Erratum: 2-(2-Thien-yl)-4,5-dihydro-1H-imidazole. Corrigendum.

Consideration of a previous unrecognized twinning of the original investigated crystal of the title compound [Kia et al. (2009 ▶). Acta Cryst. E65, o301] led to improved reliability factors and to a slightly higher precision for all geometric parameters. The crystal under investigation was twinned by pseudo-merohedry with [100, 00, 00] as the twin matrix and a refined twin domain fraction of 0.9610 (5):0.0390 (5). The results of the new crystal structure refinement are given here.[This corrects the article DOI: 10.1107/S1600536809001068.].

Experimental

Crystal data

C7H8N2S

M = 152.21

Monoclinic,

a = 6.1321 (2) Å

b = 11.5663 (3) Å

c = 10.0098 (3) Å

β = 90.154 (1)°

V = 709.95 (4) Å3

Z = 4

Mo Kα radiation

μ = 0.37 mm−1

T = 100 K

0.54 × 0.28 × 0.22 mm

Data collection

Bruker SMART APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (; Bruker, 2005 ▶) T min = 0.825, T max = 0.922

28316 measured reflections

3100 independent reflections

3040 reflections with I > 2σ(I)

R int = 0.021

Refinement

R[F 2 > 2σ(F 2)] = 0.027

wR(F 2) = 0.080

S = 1.15

3100 reflections

96 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.52 e Å−3

Δρmin = −0.24 e Å−3

Data collection: APEX2 (Bruker, 2005 ▶); cell refinement: SAINT (Bruker, 2005 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 ▶) and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809018790/wm2233sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809018790/wm2233Isup2.hkl

. DOI: 10.1107/S1600536809018790/wm2233fig1.tif

The mol­ecular structure of the title compound showing the atom labels and 50% probability displacement ellipsoids for non-H atoms.

a c. DOI: 10.1107/S1600536809018790/wm2233fig2.tif

The crystal packing of the title compound, viewed down the a axis, showing the one-dimensional infinite chain along the c axis formed by inter­molecular N—H⋯N and C—H⋯N inter­actions. The inter­molecular inter­actions are shown as dashed lines.

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1⋯N2i	0.857 (16)	2.130 (16)	2.9803 (10)	171.5 (16)
C3—H3A⋯N2i	0.95	2.59	3.4815 (11)	156

Symmetry code: (i) .