[μ-1,1'-Bis(diphenyl-phosphino)ferrocene-κP:P']bis-{[(Z)-O-isopropyl-N-(4-methyl-phen-yl)thio-carbamato-κS]gold(I)}.

In the title compound, [Au(2)Fe(C(11)H(14)NOS)(2)(C(17)H(14)P)(2)], the Fe(II) atom is located on a crystallographic centre of inversion. For the Au(I) atom, the deviation from linearity defined by its S,P-donor set [S-Au-P = 178.17 (8) Å] is due to an intra-molecular Au⋯O contact [3.079 (4) Å]. In the crystal, supra-molecular chains mediated by C-H⋯N inter-actions are formed, which run parallel to [001].

Related literature

For structural systematics and luminescence properties of <span class="Chemical">phosphinegold(I) carbonimidothio­ates, see: Ho et al. (2006 ▶); Ho & Tiekink (2007 ▶); Kuan et al. (2008 ▶). For the synthesis, see Hall et al. (1993 ▶). For a related structure, see Ho & Tiekink (2009 ▶).

Experimental

Crystal data

<span class="Chemical">[Au2Fe(C11H14NOS)2(C17H14P)2]

M = 1364.87

Trin class="Chemical">clinin class="Chemical">c,

a = 8.1631 (9) Å

b = 13.4959 (14) Å

n class="Chemical">c = 13.5154 (14) Å

α = 107.440 (2)°

β = 97.401 (2)°

γ = 106.366 (2)°

V = 1325.5 (2) Å3

Z = 1

Mo Kα radiation

μ = 5.97 mm−1

T = 223 K

0.21 × 0.07 × 0.04 mm

Data collection

Bruker SMART CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T min = 0.629, T max = 1

7710 measured reflen class="Chemical">ctionpan>s

4651 independent reflen class="Chemical">ctions

3790 reflen class="Chemical">ctionpan>s with I > 2σ(I)

R int = 0.036

Refinement

R[F 2 > 2σ(F 2)] = 0.040

wR(F 2) = 0.088

S = 0.98

4651 reflen class="Chemical">ctionpan>s

305 parameters

H-atom parameters n class="Chemical">conpan>strainpan>ed

Δρmax = 1.74 e Å−3

Δρmin = −0.93 e Å−3

Data n class="Chemical">collepan> class="Chemical">ction: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809047898/hb5221sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809047898/hb5221Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Au2Fe(C11H14NOS)2(C17H14P)2]	Z = 1
Mr = 1364.87	F(000) = 668
Triclinic, P1	Dx = 1.710 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71069 Å
a = 8.1631 (9) Å	Cell parameters from 2346 reflections
b = 13.4959 (14) Å	θ = 2.7–30.0°
c = 13.5154 (14) Å	µ = 5.97 mm−1
α = 107.440 (2)°	T = 223 K
β = 97.401 (2)°	Block, orange
γ = 106.366 (2)°	0.21 × 0.07 × 0.04 mm
V = 1325.5 (2) Å3

Bruker SMART CCD diffractometer	4651 independent reflections
Radiation source: fine-focus sealed tube	3790 reflections with I > 2σ(I)
graphite	Rint = 0.036
ω scans	θmax = 25.0°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −9→5
Tmin = 0.629, Tmax = 1	k = −16→15
7710 measured reflections	l = −15→16

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.040	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.088	H-atom parameters constrained
S = 0.98	w = 1/[σ2(Fo2) + (0.0429P)2] where P = (Fo2 + 2Fc2)/3
4651 reflections	(Δ/σ)max < 0.001
305 parameters	Δρmax = 1.74 e Å−3
0 restraints	Δρmin = −0.93 e Å−3

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Au	0.13463 (4)	0.49437 (2)	0.20439 (2)	0.03125 (11)
Fe	0.5000	0.5000	0.0000	0.0270 (3)
S1	0.1355 (3)	0.63009 (17)	0.35458 (14)	0.0434 (5)
P1	0.1284 (2)	0.35677 (14)	0.05834 (13)	0.0266 (4)
O1	0.4456 (6)	0.6118 (4)	0.4008 (3)	0.0351 (11)
N1	0.3945 (9)	0.7445 (5)	0.5308 (5)	0.0457 (17)
C1	0.3418 (10)	0.6707 (6)	0.4401 (6)	0.0382 (18)
C2	0.2892 (11)	0.8073 (7)	0.5704 (6)	0.046 (2)
C3	0.2959 (12)	0.8999 (7)	0.5460 (7)	0.057 (2)
H3	0.3647	0.9185	0.4993	0.069*
C4	0.2016 (12)	0.9663 (7)	0.5898 (7)	0.059 (2)
H4	0.2036	1.0270	0.5689	0.071*
C5	0.1061 (12)	0.9464 (8)	0.6622 (6)	0.056 (2)
C6	0.1049 (13)	0.8551 (9)	0.6871 (6)	0.062 (3)
H6	0.0406	0.8381	0.7363	0.075*
C7	0.1941 (12)	0.7875 (8)	0.6427 (7)	0.056 (2)
H7	0.1897	0.7259	0.6625	0.068*
C8	0.0014 (15)	1.0160 (9)	0.7055 (8)	0.087 (4)
H8A	−0.1098	0.9924	0.6548	0.130*
H8B	0.0657	1.0926	0.7178	0.130*
H8C	−0.0201	1.0084	0.7723	0.130*
C9	0.6271 (10)	0.6486 (7)	0.4650 (6)	0.046 (2)
H9	0.6256	0.6677	0.5414	0.055*
C10	0.6848 (11)	0.5484 (7)	0.4295 (6)	0.047 (2)
H10A	0.6075	0.4880	0.4441	0.071*
H10B	0.8042	0.5666	0.4682	0.071*
H10C	0.6794	0.5267	0.3536	0.071*
C11	0.7391 (11)	0.7471 (7)	0.4477 (7)	0.060 (2)
H11A	0.6955	0.8079	0.4726	0.091*
H11B	0.7357	0.7298	0.3723	0.091*
H11C	0.8590	0.7680	0.4870	0.091*
C12	0.2458 (8)	0.4006 (5)	−0.0322 (5)	0.0263 (15)
C13	0.2562 (9)	0.5014 (6)	−0.0501 (5)	0.0329 (16)
H13	0.2079	0.5535	−0.0145	0.039*
C14	0.3500 (10)	0.5101 (7)	−0.1288 (6)	0.044 (2)
H14	0.3747	0.5680	−0.1558	0.053*
C15	0.4004 (10)	0.4153 (7)	−0.1600 (5)	0.045 (2)
H15	0.4655	0.3996	−0.2116	0.054*
C16	0.3375 (9)	0.3480 (6)	−0.1013 (5)	0.0354 (17)
H16	0.3534	0.2804	−0.1070	0.043*
C17	−0.0903 (8)	0.2718 (5)	−0.0236 (5)	0.0267 (15)
C18	−0.2168 (10)	0.2284 (6)	0.0247 (6)	0.0423 (19)
H18	−0.1893	0.2431	0.0985	0.051*
C19	−0.3841 (11)	0.1631 (7)	−0.0356 (8)	0.058 (2)
H19	−0.4695	0.1317	−0.0030	0.070*
C20	−0.4260 (11)	0.1439 (7)	−0.1435 (8)	0.057 (2)
H20	−0.5399	0.0997	−0.1843	0.068*
C21	−0.3025 (11)	0.1890 (6)	−0.1906 (7)	0.049 (2)
H21	−0.3323	0.1767	−0.2638	0.059*
C22	−0.1347 (10)	0.2522 (6)	−0.1327 (6)	0.0384 (18)
H22	−0.0499	0.2822	−0.1663	0.046*
C23	0.2152 (8)	0.2599 (5)	0.0958 (5)	0.0294 (15)
C24	0.3196 (10)	0.2918 (7)	0.1944 (6)	0.0423 (19)
H24	0.3507	0.3648	0.2416	0.051*
C25	0.3806 (12)	0.2174 (8)	0.2258 (7)	0.059 (2)
H25	0.4512	0.2398	0.2946	0.070*
C26	0.3391 (12)	0.1131 (8)	0.1582 (7)	0.056 (2)
H26	0.3840	0.0639	0.1797	0.067*
C27	0.2318 (10)	0.0772 (6)	0.0580 (7)	0.048 (2)
H27	0.2006	0.0036	0.0119	0.057*
C28	0.1709 (9)	0.1516 (6)	0.0263 (6)	0.0400 (18)
H28	0.0993	0.1289	−0.0422	0.048*

	U11	U22	U33	U12	U13	U23
Au	0.02798 (16)	0.03521 (17)	0.02566 (15)	0.00940 (12)	0.00453 (10)	0.00587 (11)
Fe	0.0229 (7)	0.0322 (8)	0.0227 (6)	0.0055 (6)	0.0028 (5)	0.0098 (6)
S1	0.0352 (11)	0.0527 (12)	0.0320 (9)	0.0184 (10)	0.0026 (8)	−0.0004 (9)
P1	0.0224 (9)	0.0272 (9)	0.0276 (9)	0.0064 (8)	0.0042 (7)	0.0086 (8)
O1	0.028 (3)	0.042 (3)	0.029 (2)	0.014 (2)	0.000 (2)	0.005 (2)
N1	0.046 (4)	0.048 (4)	0.033 (3)	0.020 (3)	−0.002 (3)	0.003 (3)
C1	0.040 (4)	0.035 (4)	0.033 (4)	0.003 (4)	0.003 (3)	0.015 (4)
C2	0.048 (5)	0.054 (5)	0.025 (4)	0.019 (4)	0.000 (4)	0.003 (4)
C3	0.064 (6)	0.051 (5)	0.056 (5)	0.016 (5)	0.028 (5)	0.016 (5)
C4	0.065 (6)	0.040 (5)	0.063 (6)	0.016 (5)	0.013 (5)	0.008 (4)
C5	0.054 (6)	0.068 (6)	0.027 (4)	0.018 (5)	−0.002 (4)	−0.005 (4)
C6	0.063 (6)	0.092 (8)	0.034 (4)	0.027 (6)	0.015 (4)	0.023 (5)
C7	0.053 (5)	0.075 (6)	0.050 (5)	0.032 (5)	0.005 (4)	0.028 (5)
C8	0.086 (8)	0.099 (8)	0.053 (6)	0.048 (7)	0.003 (6)	−0.015 (6)
C9	0.036 (4)	0.058 (5)	0.031 (4)	0.008 (4)	−0.002 (3)	0.011 (4)
C10	0.044 (5)	0.070 (6)	0.034 (4)	0.027 (4)	0.007 (4)	0.021 (4)
C11	0.043 (5)	0.051 (5)	0.064 (6)	−0.001 (4)	−0.001 (4)	0.009 (5)
C12	0.023 (3)	0.025 (3)	0.027 (3)	0.006 (3)	0.001 (3)	0.007 (3)
C13	0.025 (4)	0.037 (4)	0.035 (4)	0.010 (3)	−0.002 (3)	0.016 (3)
C14	0.043 (5)	0.055 (5)	0.032 (4)	0.007 (4)	−0.002 (4)	0.023 (4)
C15	0.037 (4)	0.064 (6)	0.018 (3)	0.002 (4)	0.005 (3)	0.007 (4)
C16	0.032 (4)	0.037 (4)	0.030 (4)	0.009 (3)	0.005 (3)	0.006 (3)
C17	0.026 (4)	0.016 (3)	0.037 (4)	0.007 (3)	0.003 (3)	0.009 (3)
C18	0.036 (4)	0.044 (5)	0.053 (5)	0.014 (4)	0.019 (4)	0.022 (4)
C19	0.036 (5)	0.044 (5)	0.104 (8)	0.011 (4)	0.029 (5)	0.035 (5)
C20	0.025 (4)	0.042 (5)	0.088 (7)	0.006 (4)	−0.009 (5)	0.016 (5)
C21	0.036 (5)	0.045 (5)	0.049 (5)	0.009 (4)	−0.011 (4)	0.006 (4)
C22	0.036 (4)	0.038 (4)	0.037 (4)	0.012 (4)	0.006 (3)	0.009 (3)
C23	0.018 (3)	0.028 (4)	0.035 (4)	−0.002 (3)	0.007 (3)	0.011 (3)
C24	0.041 (5)	0.054 (5)	0.036 (4)	0.021 (4)	0.007 (3)	0.019 (4)
C25	0.072 (6)	0.087 (7)	0.041 (5)	0.051 (6)	0.015 (4)	0.032 (5)
C26	0.066 (6)	0.070 (6)	0.072 (6)	0.045 (5)	0.037 (5)	0.052 (6)
C27	0.040 (5)	0.031 (4)	0.074 (6)	0.004 (4)	0.019 (4)	0.026 (4)
C28	0.025 (4)	0.037 (4)	0.052 (5)	0.004 (3)	0.003 (3)	0.017 (4)

Au—S1	2.2883 (19)	C10—H10A	0.9700
Au—P1	2.2520 (17)	C10—H10B	0.9700
Fe—C13i	2.025 (6)	C10—H10C	0.9700
Fe—C13	2.025 (6)	C11—H11A	0.9700
Fe—C12	2.036 (6)	C11—H11B	0.9700
Fe—C12i	2.036 (6)	C11—H11C	0.9700
Fe—C16	2.039 (7)	C12—C16	1.420 (9)
Fe—C16i	2.039 (7)	C12—C13	1.433 (9)
Fe—C15	2.046 (7)	C13—C14	1.403 (10)
Fe—C15i	2.046 (7)	C13—H13	0.9400
Fe—C14i	2.059 (7)	C14—C15	1.416 (11)
Fe—C14	2.059 (7)	C14—H14	0.9400
S1—C1	1.753 (7)	C15—C16	1.411 (10)
P1—C12	1.784 (7)	C15—H15	0.9400
P1—C23	1.814 (7)	C16—H16	0.9400
P1—C17	1.818 (6)	C17—C18	1.377 (10)
O1—C1	1.370 (9)	C17—C22	1.396 (9)
O1—C9	1.479 (8)	C18—C19	1.382 (11)
N1—C1	1.253 (9)	C18—H18	0.9400
N1—C2	1.415 (10)	C19—C20	1.381 (13)
C2—C7	1.365 (12)	C19—H19	0.9400
C2—C3	1.373 (11)	C20—C21	1.358 (12)
C3—C4	1.390 (12)	C20—H20	0.9400
C3—H3	0.9400	C21—C22	1.371 (10)
C4—C5	1.369 (12)	C21—H21	0.9400
C4—H4	0.9400	C22—H22	0.9400
C5—C6	1.369 (13)	C23—C24	1.358 (9)
C5—C8	1.485 (12)	C23—C28	1.393 (10)
C6—C7	1.372 (12)	C24—C25	1.386 (10)
C6—H6	0.9400	C24—H24	0.9400
C7—H7	0.9400	C25—C26	1.346 (12)
C8—H8A	0.9700	C25—H25	0.9400
C8—H8B	0.9700	C26—C27	1.378 (12)
C8—H8C	0.9700	C26—H26	0.9400
C9—C11	1.488 (11)	C27—C28	1.387 (10)
C9—C10	1.519 (10)	C27—H27	0.9400
C9—H9	0.9900	C28—H28	0.9400
P1—Au—S1	178.17 (8)	O1—C9—C10	104.7 (6)
C13i—Fe—C13	180.0	C11—C9—C10	113.9 (7)
C13i—Fe—C12	138.7 (3)	O1—C9—H9	109.3
C13—Fe—C12	41.3 (3)	C11—C9—H9	109.3
C13i—Fe—C12i	41.3 (3)	C10—C9—H9	109.3
C13—Fe—C12i	138.7 (3)	C9—C10—H10A	109.5
C12—Fe—C12i	180.0	C9—C10—H10B	109.5
C13i—Fe—C16	111.4 (3)	H10A—C10—H10B	109.5
C13—Fe—C16	68.6 (3)	C9—C10—H10C	109.5
C12—Fe—C16	40.8 (3)	H10A—C10—H10C	109.5
C12i—Fe—C16	139.2 (3)	H10B—C10—H10C	109.5
C13i—Fe—C16i	68.6 (3)	C9—C11—H11A	109.5
C13—Fe—C16i	111.4 (3)	C9—C11—H11B	109.5
C12—Fe—C16i	139.2 (3)	H11A—C11—H11B	109.5
C12i—Fe—C16i	40.8 (3)	C9—C11—H11C	109.5
C16—Fe—C16i	180.0 (4)	H11A—C11—H11C	109.5
C13i—Fe—C15	112.4 (3)	H11B—C11—H11C	109.5
C13—Fe—C15	67.6 (3)	C16—C12—C13	106.7 (6)
C12—Fe—C15	68.2 (3)	C16—C12—P1	130.5 (5)
C12i—Fe—C15	111.8 (3)	C13—C12—P1	122.8 (5)
C16—Fe—C15	40.4 (3)	C16—C12—Fe	69.7 (4)
C16i—Fe—C15	139.6 (3)	C13—C12—Fe	68.9 (4)
C13i—Fe—C15i	67.6 (3)	P1—C12—Fe	127.9 (3)
C13—Fe—C15i	112.4 (3)	C14—C13—C12	109.3 (7)
C12—Fe—C15i	111.8 (3)	C14—C13—Fe	71.2 (4)
C12i—Fe—C15i	68.2 (3)	C12—C13—Fe	69.7 (4)
C16—Fe—C15i	139.6 (3)	C14—C13—H13	125.4
C16i—Fe—C15i	40.4 (3)	C12—C13—H13	125.4
C15—Fe—C15i	180.0 (2)	Fe—C13—H13	125.3
C13i—Fe—C14i	40.2 (3)	C13—C14—C15	107.0 (7)
C13—Fe—C14i	139.8 (3)	C13—C14—Fe	68.6 (4)
C12—Fe—C14i	111.2 (3)	C15—C14—Fe	69.3 (4)
C12i—Fe—C14i	68.8 (3)	C13—C14—H14	126.5
C16—Fe—C14i	111.6 (3)	C15—C14—H14	126.5
C16i—Fe—C14i	68.4 (3)	Fe—C14—H14	127.1
C15—Fe—C14i	139.6 (3)	C16—C15—C14	109.2 (7)
C15i—Fe—C14i	40.4 (3)	C16—C15—Fe	69.5 (4)
C13i—Fe—C14	139.8 (3)	C14—C15—Fe	70.3 (4)
C13—Fe—C14	40.2 (3)	C16—C15—H15	125.4
C12—Fe—C14	68.8 (3)	C14—C15—H15	125.4
C12i—Fe—C14	111.2 (3)	Fe—C15—H15	126.3
C16—Fe—C14	68.4 (3)	C15—C16—C12	107.9 (7)
C16i—Fe—C14	111.6 (3)	C15—C16—Fe	70.1 (4)
C15—Fe—C14	40.4 (3)	C12—C16—Fe	69.5 (4)
C15i—Fe—C14	139.6 (3)	C15—C16—H16	126.0
C14i—Fe—C14	180.000 (1)	C12—C16—H16	126.0
C1—S1—Au	105.7 (3)	Fe—C16—H16	126.0
C12—P1—C23	108.0 (3)	C18—C17—C22	119.3 (7)
C12—P1—C17	104.2 (3)	C18—C17—P1	118.6 (5)
C23—P1—C17	104.0 (3)	C22—C17—P1	122.1 (6)
C12—P1—Au	114.8 (2)	C17—C18—C19	119.9 (8)
C23—P1—Au	110.6 (2)	C17—C18—H18	120.0
C17—P1—Au	114.5 (2)	C19—C18—H18	120.0
C1—O1—C9	116.5 (5)	C20—C19—C18	120.1 (8)
C1—N1—C2	120.7 (7)	C20—C19—H19	120.0
N1—C1—O1	120.6 (7)	C18—C19—H19	120.0
N1—C1—S1	125.4 (6)	C21—C20—C19	120.0 (8)
O1—C1—S1	114.0 (5)	C21—C20—H20	120.0
C7—C2—C3	117.1 (8)	C19—C20—H20	120.0
C7—C2—N1	122.6 (8)	C20—C21—C22	120.8 (8)
C3—C2—N1	119.9 (8)	C20—C21—H21	119.6
C2—C3—C4	120.5 (9)	C22—C21—H21	119.6
C2—C3—H3	119.7	C21—C22—C17	119.8 (8)
C4—C3—H3	119.7	C21—C22—H22	120.1
C5—C4—C3	122.4 (9)	C17—C22—H22	120.1
C5—C4—H4	118.8	C24—C23—C28	119.2 (7)
C3—C4—H4	118.8	C24—C23—P1	119.8 (5)
C6—C5—C4	115.9 (9)	C28—C23—P1	121.0 (5)
C6—C5—C8	122.3 (10)	C23—C24—C25	120.4 (8)
C4—C5—C8	121.7 (10)	C23—C24—H24	119.8
C5—C6—C7	122.3 (9)	C25—C24—H24	119.8
C5—C6—H6	118.8	C26—C25—C24	120.2 (8)
C7—C6—H6	118.8	C26—C25—H25	119.9
C2—C7—C6	121.7 (9)	C24—C25—H25	119.9
C2—C7—H7	119.1	C25—C26—C27	121.1 (7)
C6—C7—H7	119.1	C25—C26—H26	119.5
C5—C8—H8A	109.5	C27—C26—H26	119.5
C5—C8—H8B	109.5	C26—C27—C28	118.7 (8)
H8A—C8—H8B	109.5	C26—C27—H27	120.6
C5—C8—H8C	109.5	C28—C27—H27	120.6
H8A—C8—H8C	109.5	C27—C28—C23	120.3 (7)
H8B—C8—H8C	109.5	C27—C28—H28	119.9
O1—C9—C11	110.2 (6)	C23—C28—H28	119.9
C2—N1—C1—O1	178.4 (7)	C16—Fe—C14—C13	81.9 (5)
C2—N1—C1—S1	−3.5 (11)	C16i—Fe—C14—C13	−98.1 (5)
C9—O1—C1—N1	−6.9 (10)	C15—Fe—C14—C13	118.9 (6)
C9—O1—C1—S1	174.8 (5)	C15i—Fe—C14—C13	−61.1 (6)
Au—S1—C1—N1	179.4 (6)	C13i—Fe—C14—C15	61.1 (6)
Au—S1—C1—O1	−2.4 (6)	C13—Fe—C14—C15	−118.9 (6)
C1—N1—C2—C7	101.8 (9)	C12—Fe—C14—C15	−80.9 (5)
C1—N1—C2—C3	−85.8 (10)	C12i—Fe—C14—C15	99.1 (5)
C7—C2—C3—C4	−3.1 (13)	C16—Fe—C14—C15	−37.0 (4)
N1—C2—C3—C4	−175.9 (7)	C16i—Fe—C14—C15	143.0 (4)
C2—C3—C4—C5	3.3 (14)	C15i—Fe—C14—C15	180.0
C3—C4—C5—C6	−1.7 (13)	C13—C14—C15—C16	0.3 (8)
C3—C4—C5—C8	−178.0 (9)	Fe—C14—C15—C16	58.8 (5)
C4—C5—C6—C7	0.2 (13)	C13—C14—C15—Fe	−58.5 (5)
C8—C5—C6—C7	176.4 (8)	C13i—Fe—C15—C16	97.3 (5)
C3—C2—C7—C6	1.7 (12)	C13—Fe—C15—C16	−82.7 (5)
N1—C2—C7—C6	174.3 (8)	C12—Fe—C15—C16	−38.0 (4)
C5—C6—C7—C2	−0.3 (14)	C12i—Fe—C15—C16	142.0 (4)
C1—O1—C9—C11	−78.4 (8)	C14i—Fe—C15—C16	59.6 (6)
C1—O1—C9—C10	158.6 (6)	C14—Fe—C15—C16	−120.4 (6)
C23—P1—C12—C16	24.5 (7)	C13i—Fe—C15—C14	−142.3 (4)
C17—P1—C12—C16	−85.7 (6)	C13—Fe—C15—C14	37.7 (4)
Au—P1—C12—C16	148.3 (5)	C12—Fe—C15—C14	82.4 (5)
C23—P1—C12—C13	−158.2 (5)	C12i—Fe—C15—C14	−97.6 (5)
C17—P1—C12—C13	91.7 (5)	C16—Fe—C15—C14	120.4 (6)
Au—P1—C12—C13	−34.4 (6)	C16i—Fe—C15—C14	−59.6 (6)
C23—P1—C12—Fe	−70.5 (5)	C14—C15—C16—C12	0.1 (8)
C17—P1—C12—Fe	179.3 (4)	Fe—C15—C16—C12	59.4 (5)
Au—P1—C12—Fe	53.3 (4)	C14—C15—C16—Fe	−59.3 (5)
C13i—Fe—C12—C16	−62.0 (6)	C13—C12—C16—C15	−0.5 (7)
C13—Fe—C12—C16	118.0 (6)	P1—C12—C16—C15	177.2 (5)
C16i—Fe—C12—C16	180.0	Fe—C12—C16—C15	−59.8 (5)
C15—Fe—C12—C16	37.6 (4)	C13—C12—C16—Fe	59.3 (4)
C15i—Fe—C12—C16	−142.4 (4)	P1—C12—C16—Fe	−123.0 (6)
C14i—Fe—C12—C16	−98.9 (4)	C13i—Fe—C16—C15	−99.8 (5)
C14—Fe—C12—C16	81.1 (4)	C13—Fe—C16—C15	80.2 (5)
C13i—Fe—C12—C13	180.0	C12—Fe—C16—C15	119.0 (6)
C16—Fe—C12—C13	−118.0 (6)	C12i—Fe—C16—C15	−61.0 (6)
C16i—Fe—C12—C13	62.0 (6)	C14i—Fe—C16—C15	−143.1 (5)
C15—Fe—C12—C13	−80.4 (4)	C14—Fe—C16—C15	36.9 (5)
C15i—Fe—C12—C13	99.6 (4)	C13i—Fe—C16—C12	141.2 (4)
C14i—Fe—C12—C13	143.1 (4)	C13—Fe—C16—C12	−38.8 (4)
C14—Fe—C12—C13	−36.9 (4)	C12i—Fe—C16—C12	180.0
C13i—Fe—C12—P1	64.2 (6)	C15—Fe—C16—C12	−119.0 (6)
C13—Fe—C12—P1	−115.8 (6)	C15i—Fe—C16—C12	61.0 (6)
C16—Fe—C12—P1	126.1 (6)	C14i—Fe—C16—C12	97.9 (4)
C16i—Fe—C12—P1	−53.9 (6)	C14—Fe—C16—C12	−82.1 (4)
C15—Fe—C12—P1	163.8 (5)	C12—P1—C17—C18	−177.4 (5)
C15i—Fe—C12—P1	−16.2 (5)	C23—P1—C17—C18	69.6 (6)
C14i—Fe—C12—P1	27.3 (5)	Au—P1—C17—C18	−51.2 (6)
C14—Fe—C12—P1	−152.7 (5)	C12—P1—C17—C22	0.7 (6)
C16—C12—C13—C14	0.7 (7)	C23—P1—C17—C22	−112.3 (6)
P1—C12—C13—C14	−177.2 (5)	Au—P1—C17—C22	126.9 (5)
Fe—C12—C13—C14	60.5 (5)	C22—C17—C18—C19	2.1 (10)
C16—C12—C13—Fe	−59.8 (4)	P1—C17—C18—C19	−179.7 (6)
P1—C12—C13—Fe	122.3 (5)	C17—C18—C19—C20	−1.8 (12)
C12—Fe—C13—C14	−119.8 (6)	C18—C19—C20—C21	0.2 (13)
C12i—Fe—C13—C14	60.2 (6)	C19—C20—C21—C22	1.1 (12)
C16—Fe—C13—C14	−81.5 (5)	C20—C21—C22—C17	−0.8 (12)
C16i—Fe—C13—C14	98.5 (5)	C18—C17—C22—C21	−0.8 (10)
C15—Fe—C13—C14	−37.8 (5)	P1—C17—C22—C21	−178.9 (6)
C15i—Fe—C13—C14	142.2 (5)	C12—P1—C23—C24	106.1 (6)
C14i—Fe—C13—C14	180.0	C17—P1—C23—C24	−143.6 (6)
C12i—Fe—C13—C12	180.0	Au—P1—C23—C24	−20.2 (6)
C16—Fe—C13—C12	38.3 (4)	C12—P1—C23—C28	−76.4 (6)
C16i—Fe—C13—C12	−141.7 (4)	C17—P1—C23—C28	33.9 (7)
C15—Fe—C13—C12	82.0 (4)	Au—P1—C23—C28	157.3 (5)
C15i—Fe—C13—C12	−98.0 (4)	C28—C23—C24—C25	−0.3 (12)
C14i—Fe—C13—C12	−60.2 (6)	P1—C23—C24—C25	177.2 (6)
C14—Fe—C13—C12	119.8 (6)	C23—C24—C25—C26	1.0 (13)
C12—C13—C14—C15	−0.6 (7)	C24—C25—C26—C27	−1.8 (14)
Fe—C13—C14—C15	59.0 (5)	C25—C26—C27—C28	1.9 (13)
C12—C13—C14—Fe	−59.6 (4)	C26—C27—C28—C23	−1.2 (12)
C13i—Fe—C14—C13	180.0	C24—C23—C28—C27	0.4 (11)
C12—Fe—C14—C13	37.9 (4)	P1—C23—C28—C27	−177.0 (6)
C12i—Fe—C14—C13	−142.1 (4)

D—H···A	D—H	H···A	D···A	D—H···A
C25—H25···N1ii	0.94	2.45	3.370 (11)	167

Table 1

Selected bond lengths (Å)

Au—S1	2.2883 (19)
Au—P1	2.2520 (17)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C25—H25⋯N1i	0.94	2.45	3.370 (11)	167

Symmetry code: (i) .