Literature DB >> 21577706

Tetra-kis(6-methyl-2,2'-bipyridine)-1κN,N';2κN,N';3κN,N';4κN,N'-tetra-μ-nitrato-1:2κO:O';2:3κO:O',O'';2:3κO,O':O'';3:4κO:O'-tetra-nitrato-1κO,O';4κO,O'-tetra-lead(II).

Roya Ahmadi, Khadijeh Kalateh, Robabeh Alizadeh, Zeinab Khoshtarkib, Vahid Amani.   

Abstract

In the tetranuclear centrosymmetric title compound, [Pb(4)(NO(3))(8)(C(11)H(10)N(2))(4)], irregular PbN(2)O(5) and PbN(2)O(4) coordination polyhedra occur. The hepta-coordinated lead(II) ion is bonded to two bidentate and one monodentate nitrate ion and one bidentate 6-methyl-2,2'-bipyridine (mbpy) ligand. The six-coordinate lead(II) ion is bonded to one bidentate and two monodentate nitrate anions and one mbpy ligand. In the crystal, bridging nitrate anions lead to infinite chains propagating in [111]. A number of C-H⋯O hydrogen bonds may stabilize the structure.

Entities:  

Year:  2009        PMID： 21577706      PMCID： PMC2970246          DOI： 10.1107/S160053680903459X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For different metal complexes of 6-methyl-2,2′-bipyridine, see: Ahmadi, Kalateh et al. (2008 ▶); Ahmadi, Ebadi et al. (2008 ▶); Newkome et al. (1982 ▶); Onggo et al. (1990 ▶, 2005 ▶).

Experimental

Crystal data

[Pb4(NO3)8(C11H10N2)4] M = 1002.84 Triclinic, a = 11.093 (2) Å b = 11.266 (2) Å c = 12.642 (3) Å α = 109.25 (3)° β = 95.43 (3)° γ = 105.62 (3)° V = 1407.0 (7) Å3 Z = 2 Mo Kα radiation μ = 12.03 mm−1 T = 298 K 0.40 × 0.30 × 0.25 mm

Data collection

Bruker SMART CCD diffractometer Absorption correction: numerical shape of crystal determined optically (X-SHAPE and X-RED32; Stoe & Cie, 2005 ▶) T min = 0.021, T max = 0.052 16752 measured reflections 7561 independent reflections 6277 reflections with I > 2σ(I) R int = 0.089

Refinement

R[F 2 > 2σ(F 2)] = 0.049 wR(F 2) = 0.137 S = 1.10 7561 reflections 397 parameters H-atom parameters constrained Δρmax = 2.18 e Å−3 Δρmin = −2.37 e Å−3 Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT (Bruker, 1998 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: ORTEP-3 (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶). Crystal structure: contains datablocks I, global. DOI: 10.1107/S160053680903459X/hb5028sup1.cif Structure factors: contains datablocks I. DOI: 10.1107/S160053680903459X/hb5028Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report
[Pb4(NO3)8(C11H10N2)4]Z = 2
Mr = 1002.84F(000) = 936
Triclinic, P1Dx = 2.367 Mg m−3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 11.093 (2) ÅCell parameters from 1311 reflections
b = 11.266 (2) Åθ = 1.7–29.2°
c = 12.642 (3) ŵ = 12.03 mm−1
α = 109.25 (3)°T = 298 K
β = 95.43 (3)°Block, colorless
γ = 105.62 (3)°0.40 × 0.30 × 0.25 mm
V = 1407.0 (7) Å3
Bruker SMART CCD diffractometer7561 independent reflections
Radiation source: fine-focus sealed tube6277 reflections with I > 2σ(I)
graphiteRint = 0.089
ω scansθmax = 29.2°, θmin = 1.7°
Absorption correction: numerical shape of crystal determined optically (program? reference?)h = −15→15
Tmin = 0.021, Tmax = 0.052k = −15→14
16752 measured reflectionsl = −17→17
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.049Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.137H-atom parameters constrained
S = 1.10w = 1/[σ2(Fo2) + (0.0636P)2 + 3.7094P] where P = (Fo2 + 2Fc2)/3
7561 reflections(Δ/σ)max = 0.011
397 parametersΔρmax = 2.18 e Å−3
0 restraintsΔρmin = −2.37 e Å−3
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/Ueq
C10.9335 (12)0.7297 (9)0.8235 (9)0.062 (3)
H1A0.92080.69130.74160.074*
H1B1.02340.76290.85580.074*
H1C0.89830.80130.84460.074*
C20.8691 (9)0.6277 (9)0.8670 (7)0.0478 (18)
C30.7749 (12)0.6393 (12)0.9294 (9)0.066 (3)
H30.75150.71590.94850.079*
C40.7160 (12)0.5403 (12)0.9634 (10)0.067 (3)
H40.65030.54761.00320.080*
C50.7530 (10)0.4297 (10)0.9393 (8)0.053 (2)
H50.71420.36190.96360.063*
C60.8491 (8)0.4204 (8)0.8785 (7)0.0412 (15)
C70.8970 (8)0.3056 (8)0.8500 (7)0.0424 (16)
C80.8691 (9)0.2158 (9)0.9059 (9)0.052 (2)
H80.81870.22640.96090.063*
C90.9175 (12)0.1117 (9)0.8781 (10)0.062 (3)
H90.89870.05010.91320.074*
C100.9918 (11)0.0992 (10)0.8002 (10)0.060 (2)
H101.02880.03190.78340.072*
C111.0127 (10)0.1894 (9)0.7449 (9)0.053 (2)
H111.05770.17620.68590.063*
C120.3946 (11)0.3441 (9)0.3475 (10)0.062 (3)
H12A0.38140.31920.26590.075*
H12B0.48340.39130.38050.075*
H12C0.34460.40000.37780.075*
C130.3544 (9)0.2208 (9)0.3761 (8)0.0505 (19)
C140.2605 (10)0.2030 (13)0.4403 (10)0.068 (3)
H140.21930.26600.46460.081*
C150.2295 (11)0.0929 (14)0.4671 (10)0.075 (3)
H150.16640.07980.50940.091*
C160.2915 (9)0.0006 (12)0.4318 (9)0.062 (3)
H160.2723−0.07450.45070.074*
C170.3841 (7)0.0227 (8)0.3667 (7)0.0425 (16)
C180.4550 (8)−0.0716 (8)0.3243 (7)0.0442 (17)
C190.4256 (11)−0.1938 (10)0.3387 (9)0.063 (3)
H190.3604−0.21850.37590.076*
C200.4965 (13)−0.2769 (10)0.2960 (11)0.072 (3)
H200.4774−0.35890.30360.087*
C210.5926 (12)−0.2405 (10)0.2438 (11)0.067 (3)
H210.6405−0.29590.21600.081*
C220.6182 (10)−0.1186 (10)0.2325 (10)0.059 (2)
H220.6836−0.09310.19560.071*
N10.9053 (7)0.5176 (7)0.8420 (6)0.0411 (13)
N20.9713 (8)0.2921 (7)0.7728 (6)0.0477 (16)
N31.2895 (7)0.5378 (9)0.7956 (8)0.057 (2)
N40.9322 (8)0.2233 (8)0.4204 (7)0.0519 (17)
N50.7285 (7)0.3733 (8)0.4898 (6)0.0469 (15)
N60.4148 (6)0.1316 (7)0.3391 (6)0.0410 (13)
N70.5523 (7)−0.0368 (7)0.2727 (6)0.0443 (14)
N80.3510 (8)0.0199 (8)0.0272 (7)0.0505 (16)
O11.2315 (7)0.4180 (7)0.7307 (8)0.071 (2)
O21.2252 (7)0.6164 (7)0.8206 (7)0.0591 (16)
O31.4048 (7)0.5766 (10)0.8320 (9)0.083 (3)
O40.9642 (9)0.3404 (8)0.4264 (7)0.068 (2)
O50.9608 (9)0.2066 (8)0.5144 (8)0.076 (2)
O60.8789 (12)0.1308 (10)0.3342 (9)0.110 (4)
O70.7188 (10)0.4369 (9)0.4276 (8)0.082 (3)
O80.7761 (7)0.4279 (7)0.5941 (6)0.0578 (16)
O90.6873 (7)0.2468 (7)0.4469 (6)0.0612 (17)
O100.3682 (10)0.1365 (8)0.0852 (8)0.077 (3)
O110.4108 (7)−0.0399 (7)0.0670 (7)0.0614 (17)
O120.2747 (8)−0.0373 (8)−0.0665 (7)0.070 (2)
Pb11.02005 (3)0.45241 (3)0.67017 (2)0.04043 (9)
Pb20.58525 (3)0.16179 (3)0.22876 (3)0.04202 (10)
U11U22U33U12U13U23
C10.087 (7)0.044 (5)0.063 (6)0.030 (5)0.012 (5)0.024 (4)
C20.057 (5)0.046 (4)0.046 (4)0.030 (4)0.008 (4)0.014 (3)
C30.086 (8)0.074 (7)0.052 (5)0.049 (6)0.018 (5)0.021 (5)
C40.076 (7)0.081 (7)0.065 (6)0.048 (6)0.041 (5)0.028 (5)
C50.057 (5)0.064 (5)0.048 (4)0.022 (4)0.017 (4)0.029 (4)
C60.045 (4)0.048 (4)0.038 (3)0.021 (3)0.009 (3)0.020 (3)
C70.047 (4)0.040 (4)0.042 (4)0.012 (3)0.011 (3)0.019 (3)
C80.053 (5)0.050 (5)0.067 (5)0.016 (4)0.021 (4)0.036 (4)
C90.079 (7)0.043 (4)0.073 (6)0.019 (5)0.020 (5)0.032 (5)
C100.070 (6)0.043 (4)0.075 (6)0.026 (4)0.017 (5)0.026 (4)
C110.059 (5)0.048 (5)0.061 (5)0.028 (4)0.020 (4)0.022 (4)
C120.068 (6)0.045 (5)0.078 (7)0.035 (4)0.015 (5)0.013 (4)
C130.048 (5)0.050 (5)0.049 (4)0.019 (4)0.008 (4)0.010 (4)
C140.052 (5)0.086 (8)0.067 (6)0.031 (5)0.027 (5)0.019 (6)
C150.056 (6)0.112 (10)0.064 (6)0.025 (6)0.036 (5)0.035 (6)
C160.044 (5)0.080 (7)0.064 (6)0.009 (5)0.018 (4)0.038 (5)
C170.034 (3)0.048 (4)0.044 (4)0.007 (3)0.008 (3)0.021 (3)
C180.040 (4)0.039 (4)0.048 (4)0.003 (3)0.004 (3)0.019 (3)
C190.070 (6)0.053 (5)0.066 (6)0.002 (5)0.007 (5)0.037 (5)
C200.093 (8)0.044 (5)0.082 (7)0.019 (5)−0.008 (6)0.036 (5)
C210.083 (8)0.050 (5)0.080 (7)0.039 (5)0.005 (6)0.027 (5)
C220.053 (5)0.052 (5)0.075 (6)0.026 (4)0.006 (5)0.022 (5)
N10.046 (4)0.040 (3)0.043 (3)0.022 (3)0.010 (3)0.016 (3)
N20.060 (4)0.043 (4)0.045 (4)0.020 (3)0.015 (3)0.018 (3)
N30.038 (4)0.064 (5)0.081 (6)0.012 (3)0.004 (4)0.047 (5)
N40.057 (4)0.054 (4)0.055 (4)0.019 (3)0.021 (3)0.017 (3)
N50.038 (3)0.056 (4)0.049 (4)0.020 (3)0.007 (3)0.019 (3)
N60.035 (3)0.041 (3)0.045 (3)0.012 (3)0.006 (3)0.014 (3)
N70.052 (4)0.036 (3)0.047 (4)0.017 (3)0.011 (3)0.016 (3)
N80.051 (4)0.053 (4)0.050 (4)0.018 (3)0.015 (3)0.020 (3)
O10.054 (4)0.053 (4)0.118 (7)0.021 (3)0.016 (4)0.045 (4)
O20.054 (4)0.053 (4)0.076 (5)0.024 (3)0.017 (3)0.025 (3)
O30.043 (4)0.096 (6)0.111 (7)0.012 (4)0.003 (4)0.053 (6)
O40.088 (6)0.058 (4)0.062 (4)0.015 (4)0.019 (4)0.032 (3)
O50.086 (6)0.066 (5)0.091 (6)0.027 (4)0.019 (5)0.047 (4)
O60.121 (9)0.070 (6)0.086 (7)0.011 (6)0.025 (6)−0.023 (5)
O70.104 (7)0.089 (6)0.081 (6)0.051 (5)0.020 (5)0.051 (5)
O80.052 (4)0.065 (4)0.046 (3)0.019 (3)0.011 (3)0.007 (3)
O90.056 (4)0.063 (4)0.058 (4)0.011 (3)0.009 (3)0.022 (3)
O100.089 (7)0.059 (5)0.078 (5)0.040 (5)−0.004 (5)0.023 (4)
O110.057 (4)0.062 (4)0.075 (5)0.025 (3)0.009 (3)0.033 (4)
O120.062 (4)0.078 (5)0.059 (4)0.015 (4)−0.002 (3)0.021 (4)
Pb10.04429 (17)0.04041 (16)0.04192 (15)0.01671 (12)0.01061 (11)0.01886 (12)
Pb20.04585 (17)0.03412 (15)0.04792 (17)0.01031 (11)0.01553 (12)0.01783 (12)
Pb1—O12.566 (8)C5—C61.379 (14)
Pb1—O22.609 (8)C6—C71.478 (13)
Pb1—O42.851 (8)C7—C81.401 (14)
Pb1—O52.675 (9)C8—C91.375 (16)
Pb1—O82.693 (8)C9—C101.339 (18)
Pb1—N12.618 (8)C10—C111.396 (16)
Pb1—N22.528 (8)C12—C131.512 (15)
Pb2—O92.624 (7)C13—C141.392 (16)
Pb2—O102.763 (11)C14—C151.36 (2)
Pb2—O112.629 (8)C15—C161.375 (18)
Pb2—N62.470 (7)C16—C171.397 (14)
Pb2—N72.422 (8)C17—C181.480 (13)
Pb2—O12i2.910 (9)C18—C191.403 (15)
O1—N31.269 (13)C19—C201.389 (18)
O2—N31.261 (12)C20—C211.348 (19)
O3—N31.222 (12)C21—C221.384 (17)
O4—N41.245 (13)C1—H1A0.9600
O5—N41.287 (13)C1—H1B0.9600
O6—N41.192 (14)C1—H1C0.9600
O7—N51.241 (13)C3—H30.9300
O8—N51.247 (10)C4—H40.9300
O9—N51.275 (12)C5—H50.9300
O10—N81.226 (13)C8—H80.9300
O11—N81.244 (12)C9—H90.9300
O12—N81.244 (12)C10—H100.9300
N1—C21.354 (13)C11—H110.9300
N1—C61.349 (12)C12—H12A0.9600
N2—C71.333 (12)C12—H12B0.9600
N2—C111.312 (14)C12—H12C0.9600
N6—C131.338 (13)C14—H140.9300
N6—C171.350 (12)C15—H150.9300
N7—C181.348 (12)C16—H160.9300
N7—C221.329 (14)C19—H190.9300
C1—C21.477 (15)C20—H200.9300
C2—C31.376 (16)C21—H210.9300
C3—C41.354 (19)C22—H220.9300
C4—C51.365 (18)
O1—Pb1—O249.6 (3)N1—C2—C3119.6 (10)
O1—Pb1—O4105.4 (3)C1—C2—C3123.3 (10)
O1—Pb1—O584.7 (3)C2—C3—C4120.6 (12)
O1—Pb1—O8166.8 (3)C3—C4—C5120.0 (12)
O1—Pb1—N1111.9 (3)C4—C5—C6118.8 (11)
O1—Pb1—N273.1 (3)N1—C6—C5121.1 (9)
O2—Pb1—O4133.0 (3)N1—C6—C7116.2 (8)
O2—Pb1—O5134.1 (3)C5—C6—C7122.7 (9)
O2—Pb1—O8141.9 (2)N2—C7—C6118.4 (8)
O2—Pb1—N183.7 (2)N2—C7—C8120.7 (9)
O2—Pb1—N294.9 (3)C6—C7—C8120.8 (8)
O4—Pb1—O545.5 (3)C7—C8—C9118.9 (10)
O4—Pb1—O871.0 (3)C8—C9—C10119.8 (10)
O4—Pb1—N1140.2 (3)C9—C10—C11118.6 (11)
O4—Pb1—N2116.8 (3)N2—C11—C10122.6 (10)
O5—Pb1—O884.0 (3)N6—C13—C12117.1 (9)
O5—Pb1—N1124.2 (3)N6—C13—C14121.8 (10)
O5—Pb1—N272.2 (3)C12—C13—C14121.1 (10)
O8—Pb1—N169.5 (2)C13—C14—C15119.5 (12)
O8—Pb1—N296.9 (3)C14—C15—C16120.0 (12)
N1—Pb1—N263.9 (3)C15—C16—C17118.2 (12)
O9—Pb2—O10141.1 (3)N6—C17—C16122.1 (9)
O9—Pb2—O11141.2 (3)N6—C17—C18115.9 (7)
O9—Pb2—N670.3 (2)C16—C17—C18122.0 (9)
O9—Pb2—N775.0 (2)N7—C18—C17118.5 (8)
O9—Pb2—O12i117.1 (2)N7—C18—C19119.6 (9)
O10—Pb2—O1146.0 (3)C17—C18—C19121.9 (9)
O10—Pb2—N675.8 (3)C18—C19—C20118.3 (11)
O10—Pb2—N7109.1 (3)C19—C20—C21121.0 (11)
O10—Pb2—O12i101.8 (3)C20—C21—C22118.3 (12)
O11—Pb2—N681.6 (2)N7—C22—C21122.0 (11)
O11—Pb2—N769.7 (3)C2—C1—H1A110.00
O11—Pb2—O12i74.6 (3)C2—C1—H1B110.00
N6—Pb2—N767.5 (3)C2—C1—H1C110.00
O12i—Pb2—N6147.3 (3)H1A—C1—H1B109.00
O12i—Pb2—N783.3 (3)H1A—C1—H1C109.00
Pb1—O1—N396.4 (6)H1B—C1—H1C109.00
Pb1—O2—N394.6 (6)C2—C3—H3120.00
Pb1—O4—N494.8 (6)C4—C3—H3120.00
Pb1—O4—Pb1ii110.9 (3)C3—C4—H4120.00
Pb1ii—O4—N4153.4 (7)C5—C4—H4120.00
Pb1—O5—N4102.2 (6)C4—C5—H5121.00
Pb1—O8—N5120.0 (6)C6—C5—H5121.00
Pb2—O9—N5110.7 (5)C7—C8—H8121.00
Pb2—O10—N894.1 (7)C9—C8—H8121.00
Pb2—O11—N8100.3 (6)C8—C9—H9120.00
Pb2i—O12—N8106.0 (7)C10—C9—H9120.00
Pb1—N1—C2119.9 (6)C9—C10—H10121.00
Pb1—N1—C6116.9 (6)C11—C10—H10121.00
C2—N1—C6119.9 (8)N2—C11—H11119.00
Pb1—N2—C7120.8 (6)C10—C11—H11119.00
Pb1—N2—C11119.8 (7)C13—C12—H12A109.00
C7—N2—C11119.2 (9)C13—C12—H12B109.00
O1—N3—O2118.2 (8)C13—C12—H12C110.00
O1—N3—O3121.0 (10)H12A—C12—H12B109.00
O2—N3—O3120.7 (10)H12A—C12—H12C109.00
O4—N4—O5115.7 (9)H12B—C12—H12C109.00
O4—N4—O6123.4 (10)C13—C14—H14120.00
O5—N4—O6120.9 (10)C15—C14—H14120.00
O7—N5—O8122.7 (9)C14—C15—H15120.00
O7—N5—O9119.5 (8)C16—C15—H15120.00
O8—N5—O9117.8 (8)C15—C16—H16121.00
Pb2—N6—C13122.8 (6)C17—C16—H16121.00
Pb2—N6—C17118.7 (5)C18—C19—H19121.00
C13—N6—C17118.4 (8)C20—C19—H19121.00
Pb2—N7—C18118.9 (6)C19—C20—H20119.00
Pb2—N7—C22119.8 (7)C21—C20—H20119.00
C18—N7—C22120.7 (9)C20—C21—H21121.00
O10—N8—O11117.3 (9)C22—C21—H21121.00
O10—N8—O12121.4 (10)N7—C22—H22119.00
O11—N8—O12121.3 (9)C21—C22—H22119.00
N1—C2—C1117.2 (9)
O2—Pb1—O1—N3−6.2 (6)O11—Pb2—N7—C2287.4 (8)
O4—Pb1—O1—N3127.9 (6)N6—Pb2—N7—C22176.5 (8)
O5—Pb1—O1—N3168.9 (7)O12i—Pb2—N7—C2211.4 (8)
N1—Pb1—O1—N3−66.3 (7)O12i—Pb2—N6—C13−155.8 (6)
N2—Pb1—O1—N3−118.2 (7)O9—Pb2—N6—C17−83.2 (6)
O4ii—Pb1—O1—N354.0 (7)O10—Pb2—N6—C17116.3 (6)
O1—Pb1—O2—N36.2 (6)O11—Pb2—N6—C1769.7 (6)
O4—Pb1—O2—N3−65.2 (7)N7—Pb2—N6—C17−1.8 (6)
O5—Pb1—O2—N3−0.8 (8)O12i—Pb2—N6—C1726.5 (8)
O8—Pb1—O2—N3176.8 (5)O9—Pb2—N7—C1880.0 (6)
N1—Pb1—O2—N3132.1 (6)O10—Pb2—N7—C18−59.4 (7)
N2—Pb1—O2—N369.1 (6)O11—Pb2—N7—C18−83.6 (6)
O4ii—Pb1—O2—N3−122.8 (6)N6—Pb2—N7—C185.5 (6)
O1—Pb1—O4—N473.9 (7)O12i—Pb2—N7—C18−159.6 (6)
O2—Pb1—O4—N4122.3 (6)O9—Pb2—N6—C1394.5 (7)
O5—Pb1—O4—N47.7 (6)O10—Pb2—N6—C13−66.0 (7)
O8—Pb1—O4—N4−92.9 (7)O11—Pb2—N6—C13−112.6 (7)
N1—Pb1—O4—N4−85.2 (8)N7—Pb2—N6—C13175.9 (7)
N2—Pb1—O4—N4−4.7 (8)O9—Pb2—N7—C22−109.0 (8)
O4ii—Pb1—O4—N4−173.2 (7)O10—Pb2—N7—C22111.6 (8)
O1—Pb1—O4—Pb1ii−113.0 (3)Pb1—O1—N3—O3−168.1 (10)
O2—Pb1—O4—Pb1ii−64.5 (5)Pb1—O1—N3—O211.1 (10)
O5—Pb1—O4—Pb1ii−179.1 (6)Pb1—O2—N3—O1−10.8 (10)
O8—Pb1—O4—Pb1ii80.3 (3)Pb1—O2—N3—O3168.4 (10)
N1—Pb1—O4—Pb1ii88.0 (5)Pb1ii—O4—N4—O5−178.4 (13)
N2—Pb1—O4—Pb1ii168.5 (3)Pb1—O4—N4—O6167.5 (11)
O4ii—Pb1—O4—Pb1ii0.0 (3)Pb1—O4—N4—O5−12.8 (10)
O1ii—Pb1ii—O4—Pb1−97.2 (4)Pb1ii—O4—N4—O62(2)
O2ii—Pb1ii—O4—Pb1−138.7 (4)Pb1—O5—N4—O413.9 (11)
O4ii—Pb1ii—O4—Pb10.0 (3)Pb1—O5—N4—O6−166.4 (10)
O5ii—Pb1ii—O4—Pb1−0.7 (5)Pb1—O8—N5—O981.2 (9)
O8ii—Pb1ii—O4—Pb175.2 (3)Pb1—O8—N5—O7−99.6 (10)
N1ii—Pb1ii—O4—Pb1138.6 (3)Pb2—O9—N5—O8177.8 (6)
O1ii—Pb1ii—O4—N467.4 (18)Pb2—O9—N5—O7−1.4 (11)
O2ii—Pb1ii—O4—N426.0 (17)Pb2—O10—N8—O1114.9 (10)
O4ii—Pb1ii—O4—N4164.7 (18)Pb2—O10—N8—O12−166.7 (9)
O5ii—Pb1ii—O4—N4164.0 (17)Pb2—O11—N8—O10−15.9 (10)
O8ii—Pb1ii—O4—N4−120.2 (17)Pb2—O11—N8—O12165.7 (8)
N1ii—Pb1ii—O4—N4−56.7 (18)Pb2i—O12—N8—O10129.4 (9)
O1—Pb1—O5—N4−125.3 (7)Pb2i—O12—N8—O11−52.2 (11)
O2—Pb1—O5—N4−120.0 (7)Pb1—N1—C2—C1−20.6 (11)
O4—Pb1—O5—N4−7.6 (6)C6—N1—C2—C1−179.4 (8)
O8—Pb1—O5—N461.6 (7)Pb1—N1—C2—C3158.7 (7)
N1—Pb1—O5—N4121.8 (6)C6—N1—C2—C3−0.1 (13)
N2—Pb1—O5—N4160.8 (8)C2—N1—C6—C51.3 (13)
O4ii—Pb1—O5—N4−8.5 (8)Pb1—N1—C6—C722.2 (10)
O2—Pb1—O8—N5141.4 (7)C2—N1—C6—C7−178.4 (8)
O4—Pb1—O8—N54.4 (7)Pb1—N1—C6—C5−158.2 (7)
O5—Pb1—O8—N5−40.4 (7)C11—N2—C7—C6−178.7 (9)
N1—Pb1—O8—N5−170.4 (8)Pb1—N2—C7—C8179.4 (7)
N2—Pb1—O8—N5−111.6 (7)C7—N2—C11—C10−5.9 (16)
O4ii—Pb1—O8—N577.1 (7)Pb1—N2—C11—C10178.3 (8)
O8—Pb1—N1—C692.2 (6)Pb1—N2—C7—C6−3.1 (11)
N2—Pb1—N1—C6−16.8 (6)C11—N2—C7—C83.7 (14)
O4ii—Pb1—N1—C6159.2 (6)Pb2—N6—C17—C16178.1 (7)
O1—Pb1—N2—C7135.5 (7)C13—N6—C17—C160.3 (13)
O2—Pb1—N2—C790.4 (7)Pb2—N6—C13—C14−178.6 (8)
O4—Pb1—N2—C7−125.4 (7)Pb2—N6—C13—C120.1 (12)
O5—Pb1—N2—C7−134.7 (7)C17—N6—C13—C12177.7 (8)
O8—Pb1—N2—C7−53.3 (7)Pb2—N6—C17—C18−1.6 (9)
N1—Pb1—N2—C79.9 (6)C17—N6—C13—C14−0.9 (14)
O1—Pb1—N2—C11−48.8 (8)C13—N6—C17—C18−179.4 (8)
O2—Pb1—N2—C11−93.9 (8)Pb2—N7—C22—C21−172.4 (9)
O4—Pb1—N2—C1150.2 (8)Pb2—N7—C18—C19172.8 (7)
O5—Pb1—N2—C1140.9 (8)Pb2—N7—C18—C17−8.6 (10)
O8—Pb1—N2—C11122.4 (8)C18—N7—C22—C21−1.5 (16)
N1—Pb1—N2—C11−174.4 (8)C22—N7—C18—C17−179.5 (9)
O5—Pb1—N1—C625.0 (7)C22—N7—C18—C191.9 (13)
O5—Pb1—N1—C2−134.5 (7)C1—C2—C3—C4177.5 (11)
O8—Pb1—N1—C2−67.3 (7)N1—C2—C3—C4−1.7 (16)
N2—Pb1—N1—C2−176.2 (8)C2—C3—C4—C52.3 (18)
O4ii—Pb1—N1—C2−0.2 (7)C3—C4—C5—C6−1.1 (17)
O1—Pb1—N1—C2126.8 (7)C4—C5—C6—N1−0.7 (14)
O2—Pb1—N1—C285.1 (7)C4—C5—C6—C7179.0 (9)
O4—Pb1—N1—C2−75.0 (8)N1—C6—C7—C8164.3 (9)
O4—Pb1—N1—C684.5 (7)N1—C6—C7—N2−13.3 (12)
O1—Pb1—N1—C6−73.7 (7)C5—C6—C7—C8−15.4 (14)
O2—Pb1—N1—C6−115.4 (6)C5—C6—C7—N2167.0 (9)
O10i—Pb2i—O12—N811.7 (7)C6—C7—C8—C9−178.9 (10)
O11i—Pb2i—O12—N8−25.8 (7)N2—C7—C8—C9−1.3 (15)
N6i—Pb2i—O12—N8−70.4 (8)C7—C8—C9—C101.2 (17)
N7i—Pb2i—O12—N8−96.6 (7)C8—C9—C10—C11−3.2 (18)
O9i—Pb2i—O12—N8−165.9 (6)C9—C10—C11—N25.8 (18)
O10—Pb2—O9—N5−74.9 (7)C12—C13—C14—C15−178.1 (11)
O11—Pb2—O9—N5−151.9 (6)N6—C13—C14—C150.5 (16)
N6—Pb2—O9—N5−105.8 (6)C13—C14—C15—C160.6 (18)
N7—Pb2—O9—N5−176.8 (7)C14—C15—C16—C17−1.2 (17)
O12i—Pb2—O9—N5109.0 (6)C15—C16—C17—N60.8 (15)
O9—Pb2—O10—N8−130.6 (6)C15—C16—C17—C18−179.6 (9)
O11—Pb2—O10—N8−8.6 (6)C16—C17—C18—C195.6 (14)
N6—Pb2—O10—N8−100.6 (7)N6—C17—C18—C19−174.7 (8)
N7—Pb2—O10—N8−41.0 (7)C16—C17—C18—N7−173.0 (8)
O12i—Pb2—O10—N845.9 (7)N6—C17—C18—N76.7 (11)
O9—Pb2—O11—N8130.3 (6)C17—C18—C19—C20179.8 (10)
O10—Pb2—O11—N88.6 (6)N7—C18—C19—C20−1.7 (15)
N6—Pb2—O11—N887.0 (6)C18—C19—C20—C211.1 (18)
N7—Pb2—O11—N8156.0 (7)C19—C20—C21—C22−0.7 (19)
O12i—Pb2—O11—N8−115.5 (6)C20—C21—C22—N70.9 (19)
D—H···AD—HH···AD···AD—H···A
C1—H1A···O4ii0.962.553.378 (14)144
C3—H3···O10iii0.932.503.368 (17)155
C10—H10···O6iv0.932.473.349 (17)157
C12—H12A···O100.962.483.299 (15)143
C12—H12B···O70.962.493.412 (17)160
C12—H12C···O8iii0.962.593.516 (14)162
C19—H19···O9v0.932.453.253 (13)145
C21—H21···O1iv0.932.423.212 (15)143
C22—H22···O12i0.932.533.268 (15)137
Table 1

Selected bond lengths (Å)

Pb1—O12.566 (8)
Pb1—O22.609 (8)
Pb1—O42.851 (8)
Pb1—O52.675 (9)
Pb1—O82.693 (8)
Pb1—N12.618 (8)
Pb1—N22.528 (8)
Pb2—O92.624 (7)
Pb2—O102.763 (11)
Pb2—O112.629 (8)
Pb2—N62.470 (7)
Pb2—N72.422 (8)
Pb2—O12i2.910 (9)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯AD—HH⋯AD⋯AD—H⋯A
C1—H1A⋯O4ii0.962.553.378 (14)144
C3—H3⋯O10iii0.932.503.368 (17)155
C10—H10⋯O6iv0.932.473.349 (17)157
C12—H12A⋯O100.962.483.299 (15)143
C12—H12B⋯O70.962.493.412 (17)160
C12—H12C⋯O8iii0.962.593.516 (14)162
C19—H19⋯O9v0.932.453.253 (13)145
C21—H21⋯O1iv0.932.423.212 (15)143
C22—H22⋯O12i0.932.533.268 (15)137

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .

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1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  Dichlorido(6-methyl-2,2'-bipyridine-κN,N')mercury(II).

Authors:  Roya Ahmadi; Amin Ebadi; Khadijeh Kalateh; Ali Norouzi; Vahid Amani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-10-15

3.  Dichlorido(6-methyl-2,2'-bipyridine-κN,N')zinc(II).

Authors:  Roya Ahmadi; Khadijeh Kalateh; Amin Ebadi; Vahid Amani; Hamid Reza Khavasi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-13
  3 in total
  6 in total

1.  Dibromido(6-methyl-2,2'-bipyridine-κN,N')zinc(II).

Authors:  Khadijeh Kalateh; Roya Ahmadi; Vahid Amani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-09-11

2.  Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Authors:  Robabeh Alizadeh; Khadijeh Kalateh; Amin Ebadi; Roya Ahmadi; Vahid Amani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-09-26

3.  Dibromido(dimethyl sulfoxide-κO)(6-methyl-2,2'-bipyridine-κ(2)N,N')cadmium.

Authors:  Sadif A Shirvan; Sara Haydari Dezfuli
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-07-28

4.  Dichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')cobalt(II).

Authors:  Niloufar Akbarzadeh Torbati; Ali Reza Rezvani; Hamideh Saravani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-10-06

5.  Dibromido(6-methyl-2,2'-bipyridine-κ(2) N,N')cobalt(II).

Authors:  Sadif A Shirvan; Sara Haydari Dezfuli; Fereydoon Khazali; Ali Borsalani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-07

6.  Trichlorido(6-methyl-2,2'-bipyridine-κ(2)N,N')(dimethyl-sulfoxide-κO)indium(III).

Authors:  Sadif A Shirvan; Sara Haydari Dezfuli; Elyas Golabi; Mohammad Amin Gholamzadeh
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-10-06
  6 in total

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