| Literature DB >> 21595479 |
Mariham Y Abraham1, Yuzhong Wang, Yaoming Xie, Pingrong Wei, Henry F Schaefer, Paul v R Schleyer, Gregory H Robinson.
Abstract
Reaction of carbene-stabilized disilicon L:Si═Si:L (L: = :C{N(2,6-Pr(i)(2)C(6)H(3))CH}(2), 1) with BH(3)·THF results in facile cleavage of the silicon-silicon double bond and the formation of two quite different "push-pull" stabilized products with borane- and carbene-coordinated silylene moieties: 2, containing a parent silylene (:SiH(2)); and 3, containing a unique three-membered cyclosilylene.Entities:
Year: 2011 PMID： 21595479 DOI： 10.1021/ja203208t
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419