Chlorido[hydridotris(pyrazol-1-yl-κN)borato](1H-pyrazole-κN)(triphenyl-phosphine-κP)ruthenium(II).

In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N',N''-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol-ecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN(4) octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547 (10):0.453 (10) ratio, and a weak intra-molecular N-H⋯Cl hydrogen bond generates an S(5) ring.

Related literature

For general background to pan class="Chemical">ruthenium coordination chemistry with pan class="Chemical">pyrazole-type ligands, see: Alcock et al. (1992 ▶); Cheng et al. (2009 ▶); Deacon et al. (1998 ▶); Govind et al. (1996 ▶); Lo et al. (2004 ▶); Pavlik et al. (2005 ▶). For related structures, see: Gemel et al. (1996 ▶); Slugovc et al. (1998 ▶). Tong et al. (2008 ▶, 2009 ▶).

Experimental

Crystal data

[Ru(C9H10BN6)Cl(C3H4N2)(C18H15P)]

M = 679.91

Monoclinic,

a = 17.7782 (12) Å

b = 10.0843 (5) Å

c = 18.9139 (10) Å

β = 116.316 (3)°

V = 3039.5 (3) Å3

Z = 4

Mo Kα radiation

μ = 0.69 mm−1

T = 200 K

0.11 × 0.08 × 0.03 mm

Data collection

Nonius KappaCCD diffractometer

Absorption correction: multi-scan (SORTAV; Blessing, 1995 ▶) T min = 0.928, T max = 0.980

22639 measured reflections

5292 independent reflections

3470 reflections with I > 2σ(I)

R int = 0.079

Refinement

R[F 2 > 2σ(F 2)] = 0.053

wR(F 2) = 0.118

S = 1.02

5292 reflections

360 parameters

H-atom parameters constrained

Δρmax = 0.89 e Å−3

Δρmin = −0.88 e Å−3

Data collection: COLLECT (Nonius, 1999 ▶); cell refinement: DENZO and SCALEPACK (Otwinowski & Minor, 1997 ▶); data reduction: DENZO and SCALEPACK; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810021525/pan class="CellLine">hb5462supn>1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810021525/pan class="CellLine">hb5462Isupn>2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ru(C9H10BN6)Cl(C3H4N2)(C18H15P)]	Z = 4
Mr = 679.91	F(000) = 1384
Monoclinic, P21/c	Dx = 1.486 Mg m−3
Hall symbol: -P 2ybc	Mo Kα radiation, λ = 0.71073 Å
a = 17.7782 (12) Å	µ = 0.69 mm−1
b = 10.0843 (5) Å	T = 200 K
c = 18.9139 (10) Å	Prism, yellow
β = 116.316 (3)°	0.11 × 0.08 × 0.03 mm
V = 3039.5 (3) Å3

Nonius KappaCCD diffractometer	5292 independent reflections
Radiation source: fine-focus sealed tube	3470 reflections with I > 2σ(I)
graphite	Rint = 0.079
Detector resolution: 9 pixels mm-1	θmax = 25.0°, θmin = 2.4°
CCD rotation images, thick slices scans	h = −21→21
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	k = −11→12
Tmin = 0.928, Tmax = 0.980	l = −22→21
22639 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.053	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.118	H-atom parameters constrained
S = 1.02	w = 1/[σ2(Fo2) + (0.0431P)2 + 4.7477P] where P = (Fo2 + 2Fc2)/3
5292 reflections	(Δ/σ)max = 0.001
360 parameters	Δρmax = 0.89 e Å−3
0 restraints	Δρmin = −0.88 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2902 (4)	0.3286 (6)	0.1960 (4)	0.0463 (16)
H1	0.2738	0.2987	0.1436	0.056*
C2	0.2953 (4)	0.4609 (6)	0.2186 (4)	0.0555 (18)
H2	0.2837	0.5370	0.1858	0.067*
C3	0.3205 (4)	0.4581 (6)	0.2979 (4)	0.0474 (17)
H3	0.3290	0.5333	0.3309	0.057*
C4	0.5121 (3)	0.0343 (6)	0.4007 (4)	0.0404 (15)
H4	0.5261	−0.0394	0.3776	0.048*
C5	0.5677 (4)	0.0987 (7)	0.4686 (4)	0.0539 (18)
H5	0.6255	0.0793	0.4997	0.065*
C6	0.5218 (4)	0.1956 (6)	0.4810 (4)	0.0480 (17)
H6	0.5419	0.2566	0.5238	0.058*
C7	0.2128 (4)	0.0109 (6)	0.3727 (4)	0.0402 (15)
H7	0.1830	−0.0666	0.3468	0.048*
C8	0.2055 (4)	0.0742 (7)	0.4345 (4)	0.0562 (19)
H8	0.1701	0.0498	0.4580	0.067*
C9	0.2593 (4)	0.1778 (7)	0.4543 (4)	0.057 (2)
H9	0.2689	0.2395	0.4954	0.069*
C10	0.4314 (4)	0.1132 (7)	0.1913 (4)	0.0540 (18)
H10	0.4311	0.2064	0.1983	0.065*
C11	0.4754 (5)	0.0497 (8)	0.1565 (4)	0.073 (2)
H11	0.5096	0.0890	0.1354	0.087*
C12	0.4589 (5)	−0.0808 (8)	0.1592 (4)	0.069 (2)
H12	0.4799	−0.1519	0.1401	0.082*
C13	0.1166 (4)	−0.1063 (6)	0.1829 (3)	0.0387 (15)
C14	0.1434 (4)	−0.2266 (6)	0.2193 (5)	0.068 (2)
H14	0.2008	−0.2507	0.2383	0.082*
C15	0.0875 (6)	−0.3145 (8)	0.2288 (5)	0.097 (2)
H15	0.1071	−0.3971	0.2545	0.116*
C16	0.0059 (6)	−0.2816 (8)	0.2013 (4)	0.0853 (19)
H16	−0.0322	−0.3420	0.2069	0.102*
C17	−0.0222 (5)	−0.1622 (7)	0.1657 (4)	0.0608 (14)
H17	−0.0796	−0.1390	0.1474	0.073*
C18	0.0328 (4)	−0.0738 (6)	0.1559 (3)	0.0448 (16)
H18	0.0126	0.0090	0.1307	0.054*
C19	0.1261 (3)	0.1512 (5)	0.1297 (3)	0.0377 (15)
C20	0.1150 (3)	0.2350 (5)	0.1821 (4)	0.0389 (15)
H20	0.1442	0.2181	0.2371	0.047*
C21	0.0622 (4)	0.3428 (7)	0.1557 (4)	0.0608 (14)
H21	0.0536	0.3977	0.1923	0.073*
C22	0.0221 (6)	0.3709 (8)	0.0766 (5)	0.0853 (19)
H22	−0.0124	0.4473	0.0582	0.102*
C23	0.0325 (6)	0.2860 (8)	0.0239 (5)	0.097 (2)
H23	0.0037	0.3030	−0.0311	0.116*
C24	0.0842 (5)	0.1779 (7)	0.0509 (4)	0.078 (3)
H24	0.0909	0.1206	0.0142	0.094*
C25	0.2000 (3)	−0.0681 (5)	0.0859 (3)	0.0391 (15)
C26	0.2011 (7)	−0.2090 (10)	0.0842 (7)	0.039 (3)*	0.547 (10)
H26	0.1893	−0.2624	0.1194	0.047*	0.547 (10)
C27	0.2208 (7)	−0.2625 (12)	0.0263 (7)	0.052 (4)*	0.547 (10)
H27	0.2197	−0.3561	0.0204	0.063*	0.547 (10)
C28	0.2412 (8)	−0.1881 (13)	−0.0209 (9)	0.048 (3)*	0.547 (10)
H28	0.2497	−0.2303	−0.0617	0.058*	0.547 (10)
C26'	0.1488 (9)	−0.1639 (13)	0.0340 (8)	0.045 (4)*	0.453 (10)
H26'	0.1061	−0.2001	0.0454	0.054*	0.453 (10)
C27'	0.1535 (10)	−0.2134 (15)	−0.0340 (9)	0.060 (5)*	0.453 (10)
H27'	0.1188	−0.2849	−0.0632	0.072*	0.453 (10)
C28'	0.2087 (10)	−0.1562 (15)	−0.0564 (10)	0.048 (4)*	0.453 (10)
H28'	0.2167	−0.1872	−0.1000	0.057*	0.453 (10)
C29	0.2503 (5)	−0.0547 (7)	−0.0130 (4)	0.063 (2)
H29	0.2658	−0.0021	−0.0462	0.076*
C30	0.2354 (6)	−0.0005 (7)	0.0473 (4)	0.075 (3)
H30	0.2511	0.0891	0.0619	0.090*
N1	0.3114 (3)	0.2499 (4)	0.2585 (3)	0.0316 (11)
N2	0.3313 (3)	0.3310 (4)	0.3217 (3)	0.0337 (11)
N3	0.4364 (3)	0.0895 (4)	0.3725 (2)	0.0281 (10)
N4	0.4429 (3)	0.1907 (4)	0.4224 (3)	0.0334 (11)
N5	0.2680 (3)	0.0749 (4)	0.3548 (3)	0.0303 (11)
N6	0.2968 (3)	0.1791 (4)	0.4062 (3)	0.0389 (12)
N7	0.3897 (3)	0.0274 (4)	0.2138 (3)	0.0367 (12)
N8	0.4080 (3)	−0.0912 (5)	0.1936 (3)	0.0476 (14)
H8'	0.3887	−0.1669	0.2020	0.057*
B1	0.3644 (4)	0.2722 (6)	0.4052 (4)	0.0397 (18)
H1'	0.3771	0.3442	0.4452	0.048*
Cl1	0.34907 (9)	−0.18597 (13)	0.31246 (9)	0.0368 (4)
Ru1	0.32023 (3)	0.04732 (4)	0.27709 (3)	0.02453 (15)
P1	0.19260 (9)	0.00460 (14)	0.17152 (9)	0.0329 (4)

	U11	U22	U33	U12	U13	U23
C1	0.055 (4)	0.032 (4)	0.040 (4)	−0.002 (3)	0.010 (3)	0.011 (3)
C2	0.067 (5)	0.027 (4)	0.059 (5)	−0.006 (3)	0.016 (4)	0.020 (3)
C3	0.052 (4)	0.020 (3)	0.071 (5)	−0.007 (3)	0.028 (4)	−0.001 (3)
C4	0.034 (3)	0.037 (4)	0.045 (4)	0.003 (3)	0.013 (3)	0.005 (3)
C5	0.032 (4)	0.059 (4)	0.043 (4)	−0.006 (3)	−0.008 (3)	0.014 (4)
C6	0.052 (4)	0.047 (4)	0.026 (4)	−0.023 (4)	0.000 (3)	0.000 (3)
C7	0.032 (3)	0.034 (3)	0.052 (4)	−0.001 (3)	0.016 (3)	0.013 (3)
C8	0.055 (4)	0.063 (5)	0.072 (5)	−0.004 (4)	0.047 (4)	0.002 (4)
C9	0.078 (5)	0.054 (4)	0.068 (5)	0.003 (4)	0.058 (5)	−0.004 (4)
C10	0.064 (5)	0.061 (4)	0.049 (4)	−0.017 (4)	0.037 (4)	−0.001 (4)
C11	0.088 (6)	0.087 (6)	0.074 (6)	−0.008 (5)	0.063 (5)	0.003 (5)
C12	0.078 (6)	0.086 (6)	0.066 (5)	0.010 (5)	0.053 (5)	−0.008 (4)
C13	0.034 (3)	0.033 (3)	0.036 (4)	−0.007 (3)	0.004 (3)	−0.009 (3)
C14	0.049 (4)	0.028 (4)	0.108 (7)	−0.025 (3)	0.017 (4)	0.005 (4)
C15	0.128 (6)	0.072 (4)	0.048 (4)	0.049 (4)	0.001 (4)	0.007 (3)
C16	0.123 (5)	0.068 (4)	0.054 (4)	0.031 (4)	0.030 (4)	−0.003 (3)
C17	0.058 (3)	0.076 (4)	0.051 (3)	0.016 (3)	0.026 (3)	−0.006 (3)
C18	0.043 (4)	0.054 (4)	0.036 (4)	−0.006 (3)	0.016 (3)	−0.002 (3)
C19	0.038 (3)	0.030 (3)	0.028 (4)	0.009 (3)	−0.001 (3)	−0.005 (3)
C20	0.034 (3)	0.036 (3)	0.032 (4)	0.010 (3)	0.002 (3)	0.002 (3)
C21	0.058 (3)	0.076 (4)	0.051 (3)	0.016 (3)	0.026 (3)	−0.006 (3)
C22	0.123 (5)	0.068 (4)	0.054 (4)	0.031 (4)	0.030 (4)	−0.003 (3)
C23	0.128 (6)	0.072 (4)	0.048 (4)	0.049 (4)	0.001 (4)	0.007 (3)
C24	0.101 (6)	0.070 (5)	0.032 (4)	0.056 (5)	0.002 (4)	0.000 (4)
C25	0.030 (3)	0.031 (3)	0.045 (4)	0.001 (3)	0.007 (3)	−0.013 (3)
C29	0.087 (5)	0.061 (5)	0.040 (4)	−0.017 (4)	0.026 (4)	−0.003 (4)
C30	0.151 (8)	0.044 (4)	0.032 (4)	−0.041 (5)	0.043 (5)	−0.017 (3)
N1	0.039 (3)	0.017 (2)	0.033 (3)	−0.002 (2)	0.011 (3)	0.001 (2)
N2	0.038 (3)	0.018 (3)	0.043 (3)	−0.005 (2)	0.017 (3)	−0.003 (2)
N3	0.026 (3)	0.029 (3)	0.024 (3)	−0.001 (2)	0.008 (2)	0.000 (2)
N4	0.041 (3)	0.033 (3)	0.021 (3)	−0.009 (2)	0.008 (2)	−0.003 (2)
N5	0.030 (3)	0.025 (3)	0.034 (3)	0.002 (2)	0.012 (2)	0.001 (2)
N6	0.049 (3)	0.033 (3)	0.044 (3)	−0.001 (2)	0.029 (3)	−0.005 (2)
N7	0.042 (3)	0.035 (3)	0.037 (3)	0.001 (2)	0.021 (3)	−0.006 (2)
N8	0.058 (4)	0.044 (3)	0.052 (4)	0.001 (3)	0.034 (3)	−0.010 (3)
B1	0.049 (5)	0.029 (4)	0.045 (5)	−0.006 (3)	0.025 (4)	−0.008 (3)
Cl1	0.0399 (8)	0.0218 (7)	0.0420 (9)	0.0043 (6)	0.0120 (7)	0.0027 (6)
Ru1	0.0258 (2)	0.0193 (2)	0.0246 (3)	−0.0007 (2)	0.00759 (19)	0.0001 (2)
P1	0.0322 (9)	0.0231 (8)	0.0321 (9)	0.0004 (6)	0.0039 (7)	−0.0036 (6)

C1—N1	1.332 (7)	C20—C21	1.377 (8)
C1—C2	1.392 (8)	C20—H20	0.9500
C1—H1	0.9500	C21—C22	1.371 (9)
C2—C3	1.363 (9)	C21—H21	0.9500
C2—H2	0.9500	C22—C23	1.387 (10)
C3—N2	1.343 (7)	C22—H22	0.9500
C3—H3	0.9500	C23—C24	1.370 (9)
C4—N3	1.329 (6)	C23—H23	0.9500
C4—C5	1.387 (8)	C24—H24	0.9500
C4—H4	0.9500	C25—C30	1.341 (8)
C5—C6	1.359 (9)	C25—C26'	1.390 (14)
C5—H5	0.9500	C25—C26	1.422 (11)
C6—N4	1.350 (7)	C25—P1	1.835 (6)
C6—H6	0.9500	C26—C27	1.396 (14)
C7—N5	1.337 (6)	C26—H26	0.9500
C7—C8	1.387 (8)	C27—C28	1.334 (15)
C7—H7	0.9500	C27—H27	0.9500
C8—C9	1.352 (9)	C28—C29	1.355 (14)
C8—H8	0.9500	C28—H28	0.9500
C9—N6	1.346 (7)	C26'—C27'	1.416 (18)
C9—H9	0.9500	C26'—H26'	0.9500
C10—N7	1.326 (7)	C27'—C28'	1.358 (19)
C10—C11	1.382 (9)	C27'—H27'	0.9500
C10—H10	0.9500	C28'—C29	1.316 (16)
C11—C12	1.354 (9)	C28'—H28'	0.9500
C11—H11	0.9500	C29—C30	1.392 (9)
C12—N8	1.332 (7)	C29—H29	0.9500
C12—H12	0.9500	C30—H30	0.9500
C13—C14	1.371 (8)	N1—N2	1.359 (6)
C13—C18	1.384 (8)	N2—B1	1.539 (8)
C13—P1	1.838 (6)	N3—N4	1.361 (6)
C14—C15	1.402 (11)	N4—B1	1.524 (8)
C14—H14	0.9500	N5—N6	1.367 (6)
C15—C16	1.347 (11)	N6—B1	1.531 (8)
C15—H15	0.9500	N7—N8	1.339 (6)
C16—C17	1.362 (9)	N8—H8'	0.8800
C16—H16	0.9500	B1—H1'	1.0000
C17—C18	1.394 (8)	Ru1—N1	2.067 (4)
C17—H17	0.9500	Ru1—N3	2.097 (4)
C18—H18	0.9500	Ru1—N5	2.076 (4)
C19—C24	1.365 (8)	Ru1—N7	2.076 (4)
C19—C20	1.382 (7)	Ru1—P1	2.3031 (15)
C19—P1	1.839 (5)	Ru1—Cl1	2.4374 (14)
N1—C1—C2	110.2 (6)	C27—C26—C25	114.5 (9)
N1—C1—H1	124.9	C27—C26—H26	122.8
C2—C1—H1	124.9	C25—C26—H26	122.8
C3—C2—C1	105.2 (5)	C28—C27—C26	123.0 (12)
C3—C2—H2	127.4	C28—C27—H27	118.5
C1—C2—H2	127.4	C26—C27—H27	118.5
N2—C3—C2	108.5 (5)	C27—C28—C29	122.6 (12)
N2—C3—H3	125.8	C27—C28—H28	118.7
C2—C3—H3	125.8	C29—C28—H28	118.7
N3—C4—C5	110.8 (6)	C25—C26'—C27'	127.1 (12)
N3—C4—H4	124.6	C25—C26'—H26'	116.5
C5—C4—H4	124.6	C27'—C26'—H26'	116.5
C6—C5—C4	105.1 (6)	C28'—C27'—C26'	118.4 (15)
C6—C5—H5	127.5	C28'—C27'—H27'	120.8
C4—C5—H5	127.5	C26'—C27'—H27'	120.8
N4—C6—C5	108.5 (5)	C29—C28'—C27'	114.9 (13)
N4—C6—H6	125.8	C29—C28'—H28'	122.6
C5—C6—H6	125.8	C27'—C28'—H28'	122.6
N5—C7—C8	110.1 (5)	C28'—C29—C28	32.0 (7)
N5—C7—H7	124.9	C28'—C29—C30	123.9 (9)
C8—C7—H7	124.9	C28—C29—C30	115.0 (8)
C9—C8—C7	105.7 (5)	C28'—C29—H29	105.7
C9—C8—H8	127.1	C28—C29—H29	122.5
C7—C8—H8	127.1	C30—C29—H29	122.5
N6—C9—C8	108.8 (6)	C25—C30—C29	123.5 (6)
N6—C9—H9	125.6	C25—C30—H30	118.2
C8—C9—H9	125.6	C29—C30—H30	118.2
N7—C10—C11	111.4 (6)	C1—N1—N2	106.4 (4)
N7—C10—H10	124.3	C1—N1—Ru1	135.2 (4)
C11—C10—H10	124.3	N2—N1—Ru1	118.4 (3)
C12—C11—C10	104.8 (6)	C3—N2—N1	109.7 (5)
C12—C11—H11	127.6	C3—N2—B1	130.1 (5)
C10—C11—H11	127.6	N1—N2—B1	120.1 (4)
N8—C12—C11	107.4 (6)	C4—N3—N4	106.0 (5)
N8—C12—H12	126.3	C4—N3—Ru1	134.1 (4)
C11—C12—H12	126.3	N4—N3—Ru1	119.8 (3)
C14—C13—C18	118.2 (6)	C6—N4—N3	109.6 (5)
C14—C13—P1	119.2 (5)	C6—N4—B1	132.5 (5)
C18—C13—P1	122.7 (5)	N3—N4—B1	117.9 (5)
C13—C14—C15	121.0 (7)	C7—N5—N6	106.1 (4)
C13—C14—H14	119.5	C7—N5—Ru1	136.3 (4)
C15—C14—H14	119.5	N6—N5—Ru1	117.5 (3)
C16—C15—C14	119.9 (8)	C9—N6—N5	109.3 (5)
C16—C15—H15	120.0	C9—N6—B1	129.9 (5)
C14—C15—H15	120.0	N5—N6—B1	120.7 (4)
C15—C16—C17	120.3 (9)	C10—N7—N8	104.5 (5)
C15—C16—H16	119.9	C10—N7—Ru1	133.0 (4)
C17—C16—H16	119.9	N8—N7—Ru1	122.2 (4)
C16—C17—C18	120.4 (7)	C12—N8—N7	111.9 (5)
C16—C17—H17	119.8	C12—N8—H8'	124.0
C18—C17—H17	119.8	N7—N8—H8'	124.0
C13—C18—C17	120.2 (6)	N4—B1—N6	108.4 (5)
C13—C18—H18	119.9	N4—B1—N2	108.9 (5)
C17—C18—H18	119.9	N6—B1—N2	107.7 (5)
C24—C19—C20	118.7 (5)	N4—B1—H1'	110.6
C24—C19—P1	124.3 (5)	N6—B1—H1'	110.6
C20—C19—P1	116.9 (4)	N2—B1—H1'	110.6
C21—C20—C19	120.9 (6)	N1—Ru1—N5	87.90 (16)
C21—C20—H20	119.5	N1—Ru1—N7	91.02 (17)
C19—C20—H20	119.5	N5—Ru1—N7	171.23 (18)
C22—C21—C20	119.9 (6)	N1—Ru1—N3	85.26 (17)
C22—C21—H21	120.0	N5—Ru1—N3	86.71 (17)
C20—C21—H21	120.0	N7—Ru1—N3	84.53 (17)
C21—C22—C23	119.1 (7)	N1—Ru1—P1	93.79 (13)
C21—C22—H22	120.4	N5—Ru1—P1	93.51 (13)
C23—C22—H22	120.4	N7—Ru1—P1	95.25 (13)
C24—C23—C22	120.3 (7)	N3—Ru1—P1	179.02 (12)
C24—C23—H23	119.8	N1—Ru1—Cl1	172.51 (13)
C22—C23—H23	119.8	N5—Ru1—Cl1	92.33 (12)
C19—C24—C23	120.9 (6)	N7—Ru1—Cl1	87.62 (13)
C19—C24—H24	119.5	N3—Ru1—Cl1	87.28 (12)
C23—C24—H24	119.5	P1—Ru1—Cl1	93.67 (5)
C30—C25—C26'	106.7 (7)	C25—P1—C13	101.8 (3)
C30—C25—C26	118.8 (7)	C25—P1—C19	103.0 (3)
C26'—C25—C26	45.6 (6)	C13—P1—C19	100.0 (3)
C30—C25—P1	120.8 (4)	C25—P1—Ru1	114.28 (18)
C26'—C25—P1	128.3 (7)	C13—P1—Ru1	120.32 (19)
C26—C25—P1	115.2 (6)	C19—P1—Ru1	114.91 (19)

D—H···A	D—H	H···A	D···A	D—H···A
N8—H8'···Cl1	0.88	2.49	3.025 (6)	120

Table 1

Selected bond lengths (Å)

Ru1—N1	2.067 (4)
Ru1—N3	2.097 (4)
Ru1—N5	2.076 (4)
Ru1—N7	2.076 (4)
Ru1—P1	2.3031 (15)
Ru1—Cl1	2.4374 (14)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N8—H8′⋯Cl1	0.88	2.49	3.025 (6)	120