Literature DB >> 18271536

Intramolecular energy transfer in a one-dimensional europium tetracyanoplatinate.

Branson A Maynard1, Katrina Kalachnikova, Kendra Whitehead, Zerihun Assefa, Richard E Sykora.   

Abstract

The one-dimensional, polymeric compound (C15H11N3)Eu(H2O)2(NO3)(Pt(CN)4).CH3CN (1) has been shown to display an efficient donor-acceptor intramolecular energy-transfer (IET) process where ligand donors transfer energy to the Eu (III) acceptor. Single-crystal X-ray diffraction has been used to investigate the structural features of this compound in order to help understand the observed IET process. Crystallographic data: 1, monoclinic, space group P2(1)/c, a = 12.835(1) A, b = 15.239(1) A, c = 13.751(2) A, beta = 105.594(9) degrees , V = 2590.8(5) A(3), and Z = 4 (T = 290 K).

Entities:  

Year:  2008        PMID： 18271536     DOI： 10.1021/ic702386m

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  5 in total

1.  catena-Poly[[[diaqua-(nitrato-κO,O')(2,2':6',2''-terpyridine-κN,N',N'')neodymium(III)]-μ-cyanido-κN:C-[dicyanidoplatinum(II)]-μ-cyanido-κC:N] acetonitrile solvate 2,2':6',2''-terpyridine hemisolvate].

Authors:  Branson A Maynard; Philip A Smith; Richard E Sykora
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-08-26

2.  Reversible Humidity-Driven Transformation of a Bimetallic {EuCo} Molecular Material: Structural, Sorption, and Photoluminescence Studies.

Authors:  Jakub J Zakrzewski; Michal Heczko; Robert Jankowski; Szymon Chorazy
Journal:  Molecules       Date:  2021-02-19       Impact factor: 4.411

3.  catena-Poly[[[diaqua-(nitrato-κO,O')(2,2':6',2''-terpyridine-κN,N',N'')ytterbium(III)]-μ-cyanido-κN:C-[dicyanido-platinum(II)]-μ-cyanido-κC:N] acetonitrile monosolvate].

Authors:  Philip A Smith; Milorad Stojanovic; Richard E Sykora
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-20

4.  Crystal structure of catena-poly[[aqua(2,2':6',2''-terpyridine-κ(3) N,N',N'')cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N].

Authors:  Frankie White; Richard E Sykora
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-08-06

Review 5.  Lanthanide Photoluminescence in Heterometallic Polycyanidometallate-Based Coordination Networks.

Authors:  Szymon Chorazy; Maciej Wyczesany; Barbara Sieklucka
Journal:  Molecules       Date:  2017-11-04       Impact factor: 4.411
  5 in total

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