[μ-1,1'-Bis(diphenyl-phosphino)ferrocene]bis-{[(Z)-O-ethyl N-phenyl-thio-carbamato-κS]gold(I)} dichloro-methane solvate.

The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]·CH(2)Cl(2), which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1:1 dichloro-methane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1-Au-P1 angle is 175.35 (5) °] which is due to an intra-molecular Au⋯O contact [3.080 (5) Å]. The primary inter-molecular contacts between binuclear mol-ecules are of the type C-H⋯π, and are arranged so as to form columns in the a-axis direction in which the disordered solvent mol-ecules reside.

Related literature

For the structural systematics and luminescence properties of <pan class="Chemical">span class="Chemical">class="Chemical">phosclass="Chemical">phinegoldclass="Chemical">pan>(I) carbonimidothio­ates, see: Ho et al. (2006 ▶); Ho & Tiekink (2007 ▶); Kuan et al. (2008 ▶). For the synthesis, see: Hall et al. (1993 ▶). For related structures, see: Ho & Tiekink (2009 ▶); <class="Chemical">sppan>an class="Chemical">Tadbuppa & Tiekink (2009 ▶).

Experimental

Crystal data

[<pan class="Chemical">span class="Chemical">Auclass="Chemical">pan>2<class="Chemical">sppan>an class="Chemical">Fe(C9H10NOS)2(C17H14P)2]·CH2Cl2

M = 1393.69

Triclinic,

a = 8.442 (3) Å

b = 12.957 (5) Å

c = 13.440 (5) Å

α = 108.045 (8)°

β = 103.177 (8)°

γ = 106.853 (8)°

V = 1253.5 (9) Å3

Z = 1

Mo Kα radiation

μ = 6.42 mm−1

T = 223 K

0.49 × 0.04 × 0.04 mm

Data collection

Bruker SMART CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T min = 0.577, T max = 1

8618 measured reflections

5688 independent reflections

5025 reflections with I > 2σ(I)

R int = 0.030

Refinement

R[F 2 > 2σ(F 2)] = 0.038

wR(F 2) = 0.106

S = 1.02

5688 reflections

307 parameters

13 restraints

H-atom parameters constrained

Δρmax = 2.84 e Å−3

Δρmin = −1.47 e Å−3

Data collection: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SHELXTL (Sheldrick, 2008 ▶); program(s) used to solve structure: class="Chemical">PATTY in DIRDIF92 (Beurskens et al., 1992 ▶); class="Chemical">program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graclass="Chemical">phics: ORTEclass="Chemical">pan class="Chemical">P-3 (Farrugia, 1997 ▶) and <span class="Disease">DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S160053681001562X/pk2245sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053681001562X/pk2245Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Au2Fe(C9H10NOS)2(C17H14P)2]·CH2Cl2	Z = 1
Mr = 1393.69	F(000) = 678
Triclinic, P1	Dx = 1.846 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71069 Å
a = 8.442 (3) Å	Cell parameters from 4599 reflections
b = 12.957 (5) Å	θ = 2.6–30.1°
c = 13.440 (5) Å	µ = 6.42 mm−1
α = 108.045 (8)°	T = 223 K
β = 103.177 (8)°	Needle, orange
γ = 106.853 (8)°	0.49 × 0.04 × 0.04 mm
V = 1253.5 (9) Å3

Bruker SMART CCD diffractometer	5688 independent reflections
Radiation source: fine-focus sealed tube	5025 reflections with I > 2σ(I)
graphite	Rint = 0.030
ω scans	θmax = 27.5°, θmin = 2.6°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −10→10
Tmin = 0.577, Tmax = 1	k = −16→11
8618 measured reflections	l = −16→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.106	H-atom parameters constrained
S = 1.02	w = 1/[σ2(Fo2) + (0.0684P)2] where P = (Fo2 + 2Fc2)/3
5688 reflections	(Δ/σ)max = 0.001
307 parameters	Δρmax = 2.84 e Å−3
13 restraints	Δρmin = −1.47 e Å−3

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Au	0.54576 (2)	0.149128 (17)	0.224945 (16)	0.02842 (9)
Fe	0.0000	0.0000	0.0000	0.0234 (2)
S1	0.6884 (2)	0.11576 (15)	0.37230 (12)	0.0387 (3)
P1	0.42701 (17)	0.19357 (11)	0.08358 (11)	0.0240 (3)
O1	0.4392 (5)	0.1685 (4)	0.4324 (3)	0.0397 (10)
N1	0.6859 (6)	0.2200 (5)	0.5809 (4)	0.0368 (11)
C1	0.6054 (8)	0.1739 (5)	0.4754 (5)	0.0317 (11)
C2	0.8589 (8)	0.2308 (5)	0.6274 (5)	0.0344 (12)
C3	0.8983 (9)	0.1323 (6)	0.6232 (6)	0.0422 (14)
H3	0.8092	0.0561	0.5840	0.051*
C4	1.0693 (9)	0.1475 (6)	0.6769 (6)	0.0439 (14)
H4	1.0952	0.0810	0.6739	0.053*
C5	1.2007 (9)	0.2566 (6)	0.7341 (5)	0.0434 (15)
H5	1.3163	0.2649	0.7690	0.052*
C6	1.1636 (8)	0.3563 (6)	0.7409 (6)	0.0440 (15)
H6	1.2529	0.4323	0.7808	0.053*
C7	0.9909 (8)	0.3404 (6)	0.6873 (5)	0.0394 (13)
H7	0.9642	0.4070	0.6924	0.047*
C8	0.3614 (8)	0.2141 (7)	0.5128 (6)	0.0466 (16)
H8A	0.4412	0.2944	0.5658	0.056*
H8B	0.3408	0.1646	0.5546	0.056*
C9	0.1920 (10)	0.2139 (8)	0.4508 (6)	0.0551 (19)
H9A	0.1370	0.2436	0.5031	0.083*
H9B	0.1142	0.1342	0.3983	0.083*
H9C	0.2139	0.2640	0.4106	0.083*
C10	0.2261 (7)	0.0814 (4)	−0.0219 (4)	0.0255 (10)
C11	0.1892 (7)	−0.0416 (5)	−0.0552 (5)	0.0312 (11)
H11	0.2615	−0.0753	−0.0247	0.037*
C12	0.0209 (8)	−0.1038 (5)	−0.1443 (5)	0.0377 (14)
H12	−0.0363	−0.1860	−0.1833	0.045*
C13	−0.0434 (8)	−0.0202 (5)	−0.1629 (5)	0.0372 (13)
H13	−0.1520	−0.0377	−0.2161	0.045*
C14	0.0802 (7)	0.0937 (5)	−0.0894 (5)	0.0304 (11)
H14	0.0693	0.1650	−0.0853	0.036*
C15	0.5783 (7)	0.2270 (4)	0.0097 (5)	0.0268 (10)
C16	0.5327 (8)	0.1678 (5)	−0.1046 (5)	0.0320 (11)
H16	0.4185	0.1101	−0.1479	0.038*
C17	0.6581 (9)	0.1949 (6)	−0.1545 (5)	0.0395 (13)
H17	0.6282	0.1551	−0.2319	0.047*
C18	0.8269 (8)	0.2804 (6)	−0.0905 (6)	0.0426 (15)
H18	0.9102	0.2990	−0.1247	0.051*
C19	0.8716 (8)	0.3371 (6)	0.0215 (6)	0.0425 (14)
H19	0.9861	0.3945	0.0643	0.051*
C20	0.7489 (7)	0.3110 (5)	0.0738 (5)	0.0335 (12)
H20	0.7812	0.3498	0.1515	0.040*
C21	0.3847 (7)	0.3269 (5)	0.1315 (5)	0.0294 (11)
C22	0.3700 (7)	0.3903 (5)	0.0660 (5)	0.0321 (11)
H22	0.3774	0.3630	−0.0056	0.038*
C23	0.3444 (8)	0.4938 (5)	0.1063 (6)	0.0372 (13)
H23	0.3335	0.5363	0.0615	0.045*
C24	0.3348 (8)	0.5355 (5)	0.2118 (6)	0.0379 (13)
H24	0.3199	0.6068	0.2393	0.046*
C25	0.3471 (9)	0.4717 (6)	0.2762 (6)	0.0454 (15)
H25	0.3379	0.4988	0.3473	0.055*
C26	0.3728 (8)	0.3689 (5)	0.2371 (5)	0.0353 (12)
H26	0.3824	0.3265	0.2821	0.042*
Cl1	0.1902 (6)	0.5357 (4)	0.5501 (4)	0.1365 (14)
C27	0.0112 (19)	0.5715 (19)	0.548 (2)	0.085 (6)	0.50
H27A	0.0327	0.6434	0.5342	0.103*	0.50
H27B	0.0018	0.5900	0.6223	0.103*	0.50

	U11	U22	U33	U12	U13	U23
Au	0.02700 (12)	0.03400 (13)	0.02496 (13)	0.01353 (9)	0.00771 (8)	0.01222 (9)
Fe	0.0212 (4)	0.0246 (5)	0.0227 (5)	0.0075 (4)	0.0068 (4)	0.0093 (4)
S1	0.0421 (8)	0.0566 (9)	0.0265 (7)	0.0317 (7)	0.0117 (6)	0.0171 (6)
P1	0.0230 (6)	0.0252 (6)	0.0242 (6)	0.0100 (5)	0.0086 (5)	0.0098 (5)
O1	0.031 (2)	0.054 (3)	0.028 (2)	0.0181 (19)	0.0081 (17)	0.0088 (19)
N1	0.031 (2)	0.049 (3)	0.021 (2)	0.010 (2)	0.0066 (19)	0.009 (2)
C1	0.032 (3)	0.037 (3)	0.026 (3)	0.015 (2)	0.009 (2)	0.013 (2)
C2	0.033 (3)	0.049 (3)	0.023 (3)	0.016 (2)	0.011 (2)	0.016 (2)
C3	0.041 (3)	0.040 (3)	0.040 (3)	0.009 (3)	0.010 (3)	0.019 (3)
C4	0.051 (4)	0.048 (4)	0.042 (4)	0.025 (3)	0.013 (3)	0.027 (3)
C5	0.035 (3)	0.064 (4)	0.033 (3)	0.021 (3)	0.009 (3)	0.023 (3)
C6	0.030 (3)	0.051 (4)	0.038 (3)	0.007 (3)	0.007 (3)	0.015 (3)
C7	0.031 (3)	0.047 (3)	0.038 (3)	0.015 (3)	0.012 (3)	0.014 (3)
C8	0.037 (3)	0.061 (4)	0.036 (3)	0.022 (3)	0.014 (3)	0.007 (3)
C9	0.052 (4)	0.083 (5)	0.037 (4)	0.042 (4)	0.016 (3)	0.018 (4)
C10	0.026 (2)	0.026 (2)	0.025 (2)	0.0100 (19)	0.008 (2)	0.0101 (19)
C11	0.034 (3)	0.027 (3)	0.034 (3)	0.013 (2)	0.015 (2)	0.011 (2)
C12	0.033 (3)	0.032 (3)	0.035 (3)	0.003 (2)	0.018 (3)	0.002 (2)
C13	0.032 (3)	0.046 (3)	0.023 (3)	0.007 (2)	0.006 (2)	0.011 (2)
C14	0.026 (2)	0.041 (3)	0.027 (3)	0.012 (2)	0.010 (2)	0.019 (2)
C15	0.024 (2)	0.028 (2)	0.035 (3)	0.012 (2)	0.013 (2)	0.017 (2)
C16	0.032 (3)	0.033 (3)	0.034 (3)	0.013 (2)	0.012 (2)	0.015 (2)
C17	0.049 (3)	0.049 (3)	0.037 (3)	0.027 (3)	0.027 (3)	0.022 (3)
C18	0.038 (3)	0.053 (4)	0.065 (4)	0.028 (3)	0.033 (3)	0.040 (3)
C19	0.027 (3)	0.040 (3)	0.061 (4)	0.011 (2)	0.016 (3)	0.022 (3)
C20	0.027 (3)	0.032 (3)	0.038 (3)	0.008 (2)	0.010 (2)	0.013 (2)
C21	0.020 (2)	0.028 (2)	0.035 (3)	0.0059 (19)	0.008 (2)	0.010 (2)
C22	0.030 (3)	0.027 (3)	0.038 (3)	0.011 (2)	0.013 (2)	0.011 (2)
C23	0.028 (3)	0.035 (3)	0.048 (4)	0.012 (2)	0.011 (3)	0.019 (3)
C24	0.034 (3)	0.026 (3)	0.044 (3)	0.010 (2)	0.009 (3)	0.005 (2)
C25	0.048 (4)	0.047 (4)	0.032 (3)	0.019 (3)	0.016 (3)	0.003 (3)
C26	0.038 (3)	0.032 (3)	0.035 (3)	0.014 (2)	0.015 (3)	0.011 (2)
Cl1	0.1389 (16)	0.1335 (16)	0.1363 (16)	0.0487 (10)	0.0470 (10)	0.0583 (10)
Cl1'	0.1389 (16)	0.1335 (16)	0.1363 (16)	0.0487 (10)	0.0470 (10)	0.0583 (10)
C27	0.086 (6)	0.085 (6)	0.085 (6)	0.033 (2)	0.030 (2)	0.035 (2)

Au—P1	2.2562 (15)	C9—H9C	0.9700
Au—S1	2.3029 (16)	C10—C11	1.429 (7)
Fe—C10	2.030 (5)	C10—C14	1.435 (7)
Fe—C10i	2.030 (5)	C11—C12	1.437 (8)
Fe—C14i	2.043 (5)	C11—H11	0.9400
Fe—C14	2.043 (5)	C12—C13	1.405 (9)
Fe—C11i	2.046 (5)	C12—H12	0.9400
Fe—C11	2.046 (5)	C13—C14	1.406 (8)
Fe—C13i	2.054 (6)	C13—H13	0.9400
Fe—C13	2.054 (6)	C14—H14	0.9400
Fe—C12	2.068 (5)	C15—C16	1.387 (8)
Fe—C12i	2.068 (5)	C15—C20	1.395 (7)
S1—C1	1.755 (6)	C16—C17	1.396 (8)
P1—C10	1.788 (5)	C16—H16	0.9400
P1—C21	1.817 (5)	C17—C18	1.391 (9)
P1—C15	1.824 (5)	C17—H17	0.9400
O1—C1	1.362 (7)	C18—C19	1.357 (10)
O1—C8	1.449 (7)	C18—H18	0.9400
N1—C1	1.277 (7)	C19—C20	1.399 (8)
N1—C2	1.398 (7)	C19—H19	0.9400
C2—C7	1.368 (9)	C20—H20	0.9400
C2—C3	1.398 (9)	C21—C22	1.387 (8)
C3—C4	1.384 (9)	C21—C26	1.393 (8)
C3—H3	0.9400	C22—C23	1.382 (8)
C4—C5	1.360 (10)	C22—H22	0.9400
C4—H4	0.9400	C23—C24	1.383 (9)
C5—C6	1.397 (10)	C23—H23	0.9400
C5—H5	0.9400	C24—C25	1.376 (10)
C6—C7	1.393 (9)	C24—H24	0.9400
C6—H6	0.9400	C25—C26	1.372 (9)
C7—H7	0.9400	C25—H25	0.9400
C8—C9	1.480 (9)	C26—H26	0.9400
C8—H8A	0.9800	Cl1—C27	1.701 (5)
C8—H8B	0.9800	Cl1—C27ii	1.74 (2)
C9—H9A	0.9700	C27—H27A	0.9800
C9—H9B	0.9700	C27—H27B	0.9800
P1—Au—S1	175.35 (5)	C9—C8—H8B	110.1
C10—Fe—C10i	180.0 (3)	H8A—C8—H8B	108.4
C10—Fe—C14i	138.7 (2)	C8—C9—H9A	109.5
C10i—Fe—C14i	41.3 (2)	C8—C9—H9B	109.5
C10—Fe—C14	41.3 (2)	H9A—C9—H9B	109.5
C10i—Fe—C14	138.7 (2)	C8—C9—H9C	109.5
C14i—Fe—C14	180.0 (3)	H9A—C9—H9C	109.5
C10—Fe—C11i	139.0 (2)	H9B—C9—H9C	109.5
C10i—Fe—C11i	41.0 (2)	C11—C10—C14	108.0 (5)
C14i—Fe—C11i	69.0 (2)	C11—C10—P1	122.9 (4)
C14—Fe—C11i	111.0 (2)	C14—C10—P1	129.0 (4)
C10—Fe—C11	41.0 (2)	C11—C10—Fe	70.1 (3)
C10i—Fe—C11	139.0 (2)	C14—C10—Fe	69.9 (3)
C14i—Fe—C11	111.0 (2)	P1—C10—Fe	127.3 (3)
C14—Fe—C11	69.0 (2)	C10—C11—C12	107.0 (5)
C11i—Fe—C11	180.0 (3)	C10—C11—Fe	68.9 (3)
C10—Fe—C13i	111.7 (2)	C12—C11—Fe	70.4 (3)
C10i—Fe—C13i	68.3 (2)	C10—C11—H11	126.5
C14i—Fe—C13i	40.1 (2)	C12—C11—H11	126.5
C14—Fe—C13i	139.9 (2)	Fe—C11—H11	125.8
C11i—Fe—C13i	68.3 (2)	C13—C12—C11	108.1 (5)
C11—Fe—C13i	111.7 (2)	C13—C12—Fe	69.5 (3)
C10—Fe—C13	68.3 (2)	C11—C12—Fe	68.7 (3)
C10i—Fe—C13	111.7 (2)	C13—C12—H12	126.0
C14i—Fe—C13	139.9 (2)	C11—C12—H12	126.0
C14—Fe—C13	40.1 (2)	Fe—C12—H12	127.4
C11i—Fe—C13	111.7 (2)	C14—C13—C12	109.3 (5)
C11—Fe—C13	68.3 (2)	C14—C13—Fe	69.5 (3)
C13i—Fe—C13	180.0 (3)	C12—C13—Fe	70.6 (4)
C10—Fe—C12	68.4 (2)	C14—C13—H13	125.3
C10i—Fe—C12	111.6 (2)	C12—C13—H13	125.3
C14i—Fe—C12	112.2 (2)	Fe—C13—H13	126.1
C14—Fe—C12	67.8 (2)	C13—C14—C10	107.5 (5)
C11i—Fe—C12	139.1 (2)	C13—C14—Fe	70.3 (3)
C11—Fe—C12	40.9 (2)	C10—C14—Fe	68.9 (3)
C13i—Fe—C12	140.1 (3)	C13—C14—H14	126.2
C13—Fe—C12	39.9 (3)	C10—C14—H14	126.2
C10—Fe—C12i	111.6 (2)	Fe—C14—H14	126.1
C10i—Fe—C12i	68.4 (2)	C16—C15—C20	120.0 (5)
C14i—Fe—C12i	67.8 (2)	C16—C15—P1	122.6 (4)
C14—Fe—C12i	112.2 (2)	C20—C15—P1	117.3 (4)
C11i—Fe—C12i	40.9 (2)	C15—C16—C17	119.3 (5)
C11—Fe—C12i	139.1 (2)	C15—C16—H16	120.3
C13i—Fe—C12i	39.9 (3)	C17—C16—H16	120.3
C13—Fe—C12i	140.1 (3)	C18—C17—C16	120.4 (6)
C12—Fe—C12i	180.0 (4)	C18—C17—H17	119.8
C1—S1—Au	102.6 (2)	C16—C17—H17	119.8
C10—P1—C21	106.8 (2)	C19—C18—C17	120.1 (5)
C10—P1—C15	105.4 (2)	C19—C18—H18	119.9
C21—P1—C15	103.4 (2)	C17—C18—H18	119.9
C10—P1—Au	115.79 (18)	C18—C19—C20	120.7 (6)
C21—P1—Au	112.8 (2)	C18—C19—H19	119.7
C15—P1—Au	111.77 (18)	C20—C19—H19	119.7
C1—O1—C8	116.2 (5)	C15—C20—C19	119.5 (6)
C1—N1—C2	121.6 (5)	C15—C20—H20	120.3
N1—C1—O1	120.3 (5)	C19—C20—H20	120.3
N1—C1—S1	126.6 (5)	C22—C21—C26	119.1 (5)
O1—C1—S1	113.1 (4)	C22—C21—P1	121.0 (4)
C7—C2—N1	119.6 (6)	C26—C21—P1	119.8 (5)
C7—C2—C3	118.6 (6)	C23—C22—C21	119.7 (6)
N1—C2—C3	121.5 (6)	C23—C22—H22	120.1
C4—C3—C2	119.6 (6)	C21—C22—H22	120.1
C4—C3—H3	120.2	C22—C23—C24	120.7 (6)
C2—C3—H3	120.2	C22—C23—H23	119.6
C5—C4—C3	121.4 (6)	C24—C23—H23	119.6
C5—C4—H4	119.3	C25—C24—C23	119.5 (6)
C3—C4—H4	119.3	C25—C24—H24	120.2
C4—C5—C6	119.9 (6)	C23—C24—H24	120.2
C4—C5—H5	120.1	C26—C25—C24	120.3 (6)
C6—C5—H5	120.1	C26—C25—H25	119.8
C7—C6—C5	118.4 (6)	C24—C25—H25	119.8
C7—C6—H6	120.8	C25—C26—C21	120.6 (6)
C5—C6—H6	120.8	C25—C26—H26	119.7
C2—C7—C6	122.1 (6)	C21—C26—H26	119.7
C2—C7—H7	119.0	Cl1ii—C27—Cl1	116.5 (11)
C6—C7—H7	119.0	Cl1—C27—H27A	108.2
O1—C8—C9	108.1 (5)	Cl1ii—C27—H27A	108.2
O1—C8—H8A	110.1	Cl1—C27—H27B	108.2
C9—C8—H8A	110.1	Cl1ii—C27—H27B	108.2
O1—C8—H8B	110.1	H27A—C27—H27B	107.3
P1—Au—S1—C1	106.4 (6)	C11i—Fe—C12—C13	59.9 (5)
S1—Au—P1—C10	160.4 (6)	C11—Fe—C12—C13	−120.1 (5)
S1—Au—P1—C21	−76.2 (6)	C13i—Fe—C12—C13	180.000 (1)
S1—Au—P1—C15	39.7 (6)	C12i—Fe—C12—C13	−49 (34)
C2—N1—C1—O1	−177.6 (5)	C10—Fe—C12—C11	38.5 (3)
C2—N1—C1—S1	1.0 (9)	C10i—Fe—C12—C11	−141.5 (3)
C8—O1—C1—N1	−1.7 (8)	C14i—Fe—C12—C11	−96.8 (3)
C8—O1—C1—S1	179.5 (5)	C14—Fe—C12—C11	83.2 (3)
Au—S1—C1—N1	−149.8 (5)	C11i—Fe—C12—C11	180.0
Au—S1—C1—O1	28.9 (5)	C13i—Fe—C12—C11	−59.9 (5)
C1—N1—C2—C7	115.8 (7)	C13—Fe—C12—C11	120.1 (5)
C1—N1—C2—C3	−70.2 (8)	C12i—Fe—C12—C11	71 (32)
C7—C2—C3—C4	−1.5 (9)	C11—C12—C13—C14	0.9 (6)
N1—C2—C3—C4	−175.5 (6)	Fe—C12—C13—C14	58.9 (4)
C2—C3—C4—C5	0.0 (10)	C11—C12—C13—Fe	−58.0 (4)
C3—C4—C5—C6	1.1 (10)	C10—Fe—C13—C14	−38.5 (3)
C4—C5—C6—C7	−0.6 (10)	C10i—Fe—C13—C14	141.5 (3)
N1—C2—C7—C6	176.1 (6)	C14i—Fe—C13—C14	180.0
C3—C2—C7—C6	2.0 (9)	C11i—Fe—C13—C14	97.2 (4)
C5—C6—C7—C2	−1.0 (10)	C11—Fe—C13—C14	−82.8 (4)
C1—O1—C8—C9	173.2 (6)	C13i—Fe—C13—C14	54 (58)
C21—P1—C10—C11	−160.4 (4)	C12—Fe—C13—C14	−120.4 (5)
C15—P1—C10—C11	90.1 (5)	C12i—Fe—C13—C14	59.6 (5)
Au—P1—C10—C11	−33.9 (5)	C10—Fe—C13—C12	81.9 (3)
C21—P1—C10—C14	22.0 (6)	C10i—Fe—C13—C12	−98.1 (3)
C15—P1—C10—C14	−87.4 (5)	C14i—Fe—C13—C12	−59.6 (5)
Au—P1—C10—C14	148.5 (4)	C14—Fe—C13—C12	120.4 (5)
C21—P1—C10—Fe	−71.4 (4)	C11i—Fe—C13—C12	−142.4 (3)
C15—P1—C10—Fe	179.2 (3)	C11—Fe—C13—C12	37.6 (3)
Au—P1—C10—Fe	55.1 (4)	C13i—Fe—C13—C12	174 (58)
C10i—Fe—C10—C11	−160 (45)	C12i—Fe—C13—C12	180.000 (1)
C14i—Fe—C10—C11	61.1 (5)	C12—C13—C14—C10	−0.5 (6)
C14—Fe—C10—C11	−118.9 (5)	Fe—C13—C14—C10	59.1 (4)
C11i—Fe—C10—C11	180.0	C12—C13—C14—Fe	−59.6 (4)
C13i—Fe—C10—C11	98.6 (4)	C11—C10—C14—C13	−0.1 (6)
C13—Fe—C10—C11	−81.4 (4)	P1—C10—C14—C13	177.8 (4)
C12—Fe—C10—C11	−38.4 (4)	Fe—C10—C14—C13	−60.0 (4)
C12i—Fe—C10—C11	141.6 (4)	C11—C10—C14—Fe	59.9 (4)
C10i—Fe—C10—C14	−41 (45)	P1—C10—C14—Fe	−122.2 (4)
C14i—Fe—C10—C14	180.0	C10—Fe—C14—C13	118.7 (5)
C11i—Fe—C10—C14	−61.1 (5)	C10i—Fe—C14—C13	−61.3 (5)
C11—Fe—C10—C14	118.9 (5)	C14i—Fe—C14—C13	−135 (100)
C13i—Fe—C10—C14	−142.5 (3)	C11i—Fe—C14—C13	−99.3 (4)
C13—Fe—C10—C14	37.5 (3)	C11—Fe—C14—C13	80.7 (4)
C12—Fe—C10—C14	80.5 (4)	C13i—Fe—C14—C13	180.0
C12i—Fe—C10—C14	−99.5 (4)	C12—Fe—C14—C13	36.7 (4)
C10i—Fe—C10—P1	83 (45)	C12i—Fe—C14—C13	−143.3 (4)
C14i—Fe—C10—P1	−55.7 (5)	C10i—Fe—C14—C10	180.0
C14—Fe—C10—P1	124.3 (5)	C14i—Fe—C14—C10	106 (100)
C11i—Fe—C10—P1	63.2 (5)	C11i—Fe—C14—C10	142.0 (3)
C11—Fe—C10—P1	−116.8 (5)	C11—Fe—C14—C10	−38.0 (3)
C13i—Fe—C10—P1	−18.3 (4)	C13i—Fe—C14—C10	61.3 (5)
C13—Fe—C10—P1	161.7 (4)	C13—Fe—C14—C10	−118.7 (5)
C12—Fe—C10—P1	−155.2 (4)	C12—Fe—C14—C10	−82.1 (3)
C12i—Fe—C10—P1	24.8 (4)	C12i—Fe—C14—C10	97.9 (3)
C14—C10—C11—C12	0.6 (6)	C10—P1—C15—C16	−2.2 (5)
P1—C10—C11—C12	−177.4 (4)	C21—P1—C15—C16	−114.1 (5)
Fe—C10—C11—C12	60.4 (4)	Au—P1—C15—C16	124.4 (4)
C14—C10—C11—Fe	−59.8 (4)	C10—P1—C15—C20	−178.4 (4)
P1—C10—C11—Fe	122.2 (4)	C21—P1—C15—C20	69.7 (5)
C10i—Fe—C11—C10	180.0	Au—P1—C15—C20	−51.9 (5)
C14i—Fe—C11—C10	−141.8 (3)	C20—C15—C16—C17	−1.2 (8)
C14—Fe—C11—C10	38.2 (3)	P1—C15—C16—C17	−177.3 (4)
C11i—Fe—C11—C10	8(100)	C15—C16—C17—C18	−0.1 (9)
C13i—Fe—C11—C10	−98.6 (4)	C16—C17—C18—C19	0.8 (9)
C13—Fe—C11—C10	81.4 (4)	C17—C18—C19—C20	−0.3 (10)
C12—Fe—C11—C10	118.1 (5)	C16—C15—C20—C19	1.7 (8)
C12i—Fe—C11—C10	−61.9 (5)	P1—C15—C20—C19	178.1 (4)
C10—Fe—C11—C12	−118.1 (5)	C18—C19—C20—C15	−0.9 (9)
C10i—Fe—C11—C12	61.9 (5)	C10—P1—C21—C22	−73.8 (5)
C14i—Fe—C11—C12	100.1 (4)	C15—P1—C21—C22	37.1 (5)
C14—Fe—C11—C12	−79.9 (4)	Au—P1—C21—C22	157.9 (4)
C11i—Fe—C11—C12	−110 (100)	C10—P1—C21—C26	108.5 (5)
C13i—Fe—C11—C12	143.3 (4)	C15—P1—C21—C26	−140.7 (4)
C13—Fe—C11—C12	−36.7 (4)	Au—P1—C21—C26	−19.8 (5)
C12i—Fe—C11—C12	180.0	C26—C21—C22—C23	0.2 (8)
C10—C11—C12—C13	−0.9 (6)	P1—C21—C22—C23	−177.6 (4)
Fe—C11—C12—C13	58.5 (4)	C21—C22—C23—C24	0.6 (9)
C10—C11—C12—Fe	−59.4 (4)	C22—C23—C24—C25	−1.4 (9)
C10—Fe—C12—C13	−81.5 (4)	C23—C24—C25—C26	1.5 (10)
C10i—Fe—C12—C13	98.5 (4)	C24—C25—C26—C21	−0.7 (10)
C14i—Fe—C12—C13	143.1 (3)	C22—C21—C26—C25	−0.1 (9)
C14—Fe—C12—C13	−36.9 (3)	P1—C21—C26—C25	177.7 (5)

Cg1 and Cg2 are the centroids of the C2–C7 and C15–C20 rings, respectively.

D—H···A	D—H	H···A	D···A	D—H···A
C9—H9a···Cg1iii	0.97	2.75	3.623 (9)	150
C11—H11···Cg2iv	0.94	2.78	3.619 (7)	150

Table 1

Selected bond lengths (Å)

Au—P1	2.2562 (15)
Au—S1	2.3029 (16)

Table 2

Hydrogen-bond geometry (Å, °)

Cg1 and Cg2 are the centroids of the C2–C7 and C15–C20 rings, respectively.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C9—H9a⋯Cg1i	0.97	2.75	3.623 (9)	150
C11—H11⋯Cg2ii	0.94	2.78	3.619 (7)	150

Symmetry codes: (i) ; (ii) .