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Literature DB >> 21573282

Self-assembly in the electrical double layer of ionic liquids.

Susan Perkin¹, Lorna Crowhurst, Heiko Niedermeyer, Tom Welton, Alexander M Smith, Nitya Nand Gosvami.

Abstract

We have studied the structure of two ionic liquids confined between negatively charged mica sheets. Both liquids exhibit interfacial layering, however the repeat distance is dramatically different for the two liquids. Our results suggest a transition from alternating cation-anion monolayers to tail-to-tail cation bilayers when the length of the cation hydrocarbon chain is increased. This journal is © The Royal Society of Chemistry 2011

Entities: Chemical

Year: 2011 PMID： 21573282 DOI： 10.1039/c1cc11322d

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

15 in total

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6. Fundamental aspects of electric double layer force-distance measurements at liquid-solid interfaces using atomic force microscopy.

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Self-assembly in the electrical double layer of ionic liquids.

1. Ionic liquids behave as dilute electrolyte solutions.

2. Long-range electrostatic screening in ionic liquids.

3. Resolving Anomalies in Predicting Electrokinetic Energy Conversion Efficiencies of Nanofluidic Devices.

4. NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors.

5. Electrotunable lubricity with ionic liquid nanoscale films.

6. Fundamental aspects of electric double layer force-distance measurements at liquid-solid interfaces using atomic force microscopy.

7. Ion structure controls ionic liquid near-surface and interfacial nanostructure.

8. What causes extended layering of ionic liquids on the mica surface?

9. The Effect of Water and Confinement on Self-Assembly of Imidazolium Based Ionic Liquids at Mica Interfaces.

10. Near-Wall Molecular Ordering of Dilute Ionic Liquids.