(Benzonitrile-κN)chlorido[hydrido-tris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II) ethanol solvate.

The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo-nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron with an average N-Ru-N bite angle of the Tp ligand of 86.6 (2)°.

Related literature

For general background to the hydridotris(pyrazoly)borate anion and its use in the preparation of various transition metal complexes, see: Alcock et al. (1992 ▶); Burrows et al. (2001 ▶); Pavlik et al. (2005 ▶); Slugovc et al. (1998 ▶); Trofimenko (1993 ▶). For Ru—N distances in other hydridotripyrazolyl­borate complexes, see: Gemel et al. (1996 ▶); Slugovc et al. (1998 ▶).

Experimental

Crystal data

[Ru(C9H10BN6)Cl(C18H15P)(C7H5N)]·C2H6O

M = 761.02

Triclinic,

a = 8.0008 (5) Å

b = 11.0195 (5) Å

c = 19.4246 (11) Å

α = 83.438 (4)°

β = 88.726 (4)°

γ = 88.920 (4)°

V = 1700.70 (16) Å3

Z = 2

Mo Kα radiation

μ = 0.63 mm−1

T = 200 K

0.24 × 0.08 × 0.02 mm

Data collection

Nonius KappaCCD diffractometer

Absorption correction: multi-scan (Blessing, 1995 ▶) T min = 0.864, T max = 0.988

13842 measured reflections

5819 independent reflections

3804 reflections with I > 2σ(I)

R int = 0.080

Refinement

R[F 2 > 2σ(F 2)] = 0.056

wR(F 2) = 0.122

S = 1.04

5819 reflections

433 parameters

H-atom parameters constrained

Δρmax = 0.86 e Å−3

Δρmin = −0.89 e Å−3

Data collection: COLLECT (Nonius, 1999 ▶); cell refinement: DENZO and SCALEPACK (Otwinowski & Minor, 1997 ▶); data reduction: DENZO and SCALEPACK; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809010265/nc2139sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809010265/nc2139Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ru(C9H10BN6)Cl(C18H15P)(C7H5N)]·C2H6O	Z = 2
Mr = 761.02	F(000) = 780
Triclinic, P1	Dx = 1.486 Mg m−3
a = 8.0008 (5) Å	Mo Kα radiation, λ = 0.71073 Å
b = 11.0195 (5) Å	Cell parameters from 0 reflections
c = 19.4246 (11) Å	θ = 0–0°
α = 83.438 (4)°	µ = 0.63 mm−1
β = 88.726 (4)°	T = 200 K
γ = 88.920 (4)°	Prism, yellow
V = 1700.70 (16) Å3	0.24 × 0.08 × 0.02 mm

Nonius KappaCCD diffractometer	5819 independent reflections
Radiation source: fine-focus sealed tube	3804 reflections with I > 2σ(I)
graphite	Rint = 0.080
Detector resolution: 9 pixels mm-1	θmax = 25.0°, θmin = 1.9°
CCD rotation images, thick slices scans	h = −7→9
Absorption correction: multi-scan (Blessing, 1995)	k = −12→13
Tmin = 0.864, Tmax = 0.988	l = −21→23
13842 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.056	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.122	H-atom parameters constrained
S = 1.04	w = 1/[σ2(Fo2) + (0.0432P)2] where P = (Fo2 + 2Fc2)/3
5819 reflections	(Δ/σ)max = 0.001
433 parameters	Δρmax = 0.86 e Å−3
0 restraints	Δρmin = −0.89 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
B1	0.6437 (8)	1.1216 (6)	0.8145 (4)	0.0217 (17)
H1'	0.6412	1.1988	0.8370	0.026*
C1	0.4057 (7)	0.8541 (6)	0.8752 (3)	0.0250 (15)
H1	0.3660	0.7746	0.8709	0.030*
C2	0.3573 (8)	0.9230 (6)	0.9274 (3)	0.0307 (17)
H2	0.2812	0.9014	0.9648	0.037*
C3	0.4430 (8)	1.0291 (6)	0.9132 (3)	0.0292 (17)
H3	0.4369	1.0963	0.9399	0.035*
C4	1.0191 (7)	0.9563 (5)	0.7700 (3)	0.0235 (15)
H4	1.0754	0.8911	0.7507	0.028*
C5	1.0975 (8)	1.0535 (5)	0.7936 (3)	0.0295 (17)
H5	1.2141	1.0685	0.7933	0.035*
C6	0.9697 (8)	1.1240 (6)	0.8178 (3)	0.0298 (17)
H6	0.9830	1.1977	0.8379	0.036*
C7	0.4995 (7)	1.0900 (5)	0.6428 (3)	0.0218 (15)
H7	0.4781	1.0420	0.6064	0.026*
C8	0.4638 (7)	1.2139 (6)	0.6407 (3)	0.0305 (17)
H8	0.4164	1.2661	0.6037	0.037*
C9	0.5113 (7)	1.2444 (5)	0.7030 (3)	0.0232 (15)
H9	0.5017	1.3234	0.7179	0.028*
C10	0.8767 (7)	0.7020 (5)	0.8753 (3)	0.0194 (14)
C11	0.8356 (7)	0.7871 (5)	0.9212 (3)	0.0252 (15)
H11	0.7450	0.8428	0.9110	0.030*
C12	0.9232 (8)	0.7922 (6)	0.9807 (3)	0.0300 (17)
H12	0.8922	0.8506	1.0112	0.036*
C13	1.0560 (8)	0.7129 (6)	0.9964 (3)	0.0341 (18)
H13	1.1156	0.7152	1.0380	0.041*
C14	1.1002 (8)	0.6312 (6)	0.9513 (4)	0.0348 (18)
H14	1.1937	0.5781	0.9610	0.042*
C15	1.0116 (7)	0.6240 (6)	0.8916 (3)	0.0299 (17)
H15	1.0436	0.5651	0.8615	0.036*
C16	0.5928 (7)	0.5768 (5)	0.8399 (3)	0.0199 (14)
C17	0.6134 (8)	0.5104 (5)	0.9041 (3)	0.0295 (16)
H17	0.7035	0.5290	0.9319	0.035*
C18	0.5063 (8)	0.4179 (6)	0.9288 (4)	0.0333 (17)
H18	0.5250	0.3731	0.9728	0.040*
C19	0.3743 (8)	0.3901 (5)	0.8908 (4)	0.0314 (17)
H19	0.3001	0.3270	0.9081	0.038*
C20	0.3503 (7)	0.4553 (5)	0.8265 (4)	0.0282 (17)
H20	0.2592	0.4361	0.7994	0.034*
C21	0.4563 (7)	0.5477 (5)	0.8013 (3)	0.0247 (15)
H21	0.4367	0.5921	0.7573	0.030*
C22	0.8730 (7)	0.5888 (5)	0.7502 (3)	0.0190 (14)
C23	0.8347 (8)	0.4663 (6)	0.7473 (3)	0.0335 (17)
H23	0.7423	0.4315	0.7736	0.040*
C24	0.9301 (8)	0.3950 (6)	0.7066 (4)	0.0367 (18)
H24	0.9018	0.3121	0.7050	0.044*
C25	1.0658 (8)	0.4430 (6)	0.6682 (4)	0.0336 (18)
H25	1.1293	0.3945	0.6394	0.040*
C26	1.1067 (8)	0.5612 (6)	0.6726 (3)	0.0285 (16)
H26	1.2012	0.5948	0.6473	0.034*
C27	1.0130 (7)	0.6332 (5)	0.7133 (3)	0.0256 (16)
H27	1.0454	0.7150	0.7159	0.031*
C28	0.8440 (8)	0.8522 (5)	0.6049 (3)	0.0220 (15)
C29	0.9322 (7)	0.8466 (5)	0.5402 (3)	0.0228 (15)
C30	1.1031 (8)	0.8200 (5)	0.5399 (4)	0.0330 (17)
H30	1.1607	0.8058	0.5824	0.040*
C31	1.1880 (8)	0.8145 (6)	0.4785 (4)	0.0381 (18)
H31	1.3041	0.7947	0.4783	0.046*
C32	1.1051 (9)	0.8377 (5)	0.4170 (4)	0.0345 (18)
H32	1.1648	0.8348	0.3743	0.041*
C33	0.9364 (9)	0.8650 (6)	0.4167 (4)	0.0363 (18)
H33	0.8802	0.8816	0.3740	0.044*
C34	0.8494 (8)	0.8681 (6)	0.4786 (3)	0.0314 (17)
H34	0.7325	0.8850	0.4787	0.038*
C35	0.6349 (12)	0.5821 (7)	0.5823 (4)	0.066 (3)
H35A	0.5575	0.5189	0.6037	0.079*
H35B	0.7123	0.6024	0.6182	0.079*
C36	0.7341 (11)	0.5337 (7)	0.5223 (5)	0.077 (3)
H36A	0.7981	0.4604	0.5399	0.115*
H36B	0.8110	0.5965	0.5016	0.115*
H36C	0.6566	0.5133	0.4871	0.115*
Cl1	0.40407 (18)	0.80198 (13)	0.69429 (8)	0.0259 (4)
N1	0.5147 (6)	0.9129 (4)	0.8316 (3)	0.0187 (12)
N2	0.5372 (6)	1.0235 (4)	0.8556 (3)	0.0216 (12)
N3	0.8537 (6)	0.9662 (4)	0.7779 (2)	0.0201 (12)
N4	0.8238 (6)	1.0713 (4)	0.8082 (3)	0.0218 (12)
N5	0.5673 (5)	1.0477 (4)	0.7025 (3)	0.0185 (12)
N6	0.5746 (6)	1.1432 (4)	0.7404 (3)	0.0213 (12)
N7	0.7767 (6)	0.8556 (4)	0.6573 (3)	0.0190 (12)
O2	0.5442 (7)	0.6869 (5)	0.5561 (3)	0.0617 (16)
H2'	0.4895	0.7142	0.5886	0.092*
P1	0.74469 (19)	0.68826 (14)	0.80077 (9)	0.0189 (4)
Ru1	0.65206 (6)	0.87432 (4)	0.74538 (3)	0.01676 (16)

	U11	U22	U33	U12	U13	U23
B1	0.027 (4)	0.015 (4)	0.025 (5)	0.004 (3)	−0.004 (4)	−0.008 (3)
C1	0.022 (3)	0.027 (4)	0.026 (4)	−0.002 (3)	0.000 (3)	−0.002 (3)
C2	0.034 (4)	0.039 (4)	0.019 (4)	0.002 (3)	0.007 (3)	0.000 (3)
C3	0.031 (4)	0.040 (4)	0.018 (4)	0.014 (3)	0.003 (3)	−0.014 (3)
C4	0.014 (3)	0.025 (4)	0.031 (4)	0.004 (3)	−0.001 (3)	0.002 (3)
C5	0.021 (3)	0.034 (4)	0.034 (5)	−0.004 (3)	−0.010 (3)	−0.001 (3)
C6	0.031 (4)	0.031 (4)	0.029 (4)	−0.012 (3)	−0.010 (3)	−0.004 (3)
C7	0.024 (3)	0.023 (4)	0.019 (4)	0.001 (3)	−0.007 (3)	−0.004 (3)
C8	0.031 (4)	0.032 (4)	0.026 (4)	0.006 (3)	−0.006 (3)	0.007 (3)
C9	0.022 (3)	0.012 (3)	0.034 (4)	0.000 (3)	0.001 (3)	0.002 (3)
C10	0.019 (3)	0.019 (3)	0.019 (4)	−0.006 (3)	−0.001 (3)	0.003 (3)
C11	0.024 (3)	0.029 (4)	0.022 (4)	−0.001 (3)	−0.003 (3)	0.002 (3)
C12	0.032 (4)	0.040 (4)	0.020 (4)	−0.003 (3)	0.000 (3)	−0.010 (3)
C13	0.032 (4)	0.050 (5)	0.019 (4)	−0.002 (3)	−0.009 (3)	0.002 (4)
C14	0.026 (4)	0.036 (4)	0.041 (5)	0.011 (3)	−0.012 (4)	0.000 (4)
C15	0.029 (4)	0.033 (4)	0.027 (4)	0.006 (3)	−0.007 (3)	−0.003 (3)
C16	0.023 (3)	0.016 (3)	0.019 (4)	0.004 (3)	0.006 (3)	0.003 (3)
C17	0.033 (4)	0.028 (4)	0.027 (4)	−0.007 (3)	−0.004 (3)	0.002 (3)
C18	0.040 (4)	0.033 (4)	0.025 (4)	−0.006 (3)	0.003 (4)	0.004 (3)
C19	0.032 (4)	0.024 (4)	0.036 (5)	−0.005 (3)	0.011 (4)	0.005 (3)
C20	0.021 (3)	0.023 (4)	0.040 (5)	−0.003 (3)	−0.001 (3)	−0.004 (3)
C21	0.028 (3)	0.023 (4)	0.023 (4)	0.005 (3)	−0.005 (3)	−0.001 (3)
C22	0.022 (3)	0.015 (3)	0.021 (4)	0.003 (3)	−0.003 (3)	−0.005 (3)
C23	0.034 (4)	0.041 (4)	0.026 (4)	0.000 (3)	0.005 (3)	−0.009 (4)
C24	0.040 (4)	0.028 (4)	0.043 (5)	−0.004 (3)	0.005 (4)	−0.007 (4)
C25	0.044 (4)	0.030 (4)	0.028 (5)	0.008 (3)	0.002 (4)	−0.012 (3)
C26	0.026 (3)	0.031 (4)	0.028 (4)	−0.002 (3)	0.012 (3)	−0.002 (3)
C27	0.023 (3)	0.023 (4)	0.032 (4)	−0.002 (3)	0.000 (3)	−0.006 (3)
C28	0.025 (3)	0.024 (4)	0.018 (4)	−0.002 (3)	−0.005 (3)	−0.004 (3)
C29	0.026 (3)	0.019 (3)	0.023 (4)	−0.002 (3)	0.003 (3)	0.001 (3)
C30	0.037 (4)	0.029 (4)	0.032 (5)	0.004 (3)	0.003 (4)	0.001 (3)
C31	0.029 (4)	0.045 (5)	0.039 (5)	0.009 (3)	0.007 (4)	−0.002 (4)
C32	0.046 (4)	0.033 (4)	0.026 (5)	−0.013 (3)	0.011 (4)	−0.011 (3)
C33	0.046 (4)	0.047 (5)	0.018 (4)	−0.020 (4)	−0.004 (4)	−0.005 (4)
C34	0.024 (3)	0.046 (4)	0.023 (4)	−0.005 (3)	−0.002 (3)	0.001 (4)
C35	0.105 (8)	0.028 (5)	0.065 (7)	−0.005 (5)	−0.042 (6)	0.002 (5)
C36	0.087 (7)	0.049 (6)	0.100 (9)	0.022 (5)	−0.035 (7)	−0.028 (6)
Cl1	0.0209 (8)	0.0269 (9)	0.0301 (11)	−0.0032 (7)	−0.0085 (8)	−0.0020 (8)
N1	0.016 (3)	0.019 (3)	0.020 (3)	0.002 (2)	−0.006 (2)	0.002 (2)
N2	0.024 (3)	0.024 (3)	0.018 (3)	0.001 (2)	−0.001 (3)	−0.005 (2)
N3	0.022 (3)	0.022 (3)	0.016 (3)	−0.001 (2)	−0.001 (2)	0.001 (2)
N4	0.023 (3)	0.019 (3)	0.024 (3)	0.000 (2)	−0.003 (3)	−0.009 (2)
N5	0.016 (3)	0.017 (3)	0.023 (3)	0.002 (2)	−0.004 (2)	−0.005 (2)
N6	0.027 (3)	0.016 (3)	0.020 (3)	0.000 (2)	0.000 (3)	−0.002 (2)
N7	0.019 (3)	0.017 (3)	0.020 (3)	−0.002 (2)	−0.006 (3)	0.001 (3)
O2	0.066 (4)	0.073 (4)	0.046 (4)	0.007 (3)	−0.011 (3)	−0.009 (3)
P1	0.0193 (8)	0.0204 (9)	0.0169 (10)	0.0008 (7)	−0.0017 (8)	−0.0011 (8)
Ru1	0.0162 (2)	0.0176 (3)	0.0165 (3)	0.00072 (19)	−0.0021 (2)	−0.0017 (2)

B1—N2	1.530 (9)	C20—C21	1.377 (8)
B1—N4	1.541 (8)	C20—H20	0.9500
B1—N6	1.545 (8)	C21—H21	0.9500
B1—H1'	1.0000	C22—C27	1.383 (8)
C1—N1	1.326 (8)	C22—C23	1.397 (8)
C1—C2	1.380 (8)	C22—P1	1.838 (6)
C1—H1	0.9500	C23—C24	1.384 (8)
C2—C3	1.365 (9)	C23—H23	0.9500
C2—H2	0.9500	C24—C25	1.382 (9)
C3—N2	1.341 (7)	C24—H24	0.9500
C3—H3	0.9500	C25—C26	1.361 (8)
C4—N3	1.332 (7)	C25—H25	0.9500
C4—C5	1.378 (8)	C26—C27	1.382 (8)
C4—H4	0.9500	C26—H26	0.9500
C5—C6	1.379 (8)	C27—H27	0.9500
C5—H5	0.9500	C28—N7	1.144 (7)
C6—N4	1.339 (7)	C28—C29	1.436 (9)
C6—H6	0.9500	C29—C34	1.375 (8)
C7—N5	1.323 (7)	C29—C30	1.393 (8)
C7—C8	1.385 (8)	C30—C31	1.366 (9)
C7—H7	0.9500	C30—H30	0.9500
C8—C9	1.356 (8)	C31—C32	1.375 (8)
C8—H8	0.9500	C31—H31	0.9500
C9—N6	1.355 (7)	C32—C33	1.377 (9)
C9—H9	0.9500	C32—H32	0.9500
C10—C15	1.386 (7)	C33—C34	1.380 (9)
C10—C11	1.396 (8)	C33—H33	0.9500
C10—P1	1.833 (6)	C34—H34	0.9500
C11—C12	1.372 (8)	C35—O2	1.403 (8)
C11—H11	0.9500	C35—C36	1.535 (11)
C12—C13	1.380 (8)	C35—H35A	0.9900
C12—H12	0.9500	C35—H35B	0.9900
C13—C14	1.364 (8)	C36—H36A	0.9800
C13—H13	0.9500	C36—H36B	0.9800
C14—C15	1.383 (8)	C36—H36C	0.9800
C14—H14	0.9500	Cl1—Ru1	2.4259 (14)
C15—H15	0.9500	N1—N2	1.371 (6)
C16—C17	1.383 (8)	N1—Ru1	2.063 (5)
C16—C21	1.400 (7)	N3—N4	1.373 (6)
C16—P1	1.834 (6)	N3—Ru1	2.069 (4)
C17—C18	1.381 (8)	N5—N6	1.354 (6)
C17—H17	0.9500	N5—Ru1	2.102 (5)
C18—C19	1.362 (8)	N7—Ru1	1.991 (5)
C18—H18	0.9500	O2—H2'	0.8400
C19—C20	1.383 (8)	P1—Ru1	2.3205 (16)
C19—H19	0.9500
N2—B1—N4	108.7 (5)	C24—C25—H25	120.7
N2—B1—N6	107.5 (5)	C25—C26—C27	121.1 (6)
N4—B1—N6	107.0 (5)	C25—C26—H26	119.5
N2—B1—H1'	111.1	C27—C26—H26	119.5
N4—B1—H1'	111.1	C26—C27—C22	121.5 (6)
N6—B1—H1'	111.1	C26—C27—H27	119.3
N1—C1—C2	111.4 (6)	C22—C27—H27	119.3
N1—C1—H1	124.3	N7—C28—C29	178.6 (7)
C2—C1—H1	124.3	C34—C29—C30	119.9 (6)
C3—C2—C1	104.6 (6)	C34—C29—C28	120.5 (5)
C3—C2—H2	127.7	C30—C29—C28	119.6 (6)
C1—C2—H2	127.7	C31—C30—C29	120.0 (7)
N2—C3—C2	109.1 (6)	C31—C30—H30	120.0
N2—C3—H3	125.5	C29—C30—H30	120.0
C2—C3—H3	125.5	C30—C31—C32	119.9 (6)
N3—C4—C5	110.9 (5)	C30—C31—H31	120.1
N3—C4—H4	124.5	C32—C31—H31	120.1
C5—C4—H4	124.5	C31—C32—C33	120.6 (7)
C6—C5—C4	104.9 (5)	C31—C32—H32	119.7
C6—C5—H5	127.6	C33—C32—H32	119.7
C4—C5—H5	127.6	C32—C33—C34	119.8 (6)
N4—C6—C5	108.8 (5)	C32—C33—H33	120.1
N4—C6—H6	125.6	C34—C33—H33	120.1
C5—C6—H6	125.6	C29—C34—C33	119.8 (6)
N5—C7—C8	110.7 (5)	C29—C34—H34	120.1
N5—C7—H7	124.7	C33—C34—H34	120.1
C8—C7—H7	124.7	O2—C35—C36	108.7 (7)
C9—C8—C7	105.0 (6)	O2—C35—H35A	110.0
C9—C8—H8	127.5	C36—C35—H35A	110.0
C7—C8—H8	127.5	O2—C35—H35B	110.0
N6—C9—C8	108.6 (5)	C36—C35—H35B	110.0
N6—C9—H9	125.7	H35A—C35—H35B	108.3
C8—C9—H9	125.7	C35—C36—H36A	109.5
C15—C10—C11	117.4 (5)	C35—C36—H36B	109.5
C15—C10—P1	122.4 (5)	H36A—C36—H36B	109.5
C11—C10—P1	120.1 (4)	C35—C36—H36C	109.5
C12—C11—C10	121.4 (5)	H36A—C36—H36C	109.5
C12—C11—H11	119.3	H36B—C36—H36C	109.5
C10—C11—H11	119.3	C1—N1—N2	105.8 (5)
C11—C12—C13	120.4 (6)	C1—N1—Ru1	136.1 (4)
C11—C12—H12	119.8	N2—N1—Ru1	118.0 (4)
C13—C12—H12	119.8	C3—N2—N1	109.1 (5)
C14—C13—C12	118.8 (6)	C3—N2—B1	129.9 (5)
C14—C13—H13	120.6	N1—N2—B1	120.8 (5)
C12—C13—H13	120.6	C4—N3—N4	106.3 (5)
C13—C14—C15	121.4 (6)	C4—N3—Ru1	134.6 (4)
C13—C14—H14	119.3	N4—N3—Ru1	118.6 (3)
C15—C14—H14	119.3	C6—N4—N3	109.2 (5)
C14—C15—C10	120.6 (6)	C6—N4—B1	129.9 (5)
C14—C15—H15	119.7	N3—N4—B1	120.0 (4)
C10—C15—H15	119.7	C7—N5—N6	106.7 (4)
C17—C16—C21	117.1 (6)	C7—N5—Ru1	133.9 (4)
C17—C16—P1	123.2 (5)	N6—N5—Ru1	119.3 (4)
C21—C16—P1	119.5 (5)	N5—N6—C9	109.0 (5)
C18—C17—C16	121.8 (6)	N5—N6—B1	119.1 (4)
C18—C17—H17	119.1	C9—N6—B1	132.0 (5)
C16—C17—H17	119.1	C28—N7—Ru1	175.5 (5)
C19—C18—C17	120.7 (7)	C35—O2—H2'	109.5
C19—C18—H18	119.7	C10—P1—C16	100.4 (3)
C17—C18—H18	119.7	C10—P1—C22	102.2 (3)
C18—C19—C20	118.8 (6)	C16—P1—C22	99.5 (3)
C18—C19—H19	120.6	C10—P1—Ru1	113.87 (19)
C20—C19—H19	120.6	C16—P1—Ru1	119.88 (18)
C21—C20—C19	121.0 (6)	C22—P1—Ru1	118.0 (2)
C21—C20—H20	119.5	N7—Ru1—N1	173.57 (19)
C19—C20—H20	119.5	N7—Ru1—N3	89.01 (19)
C20—C21—C16	120.7 (6)	N1—Ru1—N3	90.33 (18)
C20—C21—H21	119.7	N7—Ru1—N5	89.35 (19)
C16—C21—H21	119.7	N1—Ru1—N5	84.21 (19)
C27—C22—C23	117.2 (6)	N3—Ru1—N5	85.23 (17)
C27—C22—P1	120.7 (4)	N7—Ru1—P1	94.34 (14)
C23—C22—P1	122.1 (5)	N1—Ru1—P1	92.08 (13)
C24—C23—C22	120.7 (7)	N3—Ru1—P1	92.67 (13)
C24—C23—H23	119.7	N5—Ru1—P1	175.72 (15)
C22—C23—H23	119.7	N7—Ru1—Cl1	88.69 (13)
C23—C24—C25	120.9 (6)	N1—Ru1—Cl1	90.79 (13)
C23—C24—H24	119.6	N3—Ru1—Cl1	169.39 (13)
C25—C24—H24	119.6	N5—Ru1—Cl1	84.39 (13)
C26—C25—C24	118.6 (6)	P1—Ru1—Cl1	97.83 (5)
C26—C25—H25	120.7