(OC-6-33)-(2,2'-Bipyridine-κN,N')trimeth-yl(2-methyl-sulfanyl-2-thia-zoline-κN)platinum(IV) tetra-fluoridoborate.

The asymmetric unit of the title complex, [Pt(CH(3))(3)(C(10)H(8)N(2))(C(4)H(7)NS(2))]BF(4), contains two crystallographically independent mol-ecules. The Pt(IV) atom in each complex cation exhibits a distorted octa-hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl-sulfanyl-2-thia-zoline ligand (configuration index: OC-6-33). In the crystal structure, weak inter-molecular C-H⋯F hydrogen bonds are found between the complex cations and BF(4) (-) anions.

Related literature

For general background to the substitution reactions starting from complexes exhibiting a PtMe3 unit, see: Clegg et al. (1972 ▶); Lindner et al. (2008 ▶); Steinborn & Junicke (2000 ▶); Vetter et al. (2006 ▶, 2010 ▶). For a description of the Cambridge Structural Database, see: Allen (2002 ▶). For the conformation of the five-membered thia­zoline ring, see: Bucourt (1974 ▶). For the ligand synthesis, see: Bose et al. (1973 ▶).

Experimental

Crystal data

[Pt(CH3)3(C10H8N2)(C4H7NS2)]BF4

M = 616.41

Triclinic,

a = 10.5163 (8) Å

b = 13.2441 (11) Å

c = 17.1372 (14) Å

α = 106.776 (6)°

β = 106.690 (6)°

γ = 97.050 (6)°

V = 2133.3 (3) Å3

Z = 4

Mo Kα radiation

μ = 6.82 mm−1

T = 173 K

0.55 × 0.30 × 0.26 mm

Data collection

Stoe IPDS-2 diffractometer

Absorption correction: numerical (X-RED; Stoe & Cie, 2002 ▶) T min = 0.082, T max = 0.259

15501 measured reflections

7133 independent reflections

6275 reflections with I > 2σ(I)

R int = 0.072

Refinement

R[F 2 > 2σ(F 2)] = 0.045

wR(F 2) = 0.118

S = 1.01

7133 reflections

513 parameters

H-atom parameters constrained

Δρmax = 2.72 e Å−3

Δρmin = −4.03 e Å−3

Data collection: X-AREA (Stoe & Cie, 2002 ▶); cell refinement: X-AREA; data reduction: X-RED (Stoe & Cie, 2002 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 1999 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810027546/hy2325sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810027546/hy2325Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Pt(CH3)3(C10H8N2)(C4H7NS2)]BF4	Z = 4
Mr = 616.41	F(000) = 1192
Triclinic, P1	Dx = 1.919 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.5163 (8) Å	Cell parameters from 24955 reflections
b = 13.2441 (11) Å	θ = 1.7–25.6°
c = 17.1372 (14) Å	µ = 6.82 mm−1
α = 106.776 (6)°	T = 173 K
β = 106.690 (6)°	Block, yellow
γ = 97.050 (6)°	0.55 × 0.30 × 0.26 mm
V = 2133.3 (3) Å3

Stoe IPDS-2 diffractometer	7133 independent reflections
Radiation source: sealed X-ray tube, 12 x 0.4 mm long-fine focus	6275 reflections with I > 2σ(I)
plane graphite	Rint = 0.072
Detector resolution: 6.67 pixels mm-1	θmax = 25.0°, θmin = 1.7°
rotation method scans	h = −12→12
Absorption correction: numerical (X-RED; Stoe & Cie, 2002)	k = −15→15
Tmin = 0.082, Tmax = 0.259	l = −20→20
15501 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.045	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.118	H-atom parameters constrained
S = 1.01	w = 1/[σ2(Fo2) + (0.0874P)2] where P = (Fo2 + 2Fc2)/3
7133 reflections	(Δ/σ)max = 0.002
513 parameters	Δρmax = 2.72 e Å−3
0 restraints	Δρmin = −4.03 e Å−3

	x	y	z	Uiso*/Ueq
Pt1	0.90066 (2)	0.795521 (18)	0.128788 (14)	0.03034 (11)
S1	0.7153 (2)	0.42771 (14)	−0.05713 (12)	0.0476 (5)
S2	0.6969 (2)	0.54876 (14)	0.11679 (12)	0.0439 (4)
N1	0.8333 (6)	0.6290 (4)	0.0323 (3)	0.0316 (12)
N2	0.6950 (6)	0.8095 (4)	0.1220 (4)	0.0325 (12)
N3	0.8303 (5)	0.8527 (4)	0.0203 (3)	0.0298 (11)
C1	0.9596 (8)	0.7432 (6)	0.2332 (5)	0.0430 (17)
H1A	1.0320	0.7996	0.2812	0.065*
H1B	0.9933	0.6773	0.2166	0.065*
H1C	0.8814	0.7279	0.2515	0.065*
C2	1.0985 (8)	0.8014 (7)	0.1312 (5)	0.0441 (18)
H2A	1.0987	0.7524	0.0761	0.066*
H2B	1.1487	0.7792	0.1788	0.066*
H2C	1.1421	0.8754	0.1399	0.066*
C3	0.9625 (7)	0.9513 (5)	0.2160 (5)	0.0399 (16)
H3A	0.9384	0.9531	0.2674	0.060*
H3B	0.9173	0.9993	0.1891	0.060*
H3C	1.0615	0.9756	0.2329	0.060*
C4	0.7580 (7)	0.5470 (5)	0.0323 (4)	0.0349 (14)
C5	0.8328 (8)	0.4902 (6)	−0.0979 (5)	0.0479 (18)
H5A	0.9196	0.4662	−0.0841	0.057*
H5B	0.7932	0.4715	−0.1615	0.057*
C6	0.8557 (9)	0.6106 (6)	−0.0524 (4)	0.049 (2)
H6A	0.9498	0.6469	−0.0427	0.058*
H6B	0.7917	0.6413	−0.0888	0.058*
C7	0.5935 (8)	0.4148 (6)	0.0833 (5)	0.0464 (18)
H7A	0.5181	0.4015	0.0296	0.070*
H7B	0.5570	0.4084	0.1286	0.070*
H7C	0.6492	0.3614	0.0733	0.070*
C8	0.6363 (7)	0.7983 (5)	0.1800 (4)	0.0385 (16)
H8A	0.6831	0.7741	0.2250	0.046*
C9	0.5110 (7)	0.8206 (5)	0.1766 (5)	0.0390 (16)
H9A	0.4724	0.8123	0.2188	0.047*
C10	0.4419 (7)	0.8549 (6)	0.1115 (5)	0.0440 (18)
H10A	0.3546	0.8697	0.1076	0.053*
C11	0.5008 (7)	0.8677 (6)	0.0519 (5)	0.0439 (17)
H11A	0.4555	0.8925	0.0069	0.053*
C12	0.6281 (7)	0.8436 (5)	0.0584 (4)	0.0337 (14)
C13	0.7013 (7)	0.8560 (5)	−0.0021 (4)	0.0337 (15)
C14	0.6371 (8)	0.8755 (6)	−0.0784 (5)	0.0434 (17)
H14A	0.5430	0.8760	−0.0955	0.052*
C15	0.7138 (9)	0.8938 (7)	−0.1279 (5)	0.051 (2)
H15A	0.6729	0.9085	−0.1794	0.061*
C16	0.8479 (8)	0.8911 (6)	−0.1033 (5)	0.0454 (17)
H16A	0.9018	0.9037	−0.1370	0.054*
C17	0.9039 (7)	0.8695 (5)	−0.0282 (4)	0.0367 (15)
H17A	0.9973	0.8666	−0.0107	0.044*
Pt2	0.69060 (2)	0.254880 (18)	0.416978 (15)	0.03203 (11)
S3	0.7284 (2)	0.00166 (16)	0.57064 (12)	0.0508 (5)
S4	0.8042 (3)	0.00206 (16)	0.41291 (13)	0.0553 (5)
N4	0.7031 (6)	0.1511 (5)	0.5008 (4)	0.0385 (13)
N5	0.9006 (6)	0.2658 (4)	0.4277 (4)	0.0336 (13)
N6	0.7990 (6)	0.3874 (4)	0.5379 (4)	0.0376 (14)
C18	0.6002 (8)	0.1255 (6)	0.3032 (5)	0.0439 (18)
H18A	0.6703	0.0907	0.2869	0.066*
H18B	0.5520	0.1510	0.2572	0.066*
H18C	0.5354	0.0731	0.3114	0.066*
C19	0.4940 (8)	0.2598 (8)	0.4102 (6)	0.055 (2)
H19A	0.4565	0.2017	0.4275	0.083*
H19B	0.4390	0.2503	0.3507	0.083*
H19C	0.4923	0.3299	0.4492	0.083*
C20	0.6776 (10)	0.3554 (7)	0.3447 (7)	0.061 (2)
H20A	0.5874	0.3335	0.2998	0.091*
H20B	0.7478	0.3504	0.3173	0.091*
H20C	0.6916	0.4301	0.3824	0.091*
C21	0.7396 (7)	0.0620 (5)	0.4931 (4)	0.0384 (15)
C22	0.6366 (8)	0.1002 (6)	0.6105 (5)	0.0486 (19)
H22A	0.5375	0.0683	0.5873	0.058*
H22B	0.6669	0.1252	0.6746	0.058*
C23	0.6678 (8)	0.1919 (6)	0.5802 (5)	0.0445 (17)
H23A	0.5876	0.2244	0.5676	0.053*
H23B	0.7450	0.2484	0.6259	0.053*
C24	0.8292 (12)	−0.1231 (7)	0.4296 (6)	0.067 (3)
H24A	0.7406	−0.1726	0.4112	0.101*
H24B	0.8772	−0.1088	0.4912	0.101*
H24C	0.8835	−0.1559	0.3956	0.101*
C25	0.9448 (7)	0.2162 (5)	0.3634 (4)	0.0380 (15)
H25A	0.8800	0.1706	0.3092	0.046*
C26	1.0807 (8)	0.2298 (6)	0.3738 (5)	0.0420 (16)
H26A	1.1095	0.1942	0.3274	0.050*
C27	1.1754 (8)	0.2958 (6)	0.4526 (5)	0.0454 (17)
H27A	1.2701	0.3046	0.4617	0.054*
C28	1.1301 (7)	0.3490 (6)	0.5182 (5)	0.0421 (16)
H28A	1.1935	0.3957	0.5724	0.051*
C29	0.9931 (7)	0.3338 (5)	0.5040 (4)	0.0345 (14)
C30	0.9366 (7)	0.3958 (5)	0.5676 (5)	0.0385 (16)
C31	1.0144 (8)	0.4619 (6)	0.6503 (5)	0.049 (2)
H31A	1.1093	0.4646	0.6710	0.059*
C32	0.9557 (10)	0.5250 (6)	0.7040 (5)	0.061 (2)
H32A	1.0088	0.5708	0.7613	0.073*
C33	0.8183 (10)	0.5189 (6)	0.6712 (5)	0.056 (2)
H33A	0.7755	0.5627	0.7055	0.068*
C34	0.7431 (9)	0.4500 (6)	0.5896 (5)	0.048 (2)
H34A	0.6480	0.4462	0.5685	0.058*
F1	0.5476 (9)	0.3215 (6)	0.7103 (5)	0.102 (2)
F2	0.3580 (5)	0.3890 (5)	0.7105 (3)	0.0725 (16)
F3	0.5624 (6)	0.4994 (5)	0.7516 (3)	0.0755 (16)
F4	0.4545 (5)	0.3968 (5)	0.6108 (3)	0.0651 (15)
B1	0.4768 (10)	0.3997 (8)	0.6943 (6)	0.048 (2)
F5	0.7192 (6)	0.2028 (6)	0.1475 (4)	0.089 (2)
F6	0.9447 (5)	0.2042 (5)	0.1846 (3)	0.0673 (14)
F7	0.8041 (6)	0.1086 (5)	0.0505 (4)	0.084 (2)
F8	0.8528 (7)	0.2856 (5)	0.0919 (4)	0.0819 (17)
B2	0.8268 (10)	0.1985 (7)	0.1203 (6)	0.045 (2)

	U11	U22	U33	U12	U13	U23
Pt1	0.02865 (17)	0.03093 (15)	0.02646 (15)	0.00606 (11)	0.00803 (11)	0.00410 (11)
S1	0.0597 (12)	0.0337 (8)	0.0392 (9)	0.0042 (8)	0.0200 (9)	−0.0030 (7)
S2	0.0535 (11)	0.0355 (8)	0.0407 (9)	0.0052 (8)	0.0232 (8)	0.0050 (7)
N1	0.028 (3)	0.035 (3)	0.026 (3)	0.009 (2)	0.007 (2)	0.003 (2)
N2	0.032 (3)	0.029 (2)	0.032 (3)	0.005 (2)	0.013 (2)	0.003 (2)
N3	0.027 (3)	0.030 (2)	0.026 (2)	0.004 (2)	0.004 (2)	0.007 (2)
C1	0.045 (4)	0.047 (4)	0.033 (3)	0.011 (3)	0.009 (3)	0.012 (3)
C2	0.030 (4)	0.055 (4)	0.040 (4)	0.006 (3)	0.010 (3)	0.010 (3)
C3	0.035 (4)	0.037 (3)	0.041 (4)	0.009 (3)	0.009 (3)	0.007 (3)
C4	0.033 (3)	0.031 (3)	0.033 (3)	0.010 (3)	0.007 (3)	0.004 (3)
C5	0.049 (4)	0.050 (4)	0.038 (4)	0.013 (4)	0.015 (3)	0.006 (3)
C6	0.078 (6)	0.036 (3)	0.025 (3)	0.012 (4)	0.020 (4)	−0.003 (3)
C7	0.048 (4)	0.038 (4)	0.056 (4)	0.009 (3)	0.024 (4)	0.014 (3)
C8	0.043 (4)	0.036 (3)	0.034 (3)	0.006 (3)	0.019 (3)	0.004 (3)
C9	0.038 (4)	0.039 (3)	0.044 (4)	0.009 (3)	0.023 (3)	0.010 (3)
C10	0.032 (4)	0.042 (4)	0.052 (4)	0.009 (3)	0.018 (3)	0.004 (3)
C11	0.041 (4)	0.040 (4)	0.048 (4)	0.009 (3)	0.017 (3)	0.010 (3)
C12	0.031 (3)	0.030 (3)	0.032 (3)	0.001 (3)	0.009 (3)	0.003 (2)
C13	0.035 (4)	0.030 (3)	0.027 (3)	0.001 (3)	0.012 (3)	−0.002 (2)
C14	0.035 (4)	0.050 (4)	0.043 (4)	0.011 (3)	0.010 (3)	0.015 (3)
C15	0.057 (5)	0.057 (4)	0.036 (4)	0.008 (4)	0.009 (3)	0.019 (3)
C16	0.045 (4)	0.053 (4)	0.042 (4)	0.012 (4)	0.019 (3)	0.017 (3)
C17	0.038 (4)	0.041 (3)	0.032 (3)	0.006 (3)	0.013 (3)	0.014 (3)
Pt2	0.02815 (17)	0.03542 (16)	0.03201 (16)	0.00603 (11)	0.01136 (12)	0.01006 (11)
S3	0.0646 (13)	0.0493 (10)	0.0361 (9)	0.0065 (9)	0.0116 (9)	0.0192 (8)
S4	0.0844 (16)	0.0482 (10)	0.0480 (10)	0.0291 (10)	0.0350 (11)	0.0195 (8)
N4	0.043 (3)	0.038 (3)	0.035 (3)	0.005 (3)	0.016 (3)	0.011 (2)
N5	0.030 (3)	0.033 (3)	0.034 (3)	0.005 (2)	0.012 (2)	0.006 (2)
N6	0.035 (3)	0.034 (3)	0.042 (3)	0.002 (2)	0.018 (3)	0.007 (2)
C18	0.043 (4)	0.050 (4)	0.035 (3)	0.004 (3)	0.009 (3)	0.016 (3)
C19	0.024 (4)	0.075 (6)	0.066 (5)	0.007 (4)	0.014 (4)	0.027 (5)
C20	0.063 (6)	0.051 (5)	0.079 (6)	0.014 (4)	0.031 (5)	0.031 (4)
C21	0.041 (4)	0.037 (3)	0.032 (3)	0.005 (3)	0.006 (3)	0.012 (3)
C22	0.048 (4)	0.060 (5)	0.032 (3)	0.003 (4)	0.013 (3)	0.011 (3)
C23	0.048 (4)	0.055 (4)	0.032 (3)	0.012 (4)	0.019 (3)	0.011 (3)
C24	0.101 (8)	0.048 (4)	0.058 (5)	0.030 (5)	0.031 (5)	0.016 (4)
C25	0.038 (4)	0.043 (3)	0.035 (3)	0.009 (3)	0.019 (3)	0.008 (3)
C26	0.044 (4)	0.048 (4)	0.044 (4)	0.019 (3)	0.022 (3)	0.018 (3)
C27	0.034 (4)	0.054 (4)	0.053 (4)	0.013 (3)	0.020 (3)	0.018 (4)
C28	0.037 (4)	0.042 (4)	0.042 (4)	0.003 (3)	0.014 (3)	0.008 (3)
C29	0.034 (4)	0.034 (3)	0.035 (3)	0.006 (3)	0.013 (3)	0.011 (3)
C30	0.035 (4)	0.031 (3)	0.050 (4)	0.005 (3)	0.022 (3)	0.008 (3)
C31	0.049 (4)	0.042 (4)	0.040 (4)	−0.006 (3)	0.018 (3)	−0.004 (3)
C32	0.076 (6)	0.043 (4)	0.047 (4)	−0.007 (4)	0.026 (4)	−0.006 (4)
C33	0.073 (6)	0.041 (4)	0.056 (5)	0.003 (4)	0.041 (5)	0.002 (4)
C34	0.055 (5)	0.038 (3)	0.050 (4)	0.004 (3)	0.033 (4)	0.000 (3)
F1	0.163 (7)	0.105 (5)	0.092 (5)	0.085 (5)	0.076 (5)	0.056 (4)
F2	0.065 (3)	0.108 (4)	0.048 (3)	0.014 (3)	0.035 (2)	0.019 (3)
F3	0.066 (3)	0.085 (4)	0.057 (3)	0.005 (3)	0.010 (3)	0.013 (3)
F4	0.042 (3)	0.117 (4)	0.039 (2)	0.019 (3)	0.019 (2)	0.026 (3)
B1	0.048 (5)	0.060 (5)	0.043 (4)	0.017 (4)	0.022 (4)	0.018 (4)
F5	0.067 (3)	0.152 (6)	0.063 (3)	0.034 (4)	0.040 (3)	0.036 (4)
F6	0.058 (3)	0.091 (4)	0.049 (3)	0.033 (3)	0.009 (2)	0.022 (3)
F7	0.059 (3)	0.075 (3)	0.078 (4)	0.011 (3)	0.018 (3)	−0.024 (3)
F8	0.080 (4)	0.085 (4)	0.096 (4)	0.027 (3)	0.030 (4)	0.048 (4)
B2	0.048 (5)	0.053 (5)	0.041 (4)	0.019 (4)	0.017 (4)	0.021 (4)

Pt1—C1	2.062 (8)	Pt2—N5	2.146 (6)
Pt1—C2	2.060 (7)	Pt2—N6	2.174 (5)
Pt1—C3	2.060 (6)	S3—C21	1.760 (7)
Pt1—N1	2.222 (5)	S3—C22	1.809 (9)
Pt1—N2	2.166 (6)	S4—C21	1.738 (7)
Pt1—N3	2.176 (5)	S4—C24	1.799 (9)
S1—C4	1.755 (6)	N4—C21	1.269 (10)
S1—C5	1.811 (8)	N4—C23	1.483 (8)
S2—C4	1.740 (6)	N5—C25	1.346 (8)
S2—C7	1.800 (7)	N5—C29	1.358 (9)
N1—C4	1.264 (8)	N6—C34	1.346 (9)
N1—C6	1.493 (8)	N6—C30	1.368 (9)
N2—C12	1.344 (9)	C18—H18A	0.9800
N2—C8	1.345 (8)	C18—H18B	0.9800
N3—C13	1.310 (9)	C18—H18C	0.9800
N3—C17	1.332 (8)	C19—H19A	0.9800
C1—H1A	0.9800	C19—H19B	0.9800
C1—H1B	0.9800	C19—H19C	0.9800
C1—H1C	0.9800	C20—H20A	0.9800
C2—H2A	0.9800	C20—H20B	0.9800
C2—H2B	0.9800	C20—H20C	0.9800
C2—H2C	0.9800	C22—C23	1.489 (11)
C3—H3A	0.9800	C22—H22A	0.9900
C3—H3B	0.9800	C22—H22B	0.9900
C3—H3C	0.9800	C23—H23A	0.9900
C5—C6	1.512 (10)	C23—H23B	0.9900
C5—H5A	0.9900	C24—H24A	0.9800
C5—H5B	0.9900	C24—H24B	0.9800
C6—H6A	0.9900	C24—H24C	0.9800
C6—H6B	0.9900	C25—C26	1.370 (10)
C7—H7A	0.9800	C25—H25A	0.9500
C7—H7B	0.9800	C26—C27	1.383 (11)
C7—H7C	0.9800	C26—H26A	0.9500
C8—C9	1.374 (10)	C27—C28	1.385 (10)
C8—H8A	0.9500	C27—H27A	0.9500
C9—C10	1.374 (11)	C28—C29	1.369 (10)
C9—H9A	0.9500	C28—H28A	0.9500
C10—C11	1.376 (10)	C29—C30	1.480 (9)
C10—H10A	0.9500	C30—C31	1.373 (10)
C11—C12	1.395 (10)	C31—C32	1.391 (11)
C11—H11A	0.9500	C31—H31A	0.9500
C12—C13	1.489 (8)	C32—C33	1.375 (14)
C13—C14	1.400 (10)	C32—H32A	0.9500
C14—C15	1.376 (10)	C33—C34	1.366 (11)
C14—H14A	0.9500	C33—H33A	0.9500
C15—C16	1.360 (12)	C34—H34A	0.9500
C15—H15A	0.9500	F1—B1	1.391 (12)
C16—C17	1.380 (11)	F2—B1	1.356 (10)
C16—H16A	0.9500	F3—B1	1.403 (11)
C17—H17A	0.9500	F4—B1	1.370 (10)
Pt2—C18	2.061 (7)	F5—B2	1.342 (10)
Pt2—C19	2.048 (8)	F6—B2	1.379 (11)
Pt2—C20	2.055 (9)	F7—B2	1.360 (10)
Pt2—N4	2.245 (6)	F8—B2	1.401 (11)
C3—Pt1—C2	88.8 (3)	C19—Pt2—N6	99.8 (3)
C3—Pt1—C1	87.6 (3)	C20—Pt2—N6	92.9 (3)
C2—Pt1—C1	85.0 (3)	C18—Pt2—N6	176.0 (3)
C3—Pt1—N2	86.5 (2)	N5—Pt2—N6	76.4 (2)
C2—Pt1—N2	172.1 (3)	C19—Pt2—N4	91.2 (3)
C1—Pt1—N2	101.1 (3)	C20—Pt2—N4	177.3 (3)
C3—Pt1—N3	91.6 (3)	C18—Pt2—N4	93.7 (3)
C2—Pt1—N3	97.6 (3)	N5—Pt2—N4	92.1 (2)
C1—Pt1—N3	177.3 (2)	N6—Pt2—N4	85.0 (2)
N2—Pt1—N3	76.2 (2)	C21—S3—C22	89.1 (4)
C3—Pt1—N1	178.7 (2)	C21—S4—C24	103.3 (4)
C2—Pt1—N1	91.1 (3)	C21—N4—C23	112.4 (6)
C1—Pt1—N1	93.7 (3)	C21—N4—Pt2	130.6 (5)
N2—Pt1—N1	93.46 (19)	C23—N4—Pt2	117.0 (5)
N3—Pt1—N1	87.1 (2)	C25—N5—C29	119.0 (6)
C4—S1—C5	89.9 (3)	C25—N5—Pt2	125.0 (5)
C4—S2—C7	104.4 (3)	C29—N5—Pt2	115.9 (4)
C4—N1—C6	111.8 (5)	C34—N6—C30	118.5 (6)
C4—N1—Pt1	128.6 (4)	C34—N6—Pt2	126.7 (5)
C6—N1—Pt1	118.6 (4)	C30—N6—Pt2	114.2 (4)
C12—N2—C8	118.6 (6)	Pt2—C18—H18A	109.5
C12—N2—Pt1	115.2 (4)	Pt2—C18—H18B	109.5
C8—N2—Pt1	125.8 (5)	H18A—C18—H18B	109.5
C13—N3—C17	120.7 (6)	Pt2—C18—H18C	109.5
C13—N3—Pt1	114.5 (4)	H18A—C18—H18C	109.5
C17—N3—Pt1	124.2 (5)	H18B—C18—H18C	109.5
Pt1—C1—H1A	109.5	Pt2—C19—H19A	109.5
Pt1—C1—H1B	109.5	Pt2—C19—H19B	109.5
H1A—C1—H1B	109.5	H19A—C19—H19B	109.5
Pt1—C1—H1C	109.5	Pt2—C19—H19C	109.5
H1A—C1—H1C	109.5	H19A—C19—H19C	109.5
H1B—C1—H1C	109.5	H19B—C19—H19C	109.5
Pt1—C2—H2A	109.5	Pt2—C20—H20A	109.5
Pt1—C2—H2B	109.5	Pt2—C20—H20B	109.5
H2A—C2—H2B	109.5	H20A—C20—H20B	109.5
Pt1—C2—H2C	109.5	Pt2—C20—H20C	109.5
H2A—C2—H2C	109.5	H20A—C20—H20C	109.5
H2B—C2—H2C	109.5	H20B—C20—H20C	109.5
Pt1—C3—H3A	109.5	N4—C21—S4	122.7 (5)
Pt1—C3—H3B	109.5	N4—C21—S3	117.1 (5)
H3A—C3—H3B	109.5	S4—C21—S3	120.2 (4)
Pt1—C3—H3C	109.5	C23—C22—S3	106.2 (5)
H3A—C3—H3C	109.5	C23—C22—H22A	110.5
H3B—C3—H3C	109.5	S3—C22—H22A	110.5
N1—C4—S2	122.6 (5)	C23—C22—H22B	110.5
N1—C4—S1	117.6 (5)	S3—C22—H22B	110.5
S2—C4—S1	119.8 (4)	H22A—C22—H22B	108.7
C6—C5—S1	105.1 (5)	N4—C23—C22	109.0 (6)
C6—C5—H5A	110.7	N4—C23—H23A	109.9
S1—C5—H5A	110.7	C22—C23—H23A	109.9
C6—C5—H5B	110.7	N4—C23—H23B	109.9
S1—C5—H5B	110.7	C22—C23—H23B	109.9
H5A—C5—H5B	108.8	H23A—C23—H23B	108.3
N1—C6—C5	108.9 (6)	S4—C24—H24A	109.5
N1—C6—H6A	109.9	S4—C24—H24B	109.5
C5—C6—H6A	109.9	H24A—C24—H24B	109.5
N1—C6—H6B	109.9	S4—C24—H24C	109.5
C5—C6—H6B	109.9	H24A—C24—H24C	109.5
H6A—C6—H6B	108.3	H24B—C24—H24C	109.5
S2—C7—H7A	109.5	N5—C25—C26	121.9 (6)
S2—C7—H7B	109.5	N5—C25—H25A	119.1
H7A—C7—H7B	109.5	C26—C25—H25A	119.1
S2—C7—H7C	109.5	C25—C26—C27	119.2 (6)
H7A—C7—H7C	109.5	C25—C26—H26A	120.4
H7B—C7—H7C	109.5	C27—C26—H26A	120.4
N2—C8—C9	122.3 (7)	C26—C27—C28	119.0 (7)
N2—C8—H8A	118.8	C26—C27—H27A	120.5
C9—C8—H8A	118.8	C28—C27—H27A	120.5
C8—C9—C10	119.3 (6)	C29—C28—C27	119.4 (6)
C8—C9—H9A	120.3	C29—C28—H28A	120.3
C10—C9—H9A	120.3	C27—C28—H28A	120.3
C9—C10—C11	119.2 (7)	N5—C29—C28	121.4 (6)
C9—C10—H10A	120.4	N5—C29—C30	116.0 (6)
C11—C10—H10A	120.4	C28—C29—C30	122.4 (6)
C10—C11—C12	119.0 (8)	C31—C30—N6	120.5 (6)
C10—C11—H11A	120.5	C31—C30—C29	123.9 (7)
C12—C11—H11A	120.5	N6—C30—C29	115.6 (6)
N2—C12—C11	121.5 (6)	C30—C31—C32	120.6 (8)
N2—C12—C13	115.2 (6)	C30—C31—H31A	119.7
C11—C12—C13	123.2 (7)	C32—C31—H31A	119.7
N3—C13—C14	120.7 (6)	C33—C32—C31	117.7 (7)
N3—C13—C12	117.6 (6)	C33—C32—H32A	121.1
C14—C13—C12	121.7 (6)	C31—C32—H32A	121.1
C15—C14—C13	118.4 (7)	C34—C33—C32	120.2 (7)
C15—C14—H14A	120.8	C34—C33—H33A	119.9
C13—C14—H14A	120.8	C32—C33—H33A	119.9
C16—C15—C14	120.1 (7)	N6—C34—C33	122.3 (8)
C16—C15—H15A	119.9	N6—C34—H34A	118.8
C14—C15—H15A	119.9	C33—C34—H34A	118.8
C15—C16—C17	118.4 (7)	F2—B1—F4	110.8 (8)
C15—C16—H16A	120.8	F2—B1—F1	112.5 (8)
C17—C16—H16A	120.8	F4—B1—F1	110.1 (7)
N3—C17—C16	121.6 (7)	F2—B1—F3	108.5 (7)
N3—C17—H17A	119.2	F4—B1—F3	109.2 (7)
C16—C17—H17A	119.2	F1—B1—F3	105.6 (8)
C19—Pt2—C20	87.6 (4)	F5—B2—F7	112.4 (8)
C19—Pt2—C18	84.0 (4)	F5—B2—F6	112.9 (7)
C20—Pt2—C18	88.5 (3)	F7—B2—F6	109.1 (8)
C19—Pt2—N5	174.7 (3)	F5—B2—F8	110.3 (8)
C20—Pt2—N5	89.0 (3)	F7—B2—F8	104.9 (7)
C18—Pt2—N5	99.9 (3)	F6—B2—F8	106.7 (7)

D—H···A	D—H	H···A	D···A	D—H···A
C7—H7C···F8	0.98	2.45	3.383 (11)	158
C9—H9A···F1i	0.95	2.44	3.192 (10)	136
C16—H16A···F6ii	0.95	2.44	3.114 (9)	128
C17—H17A···F7ii	0.95	2.39	3.190 (9)	142
C28—H28A···F2iii	0.95	2.53	3.322 (10)	141
C32—H32A···F8iv	0.95	2.55	3.497 (11)	173
C34—H34A···F4	0.95	2.43	3.178 (8)	136

Table 1

Selected bond lengths (Å)

Pt1—C1	2.062 (8)
Pt1—C2	2.060 (7)
Pt1—C3	2.060 (6)
Pt1—N1	2.222 (5)
Pt1—N2	2.166 (6)
Pt1—N3	2.176 (5)
Pt2—C18	2.061 (7)
Pt2—C19	2.048 (8)
Pt2—C20	2.055 (9)
Pt2—N4	2.245 (6)
Pt2—N5	2.146 (6)
Pt2—N6	2.174 (5)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C7—H7C⋯F8	0.98	2.45	3.383 (11)	158
C9—H9A⋯F1i	0.95	2.44	3.192 (10)	136
C16—H16A⋯F6ii	0.95	2.44	3.114 (9)	128
C17—H17A⋯F7ii	0.95	2.39	3.190 (9)	142
C28—H28A⋯F2iii	0.95	2.53	3.322 (10)	141
C32—H32A⋯F8iv	0.95	2.55	3.497 (11)	173
C34—H34A⋯F4	0.95	2.43	3.178 (8)	136

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .