catena-Poly[[[diaqua-(nitrato-κO,O')(2,2':6',2''-terpyridine-κN,N',N'')neodymium(III)]-μ-cyanido-κN:C-[dicyanidoplatinum(II)]-μ-cyanido-κC:N] acetonitrile solvate 2,2':6',2''-terpyridine hemisolvate].

The title compound, {[NdPt(CN)(4)(NO(3))(C(15)H(11)N(3))(H(2)O)(2)]·CH(3)CN·0.5C(15)H(11)N(3)}(n), was isolated from solution as a one-dimensional coordination polymer. The Nd(3+) site in the structure has a ninefold coordination with a distorted tricapped trigonal-prismatic geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. Cis-bridging by the tetracyanidoplatinate anions links the Nd(3+) cations, forming the one-dimensional chains. Additionally, each Nd(3+) contains coordin-ation by two water mol-ecules, one tridentate 2,2':6',2''-terpyridine mol-ecule, and one bidentate nitrate anion. 2,2':6',2''-Terpyridine and acetonitrile solvent mol-ecules are incorporated between the chains, the former form π-stacking inter-actions (average inter-planar distance 3.33 Å) with terpyridine mol-ecules located in the chains. Relatively long Pt⋯Pt inter-actions [3.847 (1) Å] are observed in the structure. O-H⋯N and O-H⋯O hydrogen bonding interactions between the consituents consolidates the crystal packing.

Related literature

For related lanthanide tetracyanidoplatinate structures containing 2,2′:6′,2′′-terpyridine, see: Maynard et al. (2008 ▶); Maynard, Smith, Ladner et al. (2009 ▶); Maynard, Smith, Jaleel et al. (2009 ▶). For structural and spectroscopic information on simpler lanthanide tetracyanidoplatinates, see: Gliemann & Yersin (1985 ▶); Holzapfel et al. (1981 ▶). For luminescence data on lanthanide terpyridine systems, see: Mukkala et al. (1995 ▶).

Experimental

Crystal data

[NdPt(CN)4(NO3)(C15H11N3)(H2O)2]·C2H3N·0.5C15H11N3

M = 932.4

Monoclinic,

a = 33.231 (6) Å

b = 14.3642 (17) Å

c = 13.823 (3) Å

β = 108.931 (16)°

V = 6241.5 (19) Å3

Z = 8

Mo Kα radiation

μ = 6.18 mm−1

T = 290 K

0.45 × 0.17 × 0.08 mm

Data collection

Enraf–Nonius CAD-4 diffractometer

Absorption correction: analytical (XPREP; Bruker, 1998 ▶) T min = 0.308, T max = 0.632

5824 measured reflections

5722 independent reflections

4089 reflections with I > 2σ(I)

R int = 0.031

3 standard reflections frequency: 120 min intensity decay: none

Refinement

R[F 2 > 2σ(F 2)] = 0.036

wR(F 2) = 0.087

S = 1.00

5722 reflections

420 parameters

H-atom parameters constrained

Δρmax = 0.86 e Å−3

Δρmin = −0.84 e Å−3

Data collection: CAD-4-PC Software (Enraf–Nonius, 1993 ▶); cell refinement: CAD-4-PC Software; data reduction: XCAD4 (Harms & Wocadlo, 1996 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: publCIF (Westrip, 2009 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S160053680903325X/nc2153sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053680903325X/nc2153Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[NdPt(CN)4(NO3)(C15H11N3)(H2O)2]·C2H3N·0.5C15H11N3	F(000) = 3568
Mr = 932.4	Dx = 1.985 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 25 reflections
a = 33.231 (6) Å	θ = 8.5–15.4°
b = 14.3642 (17) Å	µ = 6.18 mm−1
c = 13.823 (3) Å	T = 290 K
β = 108.931 (16)°	Plate, purple
V = 6241.5 (19) Å3	0.45 × 0.17 × 0.08 mm
Z = 8

Enraf–Nonius CAD-4 diffractometer	4089 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.031
graphite	θmax = 25.4°, θmin = 2.1°
θ/2θ scans	h = 0→40
Absorption correction: analytical (SADABS; Bruker, 1998)	k = 0→17
Tmin = 0.308, Tmax = 0.632	l = −16→15
5824 measured reflections	3 standard reflections every 120 min
5722 independent reflections	intensity decay: none

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.036	Hydrogen site location: mixed
wR(F2) = 0.087	H-atom parameters constrained
S = 1.00	w = 1/[σ2(Fo2) + (0.0283P)2] where P = (Fo2 + 2Fc2)/3
5722 reflections	(Δ/σ)max = 0.001
420 parameters	Δρmax = 0.86 e Å−3
0 restraints	Δρmin = −0.84 e Å−3
44 constraints

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Nd1	0.349783 (14)	0.43585 (3)	−0.06095 (3)	0.02261 (11)
Pt1	0.308541 (10)	0.775186 (19)	0.07657 (2)	0.02355 (9)
C1	0.3149 (3)	0.6590 (6)	0.0072 (6)	0.0287 (18)
C2	0.3302 (3)	0.7125 (5)	0.2122 (6)	0.0277 (17)
C3	0.3023 (3)	0.8936 (6)	0.1443 (6)	0.0330 (19)
C4	0.2851 (3)	0.8356 (5)	−0.0596 (6)	0.0302 (18)
C5	0.2743 (3)	0.4274 (6)	0.0670 (7)	0.039 (2)
H5A	0.2704	0.4877	0.0410	0.046*
C6	0.2505 (3)	0.3991 (6)	0.1269 (7)	0.044 (2)
H6A	0.2307	0.4391	0.1391	0.053*
C7	0.2562 (3)	0.3117 (7)	0.1679 (7)	0.052 (3)
H7A	0.2411	0.2918	0.2102	0.062*
C8	0.2849 (3)	0.2537 (7)	0.1451 (7)	0.042 (2)
H8A	0.2891	0.1934	0.1709	0.051*
C9	0.3075 (3)	0.2860 (5)	0.0832 (6)	0.0329 (19)
C10	0.3394 (3)	0.2280 (6)	0.0592 (6)	0.035 (2)
C11	0.3405 (3)	0.1306 (7)	0.0718 (7)	0.050 (3)
H11A	0.3202	0.1003	0.0936	0.060*
C12	0.3719 (4)	0.0820 (7)	0.0512 (9)	0.068 (3)
H12A	0.3729	0.0176	0.0582	0.082*
C13	0.4015 (4)	0.1255 (7)	0.0211 (8)	0.057 (3)
H13A	0.4231	0.0914	0.0087	0.069*
C14	0.4000 (3)	0.2214 (6)	0.0084 (7)	0.039 (2)
C15	0.4318 (3)	0.2724 (6)	−0.0214 (6)	0.035 (2)
C16	0.4697 (3)	0.2336 (8)	−0.0204 (8)	0.056 (3)
H16A	0.4750	0.1711	−0.0036	0.067*
C17	0.4999 (3)	0.2866 (10)	−0.0443 (9)	0.069 (4)
H17A	0.5255	0.2604	−0.0442	0.083*
C18	0.4915 (3)	0.3766 (9)	−0.0677 (7)	0.058 (3)
H18A	0.5112	0.4140	−0.0841	0.069*
C19	0.4530 (3)	0.4133 (7)	−0.0669 (7)	0.045 (2)
H19A	0.4472	0.4757	−0.0837	0.054*
C20	0.5895 (4)	0.0801 (8)	0.1679 (10)	0.073 (4)
H20A	0.5883	0.0154	0.1653	0.088*
C21	0.6217 (3)	0.1261 (8)	0.1448 (8)	0.060 (3)
H21A	0.6423	0.0937	0.1265	0.072*
C22	0.6220 (3)	0.2221 (8)	0.1500 (8)	0.055 (3)
H22A	0.6435	0.2536	0.1340	0.066*
C23	0.5593 (3)	0.1288 (7)	0.1946 (8)	0.056 (3)
H23A	0.5373	0.0984	0.2094	0.068*
C24	0.5627 (3)	0.2254 (6)	0.1988 (6)	0.039 (2)
C25	0.5303 (3)	0.2810 (6)	0.2270 (6)	0.038 (2)
C26	0.5314 (3)	0.3784 (7)	0.2262 (7)	0.048 (2)
H26A	0.5527	0.4102	0.2100	0.058*
C27	0.5000	0.4252 (10)	0.2500	0.053 (4)
H27A	0.5000	0.4899	0.2500	0.063*
C28	0.4505 (6)	0.8941 (11)	0.1457 (17)	0.109 (7)
C29	0.4263 (8)	0.8338 (13)	0.1910 (18)	0.134 (7)
H29A	0.3967	0.8499	0.1644	0.4 (2)*
H29B	0.4362	0.8416	0.2639	0.12 (7)*
H29C	0.4300	0.7701	0.1745	0.09 (4)*
N1	0.3189 (2)	0.5906 (5)	−0.0313 (5)	0.0376 (17)
N2	0.3413 (2)	0.6737 (5)	0.2886 (5)	0.0378 (18)
N3	0.2968 (3)	0.9628 (5)	0.1791 (7)	0.055 (2)
N4	0.2716 (3)	0.8690 (5)	−0.1384 (6)	0.046 (2)
N5	0.4061 (2)	0.5440 (5)	0.1161 (5)	0.0326 (16)
N6	0.3027 (2)	0.3734 (5)	0.0445 (5)	0.0327 (16)
N7	0.3677 (2)	0.2706 (4)	0.0232 (5)	0.0304 (15)
N8	0.4242 (2)	0.3633 (5)	−0.0434 (5)	0.0358 (17)
N9	0.5936 (2)	0.2724 (5)	0.1765 (6)	0.0447 (19)
N10	0.5000	0.2344 (7)	0.2500	0.039 (2)
N11	0.4708 (5)	0.9406 (10)	0.1179 (14)	0.130 (6)
O1	0.38212 (18)	0.4789 (4)	0.1277 (4)	0.0366 (14)
O2	0.40884 (19)	0.5548 (4)	0.0286 (4)	0.0418 (15)
O3	0.4259 (2)	0.5928 (5)	0.1889 (5)	0.058 (2)
O4	0.27728 (18)	0.4401 (4)	−0.1750 (4)	0.0374 (14)
H4A	0.2716	0.4145	−0.2333	0.045*
H4B	0.2556	0.4753	−0.1890	0.045*
O5	0.3686 (2)	0.5374 (4)	−0.1855 (4)	0.0402 (15)
H5B	0.3769	0.5937	−0.1773	0.048*
H5C	0.3765	0.5152	−0.2334	0.048*

	U11	U22	U33	U12	U13	U23
Nd1	0.0283 (2)	0.0236 (2)	0.0168 (2)	−0.00194 (17)	0.00833 (17)	−0.00252 (16)
Pt1	0.03025 (17)	0.02168 (15)	0.02051 (15)	0.00316 (14)	0.01069 (12)	0.00322 (12)
C1	0.032 (5)	0.031 (4)	0.027 (4)	0.000 (4)	0.015 (4)	0.007 (4)
C2	0.037 (5)	0.024 (4)	0.025 (4)	0.001 (4)	0.015 (4)	−0.001 (3)
C3	0.048 (5)	0.027 (4)	0.027 (4)	0.005 (4)	0.017 (4)	0.005 (4)
C4	0.036 (5)	0.030 (4)	0.027 (4)	0.005 (4)	0.013 (4)	0.004 (4)
C5	0.037 (5)	0.033 (5)	0.047 (5)	−0.003 (4)	0.016 (4)	−0.001 (4)
C6	0.045 (6)	0.048 (5)	0.047 (5)	−0.017 (5)	0.026 (5)	−0.010 (5)
C7	0.055 (7)	0.071 (7)	0.035 (5)	−0.016 (6)	0.021 (5)	0.010 (5)
C8	0.036 (5)	0.051 (5)	0.050 (6)	−0.006 (4)	0.027 (5)	0.020 (5)
C9	0.039 (5)	0.034 (4)	0.025 (4)	−0.006 (4)	0.009 (4)	−0.005 (4)
C10	0.043 (5)	0.038 (5)	0.019 (4)	−0.005 (4)	0.004 (4)	0.010 (4)
C11	0.058 (7)	0.043 (6)	0.052 (6)	−0.001 (5)	0.021 (5)	0.013 (5)
C12	0.081 (9)	0.029 (5)	0.090 (9)	0.016 (6)	0.021 (7)	0.015 (5)
C13	0.063 (7)	0.045 (6)	0.067 (7)	0.019 (5)	0.025 (6)	0.009 (5)
C14	0.039 (5)	0.041 (5)	0.037 (5)	0.013 (4)	0.012 (4)	0.003 (4)
C15	0.036 (5)	0.048 (5)	0.020 (4)	0.007 (4)	0.007 (4)	−0.004 (4)
C16	0.050 (6)	0.065 (7)	0.053 (6)	0.024 (6)	0.019 (5)	0.010 (5)
C17	0.032 (6)	0.116 (11)	0.062 (7)	0.017 (7)	0.018 (5)	−0.004 (8)
C18	0.044 (6)	0.095 (9)	0.032 (5)	−0.015 (6)	0.012 (5)	0.008 (6)
C19	0.034 (5)	0.064 (6)	0.038 (5)	−0.001 (5)	0.015 (4)	0.002 (5)
C20	0.076 (9)	0.050 (6)	0.105 (10)	0.005 (6)	0.047 (8)	−0.004 (7)
C21	0.060 (7)	0.068 (7)	0.069 (7)	0.007 (6)	0.045 (6)	−0.008 (6)
C22	0.055 (7)	0.071 (7)	0.047 (6)	0.004 (6)	0.026 (5)	−0.004 (6)
C23	0.067 (7)	0.041 (5)	0.077 (8)	0.007 (5)	0.046 (6)	0.004 (5)
C24	0.038 (5)	0.050 (5)	0.031 (5)	0.005 (5)	0.014 (4)	−0.001 (4)
C25	0.036 (5)	0.057 (6)	0.024 (4)	0.002 (5)	0.014 (4)	0.000 (4)
C26	0.046 (6)	0.050 (6)	0.050 (6)	−0.016 (5)	0.018 (5)	0.000 (5)
C27	0.039 (8)	0.042 (8)	0.074 (11)	0.000	0.016 (8)	0.000
C28	0.080 (12)	0.061 (10)	0.17 (2)	−0.003 (8)	0.019 (12)	−0.024 (11)
C29	0.14 (2)	0.103 (15)	0.16 (2)	−0.002 (13)	0.052 (16)	−0.022 (13)
N1	0.048 (5)	0.030 (4)	0.038 (4)	−0.002 (3)	0.018 (4)	−0.003 (3)
N2	0.040 (5)	0.040 (4)	0.031 (4)	0.003 (3)	0.009 (3)	0.008 (3)
N3	0.070 (6)	0.036 (4)	0.070 (6)	0.008 (4)	0.039 (5)	−0.004 (4)
N4	0.052 (5)	0.048 (5)	0.036 (4)	0.008 (4)	0.011 (4)	0.007 (4)
N5	0.031 (4)	0.038 (4)	0.028 (4)	−0.002 (3)	0.009 (3)	−0.004 (3)
N6	0.036 (4)	0.032 (4)	0.029 (4)	−0.005 (3)	0.008 (3)	−0.001 (3)
N7	0.039 (4)	0.028 (3)	0.022 (3)	0.001 (3)	0.008 (3)	0.008 (3)
N8	0.036 (4)	0.049 (4)	0.024 (4)	0.001 (4)	0.012 (3)	0.001 (3)
N9	0.041 (5)	0.056 (5)	0.043 (4)	−0.008 (4)	0.020 (4)	−0.008 (4)
N10	0.040 (6)	0.047 (6)	0.031 (5)	0.000	0.012 (5)	0.000
N11	0.122 (14)	0.102 (12)	0.173 (16)	0.015 (10)	0.060 (12)	−0.002 (11)
O1	0.043 (4)	0.041 (3)	0.024 (3)	−0.005 (3)	0.010 (3)	−0.002 (3)
O2	0.046 (4)	0.051 (4)	0.033 (3)	−0.018 (3)	0.020 (3)	−0.007 (3)
O3	0.055 (5)	0.070 (5)	0.040 (4)	−0.015 (4)	0.001 (3)	−0.026 (4)
O4	0.032 (3)	0.048 (3)	0.027 (3)	0.007 (3)	0.002 (3)	−0.012 (3)
O5	0.063 (4)	0.033 (3)	0.032 (3)	−0.006 (3)	0.026 (3)	−0.002 (3)

Nd1—O4	2.414 (5)	C15—C16	1.374 (12)
Nd1—O5	2.486 (5)	C16—C17	1.383 (15)
Nd1—N1	2.536 (7)	C16—H16A	0.9300
Nd1—N2i	2.550 (7)	C17—C18	1.339 (16)
Nd1—O1	2.554 (5)	C17—H17A	0.9300
Nd1—O2	2.594 (6)	C18—C19	1.389 (14)
Nd1—N6	2.619 (7)	C18—H18A	0.9300
Nd1—N8	2.623 (7)	C19—N8	1.317 (11)
Nd1—N7	2.625 (6)	C19—H19A	0.9300
Nd1—N5	2.989 (7)	C20—C23	1.367 (14)
Pt1—C1	1.970 (8)	C20—C21	1.380 (14)
Pt1—C3	1.985 (8)	C20—H20A	0.9300
Pt1—C4	1.988 (8)	C21—C22	1.380 (14)
Pt1—C2	1.992 (8)	C21—H21A	0.9300
C1—N1	1.146 (10)	C22—N9	1.331 (12)
C2—N2	1.144 (9)	C22—H22A	0.9300
C3—N3	1.144 (10)	C23—C24	1.392 (12)
C4—N4	1.140 (10)	C23—H23A	0.9300
C5—N6	1.334 (11)	C24—N9	1.347 (11)
C5—C6	1.379 (12)	C24—C25	1.491 (12)
C5—H5A	0.9300	C25—N10	1.329 (10)
C6—C7	1.365 (13)	C25—C26	1.400 (12)
C6—H6A	0.9300	C26—C27	1.367 (11)
C7—C8	1.378 (14)	C26—H26A	0.9300
C7—H7A	0.9300	C27—C26ii	1.367 (11)
C8—C9	1.388 (11)	C27—H27A	0.9300
C8—H8A	0.9300	C28—N11	1.10 (2)
C9—N6	1.355 (10)	C28—C29	1.46 (2)
C9—C10	1.469 (12)	C29—H29A	0.9600
C10—N7	1.344 (10)	C29—H29B	0.9600
C10—C11	1.410 (12)	C29—H29C	0.9600
C11—C12	1.360 (14)	N2—Nd1iii	2.550 (7)
C11—H11A	0.9300	N5—O3	1.227 (8)
C12—C13	1.340 (15)	N5—O2	1.252 (8)
C12—H12A	0.9300	N5—O1	1.273 (8)
C13—C14	1.387 (13)	N10—C25ii	1.329 (10)
C13—H13A	0.9300	O4—H4A	0.8500
C14—N7	1.356 (10)	O4—H4B	0.8499
C14—C15	1.449 (12)	O5—H5B	0.8500
C15—N8	1.344 (11)	O5—H5C	0.8499
O4—Nd1—O5	87.4 (2)	C12—C13—C14	120.2 (10)
O4—Nd1—N1	73.3 (2)	C12—C13—H13A	119.9
O5—Nd1—N1	78.7 (2)	C14—C13—H13A	119.9
O4—Nd1—N2i	70.1 (2)	N7—C14—C13	119.7 (9)
O5—Nd1—N2i	77.5 (2)	N7—C14—C15	117.7 (7)
N1—Nd1—N2i	136.8 (2)	C13—C14—C15	122.6 (9)
O4—Nd1—O1	131.37 (19)	N8—C15—C16	119.9 (9)
O5—Nd1—O1	116.64 (18)	N8—C15—C14	117.1 (8)
N1—Nd1—O1	71.4 (2)	C16—C15—C14	122.8 (9)
N2i—Nd1—O1	151.8 (2)	C15—C16—C17	120.6 (10)
O4—Nd1—O2	137.3 (2)	C15—C16—H16A	119.7
O5—Nd1—O2	67.83 (18)	C17—C16—H16A	119.7
N1—Nd1—O2	68.2 (2)	C18—C17—C16	118.6 (10)
N2i—Nd1—O2	131.5 (2)	C18—C17—H17A	120.7
O1—Nd1—O2	49.51 (17)	C16—C17—H17A	120.7
O4—Nd1—N6	73.9 (2)	C17—C18—C19	119.0 (10)
O5—Nd1—N6	156.4 (2)	C17—C18—H18A	120.5
N1—Nd1—N6	82.2 (2)	C19—C18—H18A	120.5
N2i—Nd1—N6	108.3 (2)	N8—C19—C18	122.6 (10)
O1—Nd1—N6	69.15 (19)	N8—C19—H19A	118.7
O2—Nd1—N6	117.16 (19)	C18—C19—H19A	118.7
O4—Nd1—N8	141.46 (19)	C23—C20—C21	120.5 (10)
O5—Nd1—N8	81.7 (2)	C23—C20—H20A	119.7
N1—Nd1—N8	138.8 (2)	C21—C20—H20A	119.7
N2i—Nd1—N8	71.4 (2)	C20—C21—C22	117.4 (10)
O1—Nd1—N8	85.98 (19)	C20—C21—H21A	121.3
O2—Nd1—N8	70.9 (2)	C22—C21—H21A	121.3
N6—Nd1—N8	121.9 (2)	N9—C22—C21	124.2 (10)
O4—Nd1—N7	110.3 (2)	N9—C22—H22A	117.9
O5—Nd1—N7	140.0 (2)	C21—C22—H22A	117.9
N1—Nd1—N7	140.0 (2)	C20—C23—C24	117.8 (10)
N2i—Nd1—N7	75.7 (2)	C20—C23—H23A	121.1
O1—Nd1—N7	78.85 (18)	C24—C23—H23A	121.1
O2—Nd1—N7	110.9 (2)	N9—C24—C23	123.1 (9)
N6—Nd1—N7	62.3 (2)	N9—C24—C25	117.5 (8)
N8—Nd1—N7	61.8 (2)	C23—C24—C25	119.4 (9)
O4—Nd1—N5	138.48 (18)	N10—C25—C26	121.9 (9)
O5—Nd1—N5	91.78 (19)	N10—C25—C24	117.4 (8)
N1—Nd1—N5	65.9 (2)	C26—C25—C24	120.7 (8)
N2i—Nd1—N5	149.6 (2)	C27—C26—C25	117.7 (10)
O1—Nd1—N5	24.99 (17)	C27—C26—H26A	121.2
O2—Nd1—N5	24.64 (17)	C25—C26—H26A	121.2
N6—Nd1—N5	92.92 (19)	C26—C27—C26ii	121.2 (13)
N8—Nd1—N5	79.0 (2)	C26—C27—H27A	119.4
N7—Nd1—N5	96.63 (19)	C26ii—C27—H27A	119.4
C1—Pt1—C3	178.9 (3)	N11—C28—C29	175 (3)
C1—Pt1—C4	88.8 (3)	C28—C29—H29A	109.5
C3—Pt1—C4	90.2 (3)	C28—C29—H29B	109.5
C1—Pt1—C2	90.7 (3)	H29A—C29—H29B	109.5
C3—Pt1—C2	90.3 (3)	C28—C29—H29C	109.5
C4—Pt1—C2	178.1 (3)	H29A—C29—H29C	109.5
N1—C1—Pt1	178.6 (8)	H29B—C29—H29C	109.5
N2—C2—Pt1	177.1 (8)	C1—N1—Nd1	160.2 (7)
N3—C3—Pt1	176.4 (9)	C2—N2—Nd1iii	166.1 (7)
N4—C4—Pt1	179.0 (7)	O3—N5—O2	122.3 (7)
N6—C5—C6	123.8 (8)	O3—N5—O1	120.4 (7)
N6—C5—H5A	118.1	O2—N5—O1	117.3 (6)
C6—C5—H5A	118.1	O3—N5—Nd1	173.9 (6)
C7—C6—C5	119.4 (10)	O2—N5—Nd1	59.7 (4)
C7—C6—H6A	120.3	O1—N5—Nd1	58.0 (3)
C5—C6—H6A	120.3	C5—N6—C9	116.7 (8)
C6—C7—C8	118.4 (9)	C5—N6—Nd1	121.8 (5)
C6—C7—H7A	120.8	C9—N6—Nd1	121.5 (6)
C8—C7—H7A	120.8	C10—N7—C14	120.1 (7)
C7—C8—C9	119.4 (9)	C10—N7—Nd1	119.4 (5)
C7—C8—H8A	120.3	C14—N7—Nd1	118.8 (5)
C9—C8—H8A	120.3	C19—N8—C15	119.3 (8)
N6—C9—C8	122.4 (8)	C19—N8—Nd1	119.8 (6)
N6—C9—C10	116.0 (7)	C15—N8—Nd1	120.5 (6)
C8—C9—C10	121.6 (8)	C22—N9—C24	116.9 (8)
N7—C10—C11	120.4 (9)	C25—N10—C25ii	119.6 (11)
N7—C10—C9	117.9 (7)	N5—O1—Nd1	97.0 (4)
C11—C10—C9	121.7 (8)	N5—O2—Nd1	95.6 (4)
C12—C11—C10	118.3 (10)	Nd1—O4—H4A	118.3
C12—C11—H11A	120.9	Nd1—O4—H4B	139.2
C10—C11—H11A	120.9	H4A—O4—H4B	97.6
C13—C12—C11	121.0 (9)	Nd1—O5—H5B	127.5
C13—C12—H12A	119.5	Nd1—O5—H5C	122.0
C11—C12—H12A	119.5	H5B—O5—H5C	107.0

D—H···A	D—H	H···A	D···A	D—H···A
O4—H4A···N4iv	0.85	2.00	2.760 (9)	149.1
O4—H4B···N3v	0.85	2.00	2.814 (10)	160.5
O5—H5B···N9vi	0.85	2.16	2.993 (9)	167.4
O5—H5C···O1i	0.85	1.99	2.770 (8)	152.2

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O4—H4A⋯N4i	0.85	2.00	2.760 (9)	149.1
O4—H4B⋯N3ii	0.85	2.00	2.814 (10)	160.5
O5—H5B⋯N9iii	0.85	2.16	2.993 (9)	167.4
O5—H5C⋯O1iv	0.85	1.99	2.770 (8)	152.2

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .