        PMID： 21667943      PMCID： PMC3385510          DOI： 10.1021/ja204597k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  22 in total

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