trans-Carbonyl-chloridobis[tris-(4-chloro-phen-yl)phosphane]rhodium(I) acetone monosolvate.

The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solvent mol-ecule and the Cl-Rh unit results in a reduced P-Rh-Cl angle of 86.675 (15)°.

Related literature

For a review of rhodium Vaska {trans-[RhCl(CO)(PR 3)2]} compounds, see: Roodt et al. (2003 ▶). For related compounds, see: Angoletta (1959 ▶); Vaska & Di Luzio (1961 ▶); Chen et al. (1991 ▶); Kuwabara & Bau (1994 ▶); Otto et al. (2000 ▶); Otto (2001 ▶); Meijboom et al. (2005 ▶).

Experimental

Crystal data

[RhCl(C18H12Cl3P)2(CO)]·C3H6O

M = 955.64

Triclinic,

a = 10.6130 (7) Å

b = 12.7970 (8) Å

c = 16.7470 (11) Å

α = 71.631 (1)°

β = 81.742 (1)°

γ = 68.537 (1)°

V = 2007.9 (2) Å3

Z = 2

Mo Kα radiation

μ = 1.01 mm−1

T = 100 K

0.37 × 0.17 × 0.07 mm

Data collection

Bruker X8 APEXII 4K KappaCCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2007 ▶) T min = 0.707, T max = 0.933

25954 measured reflections

10031 independent reflections

9160 reflections with I > 2σ(I)

R int = 0.023

Refinement

R[F 2 > 2σ(F 2)] = 0.026

wR(F 2) = 0.069

S = 1.04

10031 reflections

471 parameters

4 restraints

H-atom parameters constrained

Δρmax = 1.17 e Å−3

Δρmin = −0.69 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT-Plus (Bruker, 2007 ▶); data reduction: SAINT-Plus and XPREP (Bruker, 2007 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg & Putz, 2005 ▶) and ORTEP-3 (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810039814/si2294sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810039814/si2294Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[RhCl(C18H12Cl3P)2(CO)]·C3H6O	Z = 2
Mr = 955.64	F(000) = 960
Triclinic, P1	Dx = 1.581 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.6130 (7) Å	Cell parameters from 25954 reflections
b = 12.7970 (8) Å	θ = 1.8–28.4°
c = 16.7470 (11) Å	µ = 1.01 mm−1
α = 71.631 (1)°	T = 100 K
β = 81.742 (1)°	Block, yellow
γ = 68.537 (1)°	0.37 × 0.17 × 0.07 mm
V = 2007.9 (2) Å3

Bruker X8 APEXII 4K KappaCCD diffractometer	9160 reflections with I > 2σ(I)
graphite	Rint = 0.023
φ and ω scans	θmax = 28.4°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Bruker, 2007)	h = −14→12
Tmin = 0.707, Tmax = 0.933	k = −16→17
25954 measured reflections	l = −21→22
10031 independent reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.026	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.069	H-atom parameters constrained
S = 1.04	w = 1/[σ2(Fo2) + (0.0302P)2 + 1.7506P] where P = (Fo2 + 2Fc2)/3
10031 reflections	(Δ/σ)max = 0.009
471 parameters	Δρmax = 1.17 e Å−3
4 restraints	Δρmin = −0.69 e Å−3

Experimental. The intensity data was collected on a Bruker X8 Apex II CCD diffractometer using an exposure time of 10 s/frame. A total of 1895 frames were collected with a frame width of 0.5° covering up to θ = 28.38° with 99.9% completeness accomplished.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.45279 (16)	0.41780 (13)	0.86206 (10)	0.0164 (3)
C2	0.41530 (18)	0.37176 (15)	0.94513 (11)	0.0210 (3)
H2	0.4811	0.3368	0.9874	0.025*
C3	0.28161 (19)	0.37668 (16)	0.96678 (12)	0.0245 (4)
H3	0.2559	0.3451	1.0234	0.029*
C4	0.18729 (17)	0.42829 (16)	0.90434 (12)	0.0232 (3)
C5	0.22084 (18)	0.47737 (16)	0.82210 (12)	0.0245 (4)
H5	0.1539	0.5149	0.7805	0.029*
C6	0.35413 (18)	0.47109 (15)	0.80104 (11)	0.0214 (3)
H6	0.3787	0.5035	0.7443	0.026*
C7	0.74075 (16)	0.32026 (14)	0.90731 (10)	0.0171 (3)
C8	0.73223 (17)	0.35235 (15)	0.98114 (11)	0.0198 (3)
H8	0.6603	0.4195	0.9892	0.024*
C9	0.82786 (18)	0.28702 (17)	1.04254 (11)	0.0245 (4)
H9	0.8209	0.3078	1.0931	0.029*
C10	0.93422 (19)	0.19046 (17)	1.02877 (12)	0.0261 (4)
C11	0.94494 (18)	0.15729 (15)	0.95637 (12)	0.0249 (4)
H11	1.0181	0.091	0.9481	0.03*
C12	0.84757 (17)	0.22195 (15)	0.89602 (11)	0.0212 (3)
H12	0.8536	0.1991	0.8464	0.025*
C13	0.62608 (16)	0.55598 (13)	0.81044 (10)	0.0161 (3)
C14	0.51081 (17)	0.64893 (15)	0.82071 (11)	0.0205 (3)
H14	0.4265	0.6367	0.8359	0.025*
C15	0.51770 (19)	0.75957 (15)	0.80891 (12)	0.0244 (4)
H15	0.4384	0.823	0.8147	0.029*
C16	0.6411 (2)	0.77582 (15)	0.78876 (11)	0.0232 (3)
C17	0.7573 (2)	0.68537 (16)	0.77805 (13)	0.0263 (4)
H17	0.8416	0.698	0.7638	0.032*
C18	0.74917 (18)	0.57584 (15)	0.78836 (12)	0.0230 (3)
H18	0.8283	0.5137	0.7803	0.028*
C19	0.86583 (16)	0.11855 (14)	0.62309 (10)	0.0173 (3)
C20	0.96226 (18)	0.10485 (16)	0.67746 (11)	0.0232 (3)
H20	0.9571	0.1691	0.6962	0.028*
C21	1.06604 (19)	−0.00186 (17)	0.70460 (12)	0.0276 (4)
H21	1.133	−0.0108	0.7406	0.033*
C22	1.06923 (19)	−0.09470 (16)	0.67782 (11)	0.0256 (4)
C23	0.9774 (2)	−0.08305 (16)	0.62225 (12)	0.0266 (4)
H23	0.9838	−0.1473	0.6031	0.032*
C24	0.87527 (19)	0.02477 (15)	0.59474 (12)	0.0236 (3)
H24	0.8115	0.0343	0.5563	0.028*
C25	0.59960 (17)	0.22421 (14)	0.55503 (11)	0.0196 (3)
C26	0.49901 (18)	0.19286 (16)	0.60992 (12)	0.0242 (4)
H26	0.4953	0.192	0.6671	0.029*
C27	0.4036 (2)	0.16278 (17)	0.58096 (14)	0.0302 (4)
H27	0.335	0.1412	0.6181	0.036*
C28	0.4105 (2)	0.16491 (16)	0.49772 (14)	0.0304 (4)
C29	0.5097 (2)	0.19354 (18)	0.44249 (13)	0.0312 (4)
H29	0.5133	0.1929	0.3856	0.037*
C30	0.60475 (19)	0.22352 (17)	0.47133 (12)	0.0259 (4)
H30	0.6738	0.2437	0.4338	0.031*
C31	0.79052 (17)	0.34837 (14)	0.50272 (10)	0.0183 (3)
C32	0.69971 (18)	0.44776 (16)	0.45032 (11)	0.0223 (3)
H32	0.6058	0.4585	0.4557	0.027*
C33	0.74499 (19)	0.53101 (16)	0.39047 (11)	0.0248 (4)
H33	0.6828	0.5983	0.3551	0.03*
C34	0.8822 (2)	0.51408 (16)	0.38325 (11)	0.0246 (4)
C35	0.97511 (19)	0.41477 (17)	0.43215 (12)	0.0261 (4)
H35	1.0692	0.4032	0.425	0.031*
C36	0.92848 (18)	0.33212 (15)	0.49190 (11)	0.0220 (3)
H36	0.9915	0.2637	0.5258	0.026*
C37	0.69720 (17)	0.47391 (12)	0.63949 (10)	0.0180 (3)
P1	0.62373 (4)	0.40975 (3)	0.82264 (3)	0.01420 (8)
P2	0.72683 (4)	0.25790 (4)	0.59485 (3)	0.01550 (8)
Cl1	0.63216 (5)	0.17010 (4)	0.79542 (3)	0.02401 (9)
Cl2	1.06102 (5)	0.11330 (5)	1.10165 (3)	0.04090 (13)
Cl3	0.65127 (5)	0.91247 (4)	0.77695 (3)	0.03312 (11)
Cl4	1.18984 (6)	−0.23221 (5)	0.71789 (3)	0.03995 (13)
Cl5	0.28900 (6)	0.13135 (5)	0.46052 (4)	0.04566 (15)
Cl6	0.93897 (6)	0.62136 (4)	0.31201 (3)	0.03453 (11)
Cl7	0.02340 (5)	0.42625 (5)	0.92807 (4)	0.03486 (11)
Rh1	0.668804 (12)	0.340979 (10)	0.705687 (7)	0.01450 (4)
O1	0.71508 (14)	0.55764 (11)	0.59840 (8)	0.0272 (3)
C38	0.3033 (2)	0.03136 (18)	0.88771 (14)	0.0311 (4)
C39	0.3764 (3)	−0.0610 (2)	0.96104 (18)	0.0542 (7)
H39A	0.3645	−0.1349	0.9651	0.081*
H39B	0.34	−0.038	1.0126	0.081*
H39C	0.473	−0.071	0.9539	0.081*
C40	0.2919 (3)	0.1538 (2)	0.87945 (19)	0.0463 (6)
H40A	0.2352	0.2075	0.8318	0.07*
H40B	0.3823	0.1605	0.8699	0.07*
H40C	0.2506	0.174	0.9312	0.07*
O2	0.2549 (2)	0.0074 (2)	0.83829 (16)	0.0709 (7)

	U11	U22	U33	U12	U13	U23
C1	0.0168 (7)	0.0131 (7)	0.0212 (8)	−0.0044 (6)	−0.0005 (6)	−0.0083 (6)
C2	0.0219 (8)	0.0212 (8)	0.0215 (8)	−0.0077 (6)	−0.0018 (6)	−0.0073 (6)
C3	0.0255 (9)	0.0272 (9)	0.0248 (9)	−0.0129 (7)	0.0046 (7)	−0.0105 (7)
C4	0.0173 (8)	0.0227 (8)	0.0354 (10)	−0.0090 (6)	0.0045 (7)	−0.0159 (7)
C5	0.0202 (8)	0.0237 (8)	0.0309 (9)	−0.0053 (7)	−0.0050 (7)	−0.0104 (7)
C6	0.0213 (8)	0.0206 (8)	0.0222 (8)	−0.0066 (6)	−0.0021 (6)	−0.0058 (6)
C7	0.0165 (7)	0.0148 (7)	0.0194 (7)	−0.0044 (6)	−0.0028 (6)	−0.0044 (6)
C8	0.0182 (8)	0.0202 (8)	0.0219 (8)	−0.0061 (6)	−0.0002 (6)	−0.0079 (6)
C9	0.0226 (8)	0.0317 (9)	0.0203 (8)	−0.0103 (7)	−0.0015 (7)	−0.0070 (7)
C10	0.0211 (8)	0.0276 (9)	0.0237 (9)	−0.0070 (7)	−0.0065 (7)	0.0019 (7)
C11	0.0205 (8)	0.0184 (8)	0.0292 (9)	−0.0015 (6)	−0.0027 (7)	−0.0031 (7)
C12	0.0206 (8)	0.0173 (8)	0.0245 (8)	−0.0042 (6)	−0.0014 (6)	−0.0069 (6)
C13	0.0200 (8)	0.0129 (7)	0.0169 (7)	−0.0055 (6)	−0.0023 (6)	−0.0056 (6)
C14	0.0195 (8)	0.0169 (8)	0.0260 (8)	−0.0048 (6)	−0.0023 (6)	−0.0083 (6)
C15	0.0260 (9)	0.0147 (8)	0.0318 (9)	−0.0019 (6)	−0.0047 (7)	−0.0100 (7)
C16	0.0351 (10)	0.0133 (7)	0.0237 (8)	−0.0102 (7)	−0.0065 (7)	−0.0042 (6)
C17	0.0264 (9)	0.0222 (8)	0.0346 (10)	−0.0128 (7)	−0.0008 (7)	−0.0087 (7)
C18	0.0203 (8)	0.0176 (8)	0.0326 (9)	−0.0061 (6)	0.0000 (7)	−0.0099 (7)
C19	0.0166 (7)	0.0168 (7)	0.0177 (7)	−0.0042 (6)	−0.0005 (6)	−0.0058 (6)
C20	0.0241 (9)	0.0229 (8)	0.0233 (8)	−0.0051 (7)	−0.0047 (7)	−0.0093 (7)
C21	0.0220 (9)	0.0317 (10)	0.0247 (9)	−0.0018 (7)	−0.0065 (7)	−0.0083 (7)
C22	0.0230 (9)	0.0217 (8)	0.0202 (8)	0.0029 (7)	−0.0002 (7)	−0.0029 (7)
C23	0.0302 (10)	0.0183 (8)	0.0298 (9)	−0.0023 (7)	−0.0027 (7)	−0.0112 (7)
C24	0.0248 (9)	0.0198 (8)	0.0272 (9)	−0.0039 (7)	−0.0068 (7)	−0.0098 (7)
C25	0.0176 (8)	0.0165 (7)	0.0251 (8)	−0.0024 (6)	−0.0053 (6)	−0.0085 (6)
C26	0.0218 (8)	0.0206 (8)	0.0311 (9)	−0.0062 (7)	−0.0041 (7)	−0.0084 (7)
C27	0.0218 (9)	0.0230 (9)	0.0469 (12)	−0.0078 (7)	−0.0057 (8)	−0.0093 (8)
C28	0.0251 (9)	0.0180 (8)	0.0511 (12)	−0.0031 (7)	−0.0179 (8)	−0.0118 (8)
C29	0.0332 (10)	0.0286 (10)	0.0345 (10)	−0.0045 (8)	−0.0150 (8)	−0.0138 (8)
C30	0.0242 (9)	0.0276 (9)	0.0281 (9)	−0.0059 (7)	−0.0055 (7)	−0.0125 (7)
C31	0.0203 (8)	0.0183 (7)	0.0163 (7)	−0.0049 (6)	0.0003 (6)	−0.0071 (6)
C32	0.0195 (8)	0.0233 (8)	0.0207 (8)	−0.0032 (6)	0.0001 (6)	−0.0069 (7)
C33	0.0284 (9)	0.0199 (8)	0.0202 (8)	−0.0021 (7)	−0.0017 (7)	−0.0049 (7)
C34	0.0319 (10)	0.0213 (8)	0.0213 (8)	−0.0120 (7)	0.0031 (7)	−0.0054 (7)
C35	0.0226 (9)	0.0268 (9)	0.0292 (9)	−0.0111 (7)	0.0015 (7)	−0.0061 (7)
C36	0.0209 (8)	0.0203 (8)	0.0234 (8)	−0.0061 (6)	−0.0017 (6)	−0.0050 (7)
C37	0.0184 (7)	0.0166 (7)	0.0203 (7)	−0.0053 (6)	−0.0007 (6)	−0.0075 (6)
P1	0.01491 (18)	0.01144 (17)	0.01693 (18)	−0.00364 (14)	−0.00065 (14)	−0.00590 (14)
P2	0.01585 (19)	0.01487 (18)	0.01667 (19)	−0.00427 (15)	−0.00100 (14)	−0.00663 (15)
Cl1	0.0373 (2)	0.01797 (18)	0.02145 (19)	−0.01497 (17)	0.00302 (16)	−0.00717 (15)
Cl2	0.0270 (2)	0.0523 (3)	0.0291 (2)	−0.0029 (2)	−0.01223 (19)	−0.0002 (2)
Cl3	0.0448 (3)	0.0168 (2)	0.0426 (3)	−0.01495 (19)	−0.0064 (2)	−0.00755 (18)
Cl4	0.0390 (3)	0.0304 (2)	0.0270 (2)	0.0134 (2)	−0.0045 (2)	−0.00510 (19)
Cl5	0.0371 (3)	0.0340 (3)	0.0742 (4)	−0.0102 (2)	−0.0292 (3)	−0.0170 (3)
Cl6	0.0432 (3)	0.0276 (2)	0.0313 (2)	−0.0178 (2)	0.0031 (2)	−0.00148 (19)
Cl7	0.0213 (2)	0.0458 (3)	0.0463 (3)	−0.0170 (2)	0.00739 (19)	−0.0223 (2)
Rh1	0.01681 (7)	0.01199 (6)	0.01609 (6)	−0.00515 (4)	0.00030 (4)	−0.00597 (4)
O1	0.0338 (7)	0.0195 (6)	0.0280 (7)	−0.0111 (5)	−0.0011 (5)	−0.0040 (5)
C38	0.0233 (9)	0.0279 (10)	0.0451 (12)	−0.0039 (7)	−0.0021 (8)	−0.0200 (9)
C39	0.0591 (17)	0.0391 (13)	0.0492 (15)	−0.0084 (12)	−0.0019 (12)	−0.0020 (11)
C40	0.0412 (13)	0.0286 (11)	0.0677 (17)	−0.0111 (10)	−0.0042 (12)	−0.0116 (11)
O2	0.0511 (12)	0.0709 (14)	0.1097 (18)	0.0001 (10)	−0.0314 (12)	−0.0635 (14)

C1—C2	1.392 (2)	C22—C23	1.380 (3)
C1—C6	1.397 (2)	C22—Cl4	1.7434 (18)
C1—P1	1.8165 (17)	C23—C24	1.393 (2)
C2—C3	1.396 (2)	C23—H23	0.95
C2—H2	0.95	C24—H24	0.95
C3—C4	1.383 (3)	C25—C26	1.395 (3)
C3—H3	0.95	C25—C30	1.398 (2)
C4—C5	1.377 (3)	C25—P2	1.8221 (17)
C4—Cl7	1.7356 (18)	C26—C27	1.397 (3)
C5—C6	1.387 (2)	C26—H26	0.95
C5—H5	0.95	C27—C28	1.378 (3)
C6—H6	0.95	C27—H27	0.95
C7—C12	1.396 (2)	C28—C29	1.373 (3)
C7—C8	1.402 (2)	C28—Cl5	1.7438 (19)
C7—P1	1.8183 (17)	C29—C30	1.392 (3)
C8—C9	1.387 (2)	C29—H29	0.95
C8—H8	0.95	C30—H30	0.95
C9—C10	1.392 (3)	C31—C36	1.395 (2)
C9—H9	0.95	C31—C32	1.400 (2)
C10—C11	1.383 (3)	C31—P2	1.8235 (17)
C10—Cl2	1.7366 (19)	C32—C33	1.391 (2)
C11—C12	1.386 (2)	C32—H32	0.95
C11—H11	0.95	C33—C34	1.385 (3)
C12—H12	0.95	C33—H33	0.95
C13—C14	1.394 (2)	C34—C35	1.384 (3)
C13—C18	1.397 (2)	C34—Cl6	1.7426 (18)
C13—P1	1.8265 (16)	C35—C36	1.392 (2)
C14—C15	1.394 (2)	C35—H35	0.95
C14—H14	0.95	C36—H36	0.95
C15—C16	1.378 (3)	C37—O1	1.1420 (18)
C15—H15	0.95	C37—Rh1	1.8177 (13)
C16—C17	1.384 (3)	P1—Rh1	2.3127 (4)
C16—Cl3	1.7387 (17)	P2—Rh1	2.3219 (4)
C17—C18	1.390 (2)	Cl1—Rh1	2.3611 (4)
C17—H17	0.95	C38—O2	1.200 (3)
C18—H18	0.95	C38—C39	1.481 (3)
C19—C24	1.391 (2)	C38—C40	1.490 (3)
C19—C20	1.394 (2)	C39—H39A	0.98
C19—P2	1.8231 (17)	C39—H39B	0.98
C20—C21	1.392 (3)	C39—H39C	0.98
C20—H20	0.95	C40—H40A	0.98
C21—C22	1.384 (3)	C40—H40B	0.98
C21—H21	0.95	C40—H40C	0.98
C2—C1—C6	119.00 (15)	C23—C24—H24	119.7
C2—C1—P1	125.78 (13)	C26—C25—C30	119.21 (17)
C6—C1—P1	115.16 (12)	C26—C25—P2	119.51 (14)
C1—C2—C3	120.45 (16)	C30—C25—P2	121.21 (14)
C1—C2—H2	119.8	C25—C26—C27	120.16 (18)
C3—C2—H2	119.8	C25—C26—H26	119.9
C4—C3—C2	118.86 (17)	C27—C26—H26	119.9
C4—C3—H3	120.6	C28—C27—C26	119.00 (19)
C2—C3—H3	120.6	C28—C27—H27	120.5
C5—C4—C3	121.87 (16)	C26—C27—H27	120.5
C5—C4—Cl7	118.27 (15)	C29—C28—C27	122.19 (18)
C3—C4—Cl7	119.80 (14)	C29—C28—Cl5	118.59 (17)
C4—C5—C6	118.82 (17)	C27—C28—Cl5	119.22 (17)
C4—C5—H5	120.6	C28—C29—C30	118.81 (19)
C6—C5—H5	120.6	C28—C29—H29	120.6
C5—C6—C1	120.96 (16)	C30—C29—H29	120.6
C5—C6—H6	119.5	C29—C30—C25	120.61 (19)
C1—C6—H6	119.5	C29—C30—H30	119.7
C12—C7—C8	119.10 (15)	C25—C30—H30	119.7
C12—C7—P1	119.17 (13)	C36—C31—C32	118.67 (16)
C8—C7—P1	121.57 (12)	C36—C31—P2	120.49 (13)
C9—C8—C7	120.63 (16)	C32—C31—P2	119.87 (13)
C9—C8—H8	119.7	C33—C32—C31	120.96 (17)
C7—C8—H8	119.7	C33—C32—H32	119.5
C8—C9—C10	118.82 (17)	C31—C32—H32	119.5
C8—C9—H9	120.6	C34—C33—C32	118.87 (17)
C10—C9—H9	120.6	C34—C33—H33	120.6
C11—C10—C9	121.59 (17)	C32—C33—H33	120.6
C11—C10—Cl2	118.84 (15)	C35—C34—C33	121.55 (16)
C9—C10—Cl2	119.51 (15)	C35—C34—Cl6	119.26 (15)
C10—C11—C12	119.16 (17)	C33—C34—Cl6	119.19 (14)
C10—C11—H11	120.4	C34—C35—C36	119.00 (17)
C12—C11—H11	120.4	C34—C35—H35	120.5
C11—C12—C7	120.69 (17)	C36—C35—H35	120.5
C11—C12—H12	119.7	C35—C36—C31	120.89 (17)
C7—C12—H12	119.7	C35—C36—H36	119.6
C14—C13—C18	118.59 (15)	C31—C36—H36	119.6
C14—C13—P1	123.20 (13)	O1—C37—Rh1	179.52 (16)
C18—C13—P1	118.21 (12)	C1—P1—C7	108.94 (8)
C13—C14—C15	120.87 (16)	C1—P1—C13	103.78 (7)
C13—C14—H14	119.6	C7—P1—C13	101.87 (7)
C15—C14—H14	119.6	C1—P1—Rh1	108.60 (5)
C16—C15—C14	119.16 (16)	C7—P1—Rh1	114.06 (5)
C16—C15—H15	120.4	C13—P1—Rh1	118.80 (5)
C14—C15—H15	120.4	C25—P2—C19	104.16 (8)
C15—C16—C17	121.33 (16)	C25—P2—C31	105.01 (8)
C15—C16—Cl3	119.40 (14)	C19—P2—C31	104.90 (7)
C17—C16—Cl3	119.27 (14)	C25—P2—Rh1	119.28 (6)
C16—C17—C18	119.17 (17)	C19—P2—Rh1	110.52 (5)
C16—C17—H17	120.4	C31—P2—Rh1	111.77 (5)
C18—C17—H17	120.4	C37—Rh1—P1	91.58 (5)
C17—C18—C13	120.86 (16)	C37—Rh1—P2	91.37 (5)
C17—C18—H18	119.6	P1—Rh1—P2	175.268 (15)
C13—C18—H18	119.6	C37—Rh1—Cl1	178.21 (5)
C24—C19—C20	119.35 (16)	P1—Rh1—Cl1	86.675 (15)
C24—C19—P2	122.03 (13)	P2—Rh1—Cl1	90.348 (15)
C20—C19—P2	118.57 (13)	O2—C38—C39	120.8 (2)
C21—C20—C19	120.77 (17)	O2—C38—C40	122.3 (2)
C21—C20—H20	119.6	C39—C38—C40	116.8 (2)
C19—C20—H20	119.6	C38—C39—H39A	109.5
C22—C21—C20	118.33 (17)	C38—C39—H39B	109.5
C22—C21—H21	120.8	H39A—C39—H39B	109.5
C20—C21—H21	120.8	C38—C39—H39C	109.5
C23—C22—C21	122.22 (17)	H39A—C39—H39C	109.5
C23—C22—Cl4	118.67 (15)	H39B—C39—H39C	109.5
C21—C22—Cl4	119.08 (15)	C38—C40—H40A	109.5
C22—C23—C24	118.69 (17)	C38—C40—H40B	109.5
C22—C23—H23	120.7	H40A—C40—H40B	109.5
C24—C23—H23	120.7	C38—C40—H40C	109.5
C19—C24—C23	120.54 (17)	H40A—C40—H40C	109.5
C19—C24—H24	119.7	H40B—C40—H40C	109.5
C6—C1—C2—C3	1.3 (2)	C32—C33—C34—Cl6	−176.89 (14)
P1—C1—C2—C3	−175.68 (13)	C33—C34—C35—C36	−2.2 (3)
C1—C2—C3—C4	−0.2 (3)	Cl6—C34—C35—C36	176.83 (15)
C2—C3—C4—C5	−1.7 (3)	C34—C35—C36—C31	0.0 (3)
C2—C3—C4—Cl7	175.40 (14)	C32—C31—C36—C35	2.1 (3)
C3—C4—C5—C6	2.3 (3)	P2—C31—C36—C35	−166.64 (15)
Cl7—C4—C5—C6	−174.84 (14)	C2—C1—P1—C7	5.09 (17)
C4—C5—C6—C1	−1.0 (3)	C6—C1—P1—C7	−172.00 (12)
C2—C1—C6—C5	−0.7 (3)	C2—C1—P1—C13	−102.85 (15)
P1—C1—C6—C5	176.61 (14)	C6—C1—P1—C13	80.06 (13)
C12—C7—C8—C9	−0.5 (2)	C2—C1—P1—Rh1	129.86 (14)
P1—C7—C8—C9	−175.72 (13)	C6—C1—P1—Rh1	−47.23 (13)
C7—C8—C9—C10	1.4 (3)	C12—C7—P1—C1	123.09 (14)
C8—C9—C10—C11	−1.2 (3)	C8—C7—P1—C1	−61.67 (15)
C8—C9—C10—Cl2	175.78 (14)	C12—C7—P1—C13	−127.67 (14)
C9—C10—C11—C12	0.1 (3)	C8—C7—P1—C13	47.57 (15)
Cl2—C10—C11—C12	−176.89 (14)	C12—C7—P1—Rh1	1.59 (15)
C10—C11—C12—C7	0.8 (3)	C8—C7—P1—Rh1	176.83 (12)
C8—C7—C12—C11	−0.6 (3)	C14—C13—P1—C1	−7.18 (16)
P1—C7—C12—C11	174.71 (14)	C18—C13—P1—C1	173.94 (14)
C18—C13—C14—C15	0.2 (3)	C14—C13—P1—C7	−120.32 (15)
P1—C13—C14—C15	−178.63 (14)	C18—C13—P1—C7	60.80 (15)
C13—C14—C15—C16	−1.5 (3)	C14—C13—P1—Rh1	113.46 (14)
C14—C15—C16—C17	1.6 (3)	C18—C13—P1—Rh1	−65.42 (15)
C14—C15—C16—Cl3	−178.16 (14)	C26—C25—P2—C19	92.47 (15)
C15—C16—C17—C18	−0.4 (3)	C30—C25—P2—C19	−84.32 (16)
Cl3—C16—C17—C18	179.36 (15)	C26—C25—P2—C31	−157.52 (14)
C16—C17—C18—C13	−0.9 (3)	C30—C25—P2—C31	25.69 (16)
C14—C13—C18—C17	1.0 (3)	C26—C25—P2—Rh1	−31.31 (16)
P1—C13—C18—C17	179.91 (15)	C30—C25—P2—Rh1	151.90 (13)
C24—C19—C20—C21	−1.1 (3)	C24—C19—P2—C25	15.80 (16)
P2—C19—C20—C21	176.43 (14)	C20—C19—P2—C25	−161.65 (14)
C19—C20—C21—C22	−1.5 (3)	C24—C19—P2—C31	−94.30 (15)
C20—C21—C22—C23	3.3 (3)	C20—C19—P2—C31	88.26 (15)
C20—C21—C22—Cl4	−174.74 (15)	C24—C19—P2—Rh1	145.08 (13)
C21—C22—C23—C24	−2.4 (3)	C20—C19—P2—Rh1	−32.37 (15)
Cl4—C22—C23—C24	175.62 (15)	C36—C31—P2—C25	−139.07 (14)
C20—C19—C24—C23	2.0 (3)	C32—C31—P2—C25	52.33 (16)
P2—C19—C24—C23	−175.44 (14)	C36—C31—P2—C19	−29.59 (16)
C22—C23—C24—C19	−0.3 (3)	C32—C31—P2—C19	161.81 (14)
C30—C25—C26—C27	−0.9 (3)	C36—C31—P2—Rh1	90.20 (14)
P2—C25—C26—C27	−177.74 (14)	C32—C31—P2—Rh1	−78.39 (15)
C25—C26—C27—C28	−0.1 (3)	C1—P1—Rh1—C37	119.85 (8)
C26—C27—C28—C29	1.2 (3)	C7—P1—Rh1—C37	−118.47 (8)
C26—C27—C28—Cl5	−178.26 (14)	C13—P1—Rh1—C37	1.69 (8)
C27—C28—C29—C30	−1.2 (3)	C1—P1—Rh1—Cl1	−60.55 (6)
Cl5—C28—C29—C30	178.27 (15)	C7—P1—Rh1—Cl1	61.14 (6)
C28—C29—C30—C25	0.1 (3)	C13—P1—Rh1—Cl1	−178.70 (6)
C26—C25—C30—C29	0.9 (3)	C25—P2—Rh1—C37	−116.11 (8)
P2—C25—C30—C29	177.70 (14)	C19—P2—Rh1—C37	123.26 (8)
C36—C31—C32—C33	−2.2 (3)	C31—P2—Rh1—C37	6.83 (8)
P2—C31—C32—C33	166.64 (14)	C25—P2—Rh1—Cl1	64.39 (7)
C31—C32—C33—C34	0.1 (3)	C19—P2—Rh1—Cl1	−56.23 (6)
C32—C33—C34—C35	2.1 (3)	C31—P2—Rh1—Cl1	−172.66 (6)

D—H···A	D—H	H···A	D···A	D—H···A
C15—H15···O2i	0.95	2.55	3.492 (3)	170
C21—H21···O2ii	0.95	2.34	3.267 (3)	165
C24—H24···Cl5iii	0.95	2.80	3.4734 (19)	129
C30—H30···Cl4iv	0.95	2.76	3.575 (2)	145
C35—H35···O1v	0.95	2.47	3.384 (2)	161
C40—H40B···Cl1	0.98	2.79	3.738 (3)	162

C37—O1	1.1420 (18)
C37—Rh1	1.8177 (13)
P1—Rh1	2.3127 (4)
P2—Rh1	2.3219 (4)
Cl1—Rh1	2.3611 (4)

O1—C37—Rh1	179.52 (16)
P1—Rh1—P2	175.268 (15)
C37—Rh1—Cl1	178.21 (5)
P1—Rh1—Cl1	86.675 (15)
P2—Rh1—Cl1	90.348 (15)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C15—H15⋯O2i	0.95	2.55	3.492 (3)	170
C21—H21⋯O2ii	0.95	2.34	3.267 (3)	165
C24—H24⋯Cl5iii	0.95	2.80	3.4734 (19)	129
C30—H30⋯Cl4iv	0.95	2.76	3.575 (2)	145
C35—H35⋯O1v	0.95	2.47	3.384 (2)	161
C40—H40B⋯Cl1	0.98	2.79	3.738 (3)	162

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .