4-[4-Eth-oxy-carbonyl-5-(3,4-methyl-ene-dioxy-phen-yl)-3-oxocyclo-hex-1-en-1-yl]-3-phenyl-sydnone.

In the title compound {systematic name: 4-[4-eth-oxy-carbonyl-5-(3,4-methyl-ene-dioxy-phen-yl)-3-oxocyclo-hex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclo-hexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a dihedral angle of 79.0 (1)°. In the mol-ecular structure, a C-H⋯O hydrogen bond generates an S(6) ring and a C-H⋯π inter-action involving the phenyl ring is observed. In the crystal structure, mol-ecules are linked into a ribbon-like structure along the a axis by C-H⋯O hydrogen bonds.

Related literature

For general background and applications of sydnone compounds, see: Rai et al. (2008 ▶); Jyothi et al. (2008 ▶). For the synthesis of sydnone derivatives, see: Kalluraya et al. (2003 ▶). For related structures, see: Goh et al. (2010 ▶). For bond-length data, see: Allen et al. (1987 ▶). For hydrogen-bond motifs, see: Bernstein et al. (1995 ▶). For puckering parameters, see: Cremer & Pople (1975 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

Experimental

Crystal data

C24H20N2O7

M = 448.42

Triclinic,

a = 8.8026 (2) Å

b = 11.5133 (2) Å

c = 11.6981 (2) Å

α = 66.860 (1)°

β = 86.545 (1)°

γ = 71.115 (1)°

V = 1028.44 (4) Å3

Z = 2

Mo Kα radiation

μ = 0.11 mm−1

T = 100 K

0.37 × 0.13 × 0.06 mm

Data collection

Bruker SMART APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.962, T max = 0.994

18550 measured reflections

4703 independent reflections

3710 reflections with I > 2σ(I)

R int = 0.035

Refinement

R[F 2 > 2σ(F 2)] = 0.048

wR(F 2) = 0.119

S = 1.03

4703 reflections

299 parameters

H-atom parameters constrained

Δρmax = 0.56 e Å−3

Δρmin = −0.34 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT (Bruker, 2009 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536810033106/ci5156sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810033106/ci5156Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C24H20N2O7	Z = 2
Mr = 448.42	F(000) = 468
Triclinic, P1	Dx = 1.448 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.8026 (2) Å	Cell parameters from 5688 reflections
b = 11.5133 (2) Å	θ = 2.2–30.2°
c = 11.6981 (2) Å	µ = 0.11 mm−1
α = 66.860 (1)°	T = 100 K
β = 86.545 (1)°	Needle, colourless
γ = 71.115 (1)°	0.37 × 0.13 × 0.06 mm
V = 1028.44 (4) Å3

Bruker SMART APEXII CCD area-detector diffractometer	4703 independent reflections
Radiation source: fine-focus sealed tube	3710 reflections with I > 2σ(I)
graphite	Rint = 0.035
φ and ω scans	θmax = 27.5°, θmin = 1.9°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −11→11
Tmin = 0.962, Tmax = 0.994	k = −14→14
18550 measured reflections	l = −15→15

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.048	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.119	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0499P)2 + 0.6557P] where P = (Fo2 + 2Fc2)/3
4703 reflections	(Δ/σ)max = 0.001
299 parameters	Δρmax = 0.56 e Å−3
0 restraints	Δρmin = −0.34 e Å−3

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	0.54796 (15)	−0.47982 (12)	0.24568 (11)	0.0225 (3)
O2	0.09931 (15)	0.43102 (12)	0.42387 (11)	0.0228 (3)
O3	0.34786 (15)	0.29504 (13)	0.53026 (11)	0.0244 (3)
O4	0.73361 (16)	0.19987 (13)	0.20782 (12)	0.0263 (3)
O5	0.63381 (15)	0.31720 (12)	0.00796 (11)	0.0234 (3)
O6	0.73888 (15)	−0.39479 (12)	0.14030 (12)	0.0249 (3)
O7	0.79429 (16)	0.03513 (13)	0.01666 (12)	0.0271 (3)
N1	0.39657 (17)	−0.31654 (14)	0.28604 (13)	0.0175 (3)
N2	0.41071 (19)	−0.43911 (14)	0.30166 (14)	0.0227 (3)
C1	0.2822 (2)	−0.29087 (18)	0.47181 (16)	0.0219 (4)
H1A	0.3768	−0.3542	0.5175	0.026*
C2	0.1577 (2)	−0.23095 (19)	0.52984 (17)	0.0255 (4)
H2A	0.1680	−0.2536	0.6152	0.031*
C3	0.0177 (2)	−0.13688 (19)	0.45938 (19)	0.0279 (4)
H3A	−0.0658	−0.0963	0.4980	0.033*
C4	0.0010 (2)	−0.10279 (19)	0.33208 (18)	0.0277 (4)
H4A	−0.0935	−0.0395	0.2861	0.033*
C5	0.1236 (2)	−0.16201 (18)	0.27268 (16)	0.0231 (4)
H5A	0.1129	−0.1404	0.1875	0.028*
C6	0.2628 (2)	−0.25450 (16)	0.34455 (15)	0.0181 (3)
C7	0.6164 (2)	−0.37744 (16)	0.19344 (15)	0.0186 (4)
C8	0.5132 (2)	−0.26951 (16)	0.22242 (15)	0.0165 (3)
C9	0.5348 (2)	−0.14190 (16)	0.19358 (14)	0.0155 (3)
C10	0.4237 (2)	−0.03949 (16)	0.23803 (15)	0.0161 (3)
H10A	0.3924	−0.0853	0.3202	0.019*
H10B	0.3269	0.0099	0.1819	0.019*
C11	0.5027 (2)	0.05872 (17)	0.24418 (16)	0.0196 (4)
H11A	0.5949	0.0075	0.3064	0.023*
C12	0.5672 (2)	0.12241 (17)	0.11849 (16)	0.0209 (4)
H12A	0.4763	0.1728	0.0550	0.025*
C13	0.6849 (2)	0.01333 (18)	0.08194 (16)	0.0200 (4)
C14	0.6583 (2)	−0.11497 (17)	0.12458 (15)	0.0177 (3)
H14A	0.7294	−0.1819	0.1035	0.021*
C15	0.3878 (2)	0.16253 (17)	0.28630 (16)	0.0193 (4)
C16	0.2380 (2)	0.24512 (18)	0.22215 (16)	0.0225 (4)
H16A	0.2090	0.2370	0.1512	0.027*
C17	0.1295 (2)	0.34015 (17)	0.26119 (16)	0.0212 (4)
H17A	0.0298	0.3947	0.2183	0.025*
C18	0.1795 (2)	0.34732 (16)	0.36599 (15)	0.0180 (4)
C19	0.1948 (2)	0.38560 (18)	0.53747 (17)	0.0232 (4)
H19A	0.1418	0.3407	0.6080	0.028*
H19B	0.2093	0.4608	0.5482	0.028*
C20	0.3280 (2)	0.26646 (17)	0.42936 (16)	0.0190 (4)
C21	0.4350 (2)	0.17364 (17)	0.39255 (16)	0.0193 (4)
H21A	0.5346	0.1204	0.4362	0.023*
C22	0.6534 (2)	0.21628 (17)	0.11888 (16)	0.0187 (4)
C23	0.7312 (2)	0.40341 (18)	−0.00653 (18)	0.0267 (4)
H23A	0.7349	0.4177	0.0695	0.032*
H23B	0.6825	0.4896	−0.0740	0.032*
C24	0.8997 (2)	0.3393 (2)	−0.0344 (2)	0.0348 (5)
H24A	0.9649	0.3929	−0.0374	0.052*
H24B	0.8965	0.3325	−0.1134	0.052*
H24C	0.9450	0.2516	0.0298	0.052*

	U11	U22	U33	U12	U13	U23
O1	0.0288 (7)	0.0144 (6)	0.0231 (6)	−0.0049 (5)	0.0041 (5)	−0.0082 (5)
O2	0.0216 (6)	0.0217 (6)	0.0233 (6)	0.0021 (5)	0.0006 (5)	−0.0142 (5)
O3	0.0209 (7)	0.0281 (7)	0.0225 (6)	0.0006 (5)	−0.0002 (5)	−0.0150 (5)
O4	0.0303 (7)	0.0250 (7)	0.0251 (7)	−0.0094 (6)	0.0006 (5)	−0.0109 (5)
O5	0.0281 (7)	0.0187 (6)	0.0231 (6)	−0.0081 (5)	0.0003 (5)	−0.0076 (5)
O6	0.0263 (7)	0.0211 (7)	0.0299 (7)	−0.0048 (5)	0.0064 (5)	−0.0158 (5)
O7	0.0295 (7)	0.0278 (7)	0.0315 (7)	−0.0141 (6)	0.0156 (6)	−0.0175 (6)
N1	0.0233 (8)	0.0134 (7)	0.0153 (7)	−0.0058 (6)	0.0011 (5)	−0.0052 (5)
N2	0.0304 (9)	0.0148 (7)	0.0217 (7)	−0.0066 (6)	0.0047 (6)	−0.0069 (6)
C1	0.0248 (9)	0.0215 (9)	0.0191 (8)	−0.0096 (7)	0.0013 (7)	−0.0061 (7)
C2	0.0312 (10)	0.0313 (10)	0.0212 (9)	−0.0166 (9)	0.0083 (7)	−0.0134 (8)
C3	0.0280 (10)	0.0265 (10)	0.0360 (11)	−0.0117 (8)	0.0134 (8)	−0.0185 (8)
C4	0.0237 (10)	0.0201 (9)	0.0345 (10)	−0.0037 (8)	0.0019 (8)	−0.0087 (8)
C5	0.0281 (10)	0.0198 (9)	0.0193 (8)	−0.0082 (8)	0.0008 (7)	−0.0053 (7)
C6	0.0221 (9)	0.0152 (8)	0.0200 (8)	−0.0087 (7)	0.0053 (7)	−0.0085 (6)
C7	0.0246 (9)	0.0138 (8)	0.0166 (8)	−0.0040 (7)	−0.0021 (7)	−0.0062 (6)
C8	0.0190 (8)	0.0156 (8)	0.0150 (8)	−0.0039 (7)	0.0010 (6)	−0.0074 (6)
C9	0.0185 (8)	0.0149 (8)	0.0125 (7)	−0.0032 (6)	−0.0018 (6)	−0.0062 (6)
C10	0.0179 (8)	0.0141 (8)	0.0167 (8)	−0.0044 (6)	0.0029 (6)	−0.0073 (6)
C11	0.0216 (9)	0.0179 (8)	0.0210 (8)	−0.0062 (7)	0.0035 (7)	−0.0099 (7)
C12	0.0238 (9)	0.0194 (9)	0.0214 (9)	−0.0073 (7)	0.0028 (7)	−0.0101 (7)
C13	0.0225 (9)	0.0232 (9)	0.0188 (8)	−0.0086 (7)	0.0044 (7)	−0.0122 (7)
C14	0.0200 (8)	0.0175 (8)	0.0172 (8)	−0.0032 (7)	0.0023 (6)	−0.0109 (6)
C15	0.0199 (9)	0.0152 (8)	0.0237 (9)	−0.0068 (7)	0.0083 (7)	−0.0086 (7)
C16	0.0287 (10)	0.0235 (9)	0.0203 (8)	−0.0105 (8)	0.0051 (7)	−0.0127 (7)
C17	0.0220 (9)	0.0183 (9)	0.0211 (9)	−0.0046 (7)	0.0013 (7)	−0.0070 (7)
C18	0.0199 (9)	0.0129 (8)	0.0207 (8)	−0.0036 (7)	0.0070 (7)	−0.0081 (6)
C19	0.0234 (9)	0.0227 (9)	0.0235 (9)	−0.0024 (7)	0.0021 (7)	−0.0132 (7)
C20	0.0212 (9)	0.0164 (8)	0.0195 (8)	−0.0063 (7)	0.0043 (7)	−0.0075 (6)
C21	0.0179 (8)	0.0151 (8)	0.0225 (9)	−0.0033 (7)	0.0041 (7)	−0.0071 (7)
C22	0.0187 (8)	0.0175 (8)	0.0210 (8)	−0.0038 (7)	0.0051 (7)	−0.0108 (7)
C23	0.0346 (11)	0.0187 (9)	0.0287 (10)	−0.0136 (8)	0.0014 (8)	−0.0071 (7)
C24	0.0315 (11)	0.0345 (12)	0.0395 (12)	−0.0176 (9)	0.0060 (9)	−0.0107 (9)

O1—N2	1.3739 (19)	C10—C11	1.532 (2)
O1—C7	1.405 (2)	C10—H10A	0.97
O2—C18	1.379 (2)	C10—H10B	0.97
O2—C19	1.432 (2)	C11—C15	1.521 (2)
O3—C20	1.378 (2)	C11—C12	1.531 (2)
O3—C19	1.434 (2)	C11—H11A	0.98
O4—C22	1.210 (2)	C12—C22	1.509 (2)
O5—C22	1.333 (2)	C12—C13	1.536 (2)
O5—C23	1.466 (2)	C12—H12A	0.98
O6—C7	1.211 (2)	C13—C14	1.455 (2)
O7—C13	1.221 (2)	C14—H14A	0.93
N1—N2	1.314 (2)	C15—C16	1.397 (3)
N1—C8	1.361 (2)	C15—C21	1.399 (2)
N1—C6	1.452 (2)	C16—C17	1.408 (2)
C1—C6	1.384 (2)	C16—H16A	0.93
C1—C2	1.388 (3)	C17—C18	1.368 (2)
C1—H1A	0.93	C17—H17A	0.93
C2—C3	1.389 (3)	C18—C20	1.383 (2)
C2—H2A	0.93	C19—H19A	0.97
C3—C4	1.387 (3)	C19—H19B	0.97
C3—H3A	0.93	C20—C21	1.370 (2)
C4—C5	1.385 (3)	C21—H21A	0.93
C4—H4A	0.93	C23—C24	1.508 (3)
C5—C6	1.385 (2)	C23—H23A	0.97
C5—H5A	0.9300	C23—H23B	0.97
C7—C8	1.431 (2)	C24—H24A	0.96
C8—C9	1.446 (2)	C24—H24B	0.96
C9—C14	1.358 (2)	C24—H24C	0.96
C9—C10	1.514 (2)
N2—O1—C7	110.82 (12)	C11—C12—C13	110.07 (14)
C18—O2—C19	105.46 (13)	C22—C12—H12A	108.5
C20—O3—C19	105.33 (13)	C11—C12—H12A	108.5
C22—O5—C23	115.58 (14)	C13—C12—H12A	108.5
N2—N1—C8	115.22 (14)	O7—C13—C14	121.36 (16)
N2—N1—C6	114.75 (14)	O7—C13—C12	120.91 (16)
C8—N1—C6	129.96 (14)	C14—C13—C12	117.71 (15)
N1—N2—O1	104.74 (13)	C9—C14—C13	123.30 (16)
C6—C1—C2	118.67 (17)	C9—C14—H14A	118.4
C6—C1—H1A	120.7	C13—C14—H14A	118.4
C2—C1—H1A	120.7	C16—C15—C21	119.99 (16)
C1—C2—C3	119.48 (17)	C16—C15—C11	121.71 (16)
C1—C2—H2A	120.3	C21—C15—C11	118.30 (15)
C3—C2—H2A	120.3	C15—C16—C17	122.31 (16)
C4—C3—C2	120.67 (18)	C15—C16—H16A	118.8
C4—C3—H3A	119.7	C17—C16—H16A	118.8
C2—C3—H3A	119.7	C18—C17—C16	115.96 (16)
C5—C4—C3	120.66 (18)	C18—C17—H17A	122.0
C5—C4—H4A	119.7	C16—C17—H17A	122.0
C3—C4—H4A	119.7	C17—C18—O2	128.32 (16)
C6—C5—C4	117.67 (17)	C17—C18—C20	121.97 (16)
C6—C5—H5A	121.2	O2—C18—C20	109.71 (15)
C4—C5—H5A	121.2	O2—C19—O3	107.89 (13)
C1—C6—C5	122.84 (16)	O2—C19—H19A	110.1
C1—C6—N1	117.38 (15)	O3—C19—H19A	110.1
C5—C6—N1	119.77 (15)	O2—C19—H19B	110.1
O6—C7—O1	120.52 (15)	O3—C19—H19B	110.1
O6—C7—C8	134.77 (16)	H19A—C19—H19B	108.4
O1—C7—C8	104.70 (14)	C21—C20—O3	127.31 (16)
N1—C8—C7	104.51 (14)	C21—C20—C18	122.79 (16)
N1—C8—C9	128.77 (15)	O3—C20—C18	109.90 (15)
C7—C8—C9	126.68 (15)	C20—C21—C15	116.97 (16)
C14—C9—C8	118.32 (15)	C20—C21—H21A	121.5
C14—C9—C10	120.05 (15)	C15—C21—H21A	121.5
C8—C9—C10	121.62 (14)	O4—C22—O5	124.34 (16)
C9—C10—C11	112.31 (14)	O4—C22—C12	124.18 (16)
C9—C10—H10A	109.1	O5—C22—C12	111.46 (14)
C11—C10—H10A	109.1	O5—C23—C24	109.97 (15)
C9—C10—H10B	109.1	O5—C23—H23A	109.7
C11—C10—H10B	109.1	C24—C23—H23A	109.7
H10A—C10—H10B	107.9	O5—C23—H23B	109.7
C15—C11—C12	112.34 (14)	C24—C23—H23B	109.7
C15—C11—C10	111.42 (14)	H23A—C23—H23B	108.2
C12—C11—C10	109.94 (14)	C23—C24—H24A	109.5
C15—C11—H11A	107.6	C23—C24—H24B	109.5
C12—C11—H11A	107.6	H24A—C24—H24B	109.5
C10—C11—H11A	107.6	C23—C24—H24C	109.5
C22—C12—C11	113.06 (14)	H24A—C24—H24C	109.5
C22—C12—C13	108.19 (14)	H24B—C24—H24C	109.5
C8—N1—N2—O1	0.58 (18)	C11—C12—C13—O7	−151.39 (16)
C6—N1—N2—O1	−176.69 (13)	C22—C12—C13—C14	154.41 (15)
C7—O1—N2—N1	−0.90 (17)	C11—C12—C13—C14	30.4 (2)
C6—C1—C2—C3	0.1 (3)	C8—C9—C14—C13	175.29 (15)
C1—C2—C3—C4	0.2 (3)	C10—C9—C14—C13	−4.6 (2)
C2—C3—C4—C5	0.1 (3)	O7—C13—C14—C9	−177.63 (16)
C3—C4—C5—C6	−0.7 (3)	C12—C13—C14—C9	0.5 (2)
C2—C1—C6—C5	−0.8 (3)	C12—C11—C15—C16	66.7 (2)
C2—C1—C6—N1	178.54 (15)	C10—C11—C15—C16	−57.2 (2)
C4—C5—C6—C1	1.1 (3)	C12—C11—C15—C21	−113.64 (17)
C4—C5—C6—N1	−178.24 (15)	C10—C11—C15—C21	122.49 (16)
N2—N1—C6—C1	78.33 (19)	C21—C15—C16—C17	−0.7 (3)
C8—N1—C6—C1	−98.4 (2)	C11—C15—C16—C17	178.99 (16)
N2—N1—C6—C5	−102.29 (18)	C15—C16—C17—C18	0.2 (3)
C8—N1—C6—C5	80.9 (2)	C16—C17—C18—O2	179.39 (16)
N2—O1—C7—O6	179.69 (15)	C16—C17—C18—C20	0.3 (3)
N2—O1—C7—C8	0.88 (17)	C19—O2—C18—C17	172.59 (18)
N2—N1—C8—C7	−0.05 (19)	C19—O2—C18—C20	−8.19 (18)
C6—N1—C8—C7	176.72 (15)	C18—O2—C19—O3	12.89 (18)
N2—N1—C8—C9	−177.79 (16)	C20—O3—C19—O2	−12.72 (18)
C6—N1—C8—C9	−1.0 (3)	C19—O3—C20—C21	−172.51 (17)
O6—C7—C8—N1	−179.06 (19)	C19—O3—C20—C18	7.75 (18)
O1—C7—C8—N1	−0.50 (17)	C17—C18—C20—C21	−0.2 (3)
O6—C7—C8—C9	−1.3 (3)	O2—C18—C20—C21	−179.48 (15)
O1—C7—C8—C9	177.31 (15)	C17—C18—C20—O3	179.55 (15)
N1—C8—C9—C14	−177.80 (16)	O2—C18—C20—O3	0.27 (19)
C7—C8—C9—C14	4.9 (3)	O3—C20—C21—C15	180.00 (16)
N1—C8—C9—C10	2.0 (3)	C18—C20—C21—C15	−0.3 (3)
C7—C8—C9—C10	−175.23 (15)	C16—C15—C21—C20	0.7 (2)
C14—C9—C10—C11	−23.1 (2)	C11—C15—C21—C20	−178.98 (15)
C8—C9—C10—C11	157.03 (15)	C23—O5—C22—O4	6.4 (2)
C9—C10—C11—C15	178.75 (14)	C23—O5—C22—C12	−171.70 (14)
C9—C10—C11—C12	53.54 (18)	C11—C12—C22—O4	34.7 (2)
C15—C11—C12—C22	57.8 (2)	C13—C12—C22—O4	−87.5 (2)
C10—C11—C12—C22	−177.53 (14)	C11—C12—C22—O5	−147.17 (15)
C15—C11—C12—C13	178.89 (14)	C13—C12—C22—O5	90.67 (17)
C10—C11—C12—C13	−56.42 (18)	C22—O5—C23—C24	80.80 (19)
C22—C12—C13—O7	−27.4 (2)

Cg1 is the centroid of the C1–C6 ring.

D—H···A	D—H	H···A	D···A	D—H···A
C4—H4A···O4i	0.93	2.49	3.304 (3)	146
C5—H5A···O7ii	0.93	2.44	3.258 (2)	146
C14—H14A···O6	0.93	2.29	2.998 (2)	133
C10—H10A···Cg1	0.97	2.48	3.570 (2)	133

Table 1

Hydrogen-bond geometry (Å, °)

Cg1 is the centroid of the C1–C6 ring.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C4—H4A⋯O4i	0.93	2.49	3.304 (3)	146
C5—H5A⋯O7ii	0.93	2.44	3.258 (2)	146
C14—H14A⋯O6	0.93	2.29	2.998 (2)	133
C10—H10A⋯Cg1	0.97	2.48	3.570 (2)	133

Symmetry codes: (i) ; (ii) .