Literature DB >> 21588487

Tris(2-chloro-benz-yl)(1H-1,2,4-triazole-5-thiol-ato-κS)tin(IV)-tris-(2-chloro-benz-yl)(4H-1,2,4-triazole-3-thiol-ato-κS)tin(IV) (1/1).

Thy Chun Keng1, Kong Mun Lo, Seik Weng Ng.   

Abstract

Tris(2-chloro-benz-yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol-ecules which differ only in the position of the nitro-gen-bound H atom of the triazole ring; one mol-ecule is linked to the other mol-ecule by an N-H⋯N hydrogen bond. In the second mol-ecule, two of the chloro-benzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both mol-ecules shows a distorted tetra-hedral SnSC(3) coordination.

Entities:  

Year:  2010        PMID: 21588487      PMCID: PMC3008140          DOI: 10.1107/S160053681003076X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


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1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

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1.  Crystal and mol-ecular structures of a binuclear mixed ligand complex of silver(I) with thio-cyanate and 1H-1,2,4-triazole-5(4H)-thione.

Authors:  Janjira Kreaunakpan; Kittipong Chainok; Nathan R Halcovitch; Edward R T Tiekink; Teerapong Pirojsirikul; Saowanit Saithong
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2020-01-01
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