2-Methyl-piperazinediium tetra-chlorido-zincate(II).

The asymmetric unit of the title compound, (C(5)H(14)N(2))[ZnCl(4)], consists of a diprotonated 2-methyl-piperazine cation and a tetra-chloridozincate anion. The Zn(II) ion is in a slightly distorted tetra-hedral coordination environment. The six-membered piperazine ring adopts a chair conformation. The crystal structure is stabilized by inter-molecular N-H⋯Cl hydrogen bonds.

Related literature

For ferroelectricity in coordination polymers, see: Fu et al. (2007 ▶). For nonlinear optical second harmonic generation induced by coordination polymers, see: Qu et al. (2003 ▶). For transition-metal complexes of (R)-2-methyl­piperazine, see: Ye et al. (2009 ▶).

Experimental

Crystal data

(C5H14N2)[ZnCl4]

M = 309.35

Monoclinic,

a = 8.4183 (17) Å

b = 14.939 (3) Å

c = 9.830 (2) Å

β = 90.35 (3)°

V = 1236.3 (4) Å3

Z = 4

Mo Kα radiation

μ = 2.81 mm−1

T = 291 K

0.35 × 0.25 × 0.15 mm

Data collection

Rigaku SCXmini CCD diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku, 2005 ▶) T min = 0.440, T max = 0.678

11203 measured reflections

2423 independent reflections

2112 reflections with I > 2σ(I)

R int = 0.045

Refinement

R[F 2 > 2σ(F 2)] = 0.037

wR(F 2) = 0.088

S = 1.11

2423 reflections

110 parameters

H-atom parameters constrained

Δρmax = 0.67 e Å−3

Δρmin = −0.45 e Å−3

Data collection: CrystalClear (Rigaku, 2005 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶) and DIAMOND (Brandenburg, 1999 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536810012547/hy2296sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536810012547/hy2296Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

(C5H14N2)[ZnCl4]	F(000) = 624
Mr = 309.35	Dx = 1.662 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 2112 reflections
a = 8.4183 (17) Å	θ = 3.2–26.0°
b = 14.939 (3) Å	µ = 2.81 mm−1
c = 9.830 (2) Å	T = 291 K
β = 90.35 (3)°	Block, colorless
V = 1236.3 (4) Å3	0.35 × 0.25 × 0.15 mm
Z = 4

Rigaku SCXmini CCD diffractometer	2423 independent reflections
Radiation source: fine-focus sealed tube	2112 reflections with I > 2σ(I)
graphite	Rint = 0.045
Detector resolution: 13.6612 pixels mm-1	θmax = 26.0°, θmin = 3.2°
ω scans	h = −10→10
Absorption correction: multi-scan (CrystalClear; Rigaku, 2005)	k = −18→18
Tmin = 0.440, Tmax = 0.678	l = −12→12
11203 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.037	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.088	H-atom parameters constrained
S = 1.11	w = 1/[σ2(Fo2) + (0.0275P)2 + 1.3805P] where P = (Fo2 + 2Fc2)/3
2423 reflections	(Δ/σ)max < 0.001
110 parameters	Δρmax = 0.67 e Å−3
0 restraints	Δρmin = −0.45 e Å−3

	x	y	z	Uiso*/Ueq
C1	0.3285 (4)	0.0505 (2)	0.7709 (4)	0.0525 (9)
H1C	0.3682	0.0101	0.8405	0.063*
H1D	0.3282	0.0188	0.6848	0.063*
C2	0.4331 (4)	0.1290 (3)	0.7618 (4)	0.0518 (9)
H2C	0.5384	0.1101	0.7346	0.062*
H2D	0.4419	0.1571	0.8505	0.062*
C3	0.2019 (3)	0.2241 (2)	0.6920 (3)	0.0373 (7)
H3	0.2013	0.2560	0.7791	0.045*
C4	0.0994 (4)	0.1433 (2)	0.7029 (4)	0.0429 (8)
H4A	0.0917	0.1145	0.6147	0.051*
H4B	−0.0066	0.1613	0.7297	0.051*
C5	0.1468 (4)	0.2868 (2)	0.5815 (4)	0.0521 (9)
H5A	0.1518	0.2569	0.4952	0.078*
H5B	0.2141	0.3386	0.5801	0.078*
H5C	0.0393	0.3047	0.5988	0.078*
Cl1	0.20460 (10)	−0.02794 (6)	0.10506 (9)	0.0464 (2)
Cl2	0.19838 (10)	0.21504 (6)	0.07287 (9)	0.0490 (2)
Cl3	−0.04089 (10)	0.10987 (6)	0.33241 (9)	0.0470 (2)
Cl4	0.40648 (12)	0.10940 (8)	0.37036 (10)	0.0670 (3)
N1	0.1644 (3)	0.07835 (19)	0.8046 (3)	0.0428 (7)
H1A	0.1639	0.1037	0.8877	0.051*
H1B	0.1013	0.0297	0.8072	0.051*
N2	0.3697 (3)	0.19527 (18)	0.6611 (3)	0.0379 (6)
H2A	0.3721	0.1708	0.5775	0.046*
H2B	0.4330	0.2438	0.6607	0.046*
Zn1	0.19783 (4)	0.10028 (3)	0.22722 (4)	0.03895 (14)

	U11	U22	U33	U12	U13	U23
C1	0.056 (2)	0.043 (2)	0.059 (2)	0.0128 (17)	0.0036 (19)	0.0120 (17)
C2	0.0327 (18)	0.066 (2)	0.057 (2)	0.0041 (16)	−0.0075 (16)	0.0141 (19)
C3	0.0335 (16)	0.0407 (18)	0.0376 (17)	0.0001 (13)	0.0016 (14)	0.0058 (14)
C4	0.0302 (16)	0.050 (2)	0.049 (2)	−0.0042 (14)	0.0006 (14)	0.0125 (16)
C5	0.048 (2)	0.050 (2)	0.058 (2)	0.0058 (16)	−0.0006 (18)	0.0196 (18)
Cl1	0.0528 (5)	0.0424 (5)	0.0441 (5)	0.0075 (4)	0.0048 (4)	−0.0056 (4)
Cl2	0.0456 (5)	0.0490 (5)	0.0527 (5)	0.0104 (4)	0.0109 (4)	0.0079 (4)
Cl3	0.0396 (4)	0.0540 (5)	0.0474 (5)	0.0026 (4)	0.0088 (4)	−0.0057 (4)
Cl4	0.0453 (5)	0.1063 (9)	0.0493 (6)	0.0189 (5)	−0.0136 (4)	−0.0232 (5)
N1	0.0417 (15)	0.0416 (16)	0.0451 (16)	−0.0079 (12)	0.0057 (13)	0.0112 (13)
N2	0.0265 (13)	0.0475 (16)	0.0398 (15)	−0.0088 (11)	0.0010 (11)	0.0074 (12)
Zn1	0.0354 (2)	0.0457 (2)	0.0357 (2)	0.00775 (16)	−0.00171 (16)	−0.00409 (16)

C1—C2	1.470 (5)	C4—H4B	0.9700
C1—N1	1.482 (4)	C5—H5A	0.9600
C1—H1C	0.9700	C5—H5B	0.9600
C1—H1D	0.9700	C5—H5C	0.9600
C2—N2	1.496 (4)	Cl1—Zn1	2.2616 (10)
C2—H2C	0.9700	Cl2—Zn1	2.2895 (10)
C2—H2D	0.9700	Cl3—Zn1	2.2702 (11)
C3—C4	1.487 (4)	Cl4—Zn1	2.2480 (12)
C3—C5	1.505 (4)	N1—H1A	0.9000
C3—N2	1.509 (4)	N1—H1B	0.9000
C3—H3	0.9800	N2—H2A	0.9000
C4—N1	1.495 (4)	N2—H2B	0.9000
C4—H4A	0.9700
C2—C1—N1	110.4 (3)	C3—C5—H5A	109.5
C2—C1—H1C	109.6	C3—C5—H5B	109.5
N1—C1—H1C	109.6	H5A—C5—H5B	109.5
C2—C1—H1D	109.6	C3—C5—H5C	109.5
N1—C1—H1D	109.6	H5A—C5—H5C	109.5
H1C—C1—H1D	108.1	H5B—C5—H5C	109.5
C1—C2—N2	110.9 (3)	C1—N1—C4	111.8 (3)
C1—C2—H2C	109.5	C1—N1—H1A	109.3
N2—C2—H2C	109.5	C4—N1—H1A	109.3
C1—C2—H2D	109.5	C1—N1—H1B	109.3
N2—C2—H2D	109.5	C4—N1—H1B	109.3
H2C—C2—H2D	108.0	H1A—N1—H1B	107.9
C4—C3—C5	112.3 (3)	C2—N2—C3	112.7 (2)
C4—C3—N2	109.1 (3)	C2—N2—H2A	109.0
C5—C3—N2	108.5 (3)	C3—N2—H2A	109.0
C4—C3—H3	109.0	C2—N2—H2B	109.0
C5—C3—H3	109.0	C3—N2—H2B	109.0
N2—C3—H3	109.0	H2A—N2—H2B	107.8
C3—C4—N1	111.4 (3)	Cl4—Zn1—Cl1	111.20 (4)
C3—C4—H4A	109.3	Cl4—Zn1—Cl3	113.67 (4)
N1—C4—H4A	109.3	Cl1—Zn1—Cl3	108.70 (4)
C3—C4—H4B	109.3	Cl4—Zn1—Cl2	111.39 (5)
N1—C4—H4B	109.3	Cl1—Zn1—Cl2	106.39 (4)
H4A—C4—H4B	108.0	Cl3—Zn1—Cl2	105.07 (4)
N1—C1—C2—N2	−55.8 (4)	C3—C4—N1—C1	−57.4 (4)
C5—C3—C4—N1	175.0 (3)	C1—C2—N2—C3	55.8 (4)
N2—C3—C4—N1	54.6 (4)	C4—C3—N2—C2	−54.5 (4)
C2—C1—N1—C4	57.2 (4)	C5—C3—N2—C2	−177.2 (3)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1A···Cl2i	0.90	2.48	3.346 (3)	161
N1—H1B···Cl3ii	0.90	2.55	3.284 (3)	140
N1—H1B···Cl1ii	0.90	2.72	3.322 (3)	125
N2—H2A···Cl4	0.90	2.25	3.150 (3)	174
N2—H2B···Cl2iii	0.90	2.48	3.199 (3)	137
N2—H2B···Cl3iii	0.90	2.77	3.444 (3)	133

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1A⋯Cl2i	0.90	2.48	3.346 (3)	161
N1—H1B⋯Cl3ii	0.90	2.55	3.284 (3)	140
N1—H1B⋯Cl1ii	0.90	2.72	3.322 (3)	125
N2—H2A⋯Cl4	0.90	2.25	3.150 (3)	174
N2—H2B⋯Cl2iii	0.90	2.48	3.199 (3)	137
N2—H2B⋯Cl3iii	0.90	2.77	3.444 (3)	133

Symmetry codes: (i) ; (ii) ; (iii) .