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Literature DB >> 21562648

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin.

S M Ibrahim Al-Rafia¹, Adam C Malcolm, Sean K Liew, Michael J Ferguson, Robert McDonald, Eric Rivard.

Abstract

The N-heterocyclic olefin, IPr=CH(2) (IPr = [(HCNDipp)(2)C], Dipp = 2,6-(i)Pr(2)C(6)H(3)) has been demonstrated to be of sufficient Lewis basicity to stabilize main group hydrides in unusually low oxidation states. This journal is © The Royal Society of Chemistry 2011

Entities: Chemical Disease Gene

Year: 2011 PMID： 21562648 DOI： 10.1039/c1cc11737h

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

6 in total

1. N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide).

Authors: Stefan Naumann; Anthony W Thomas; Andrew P Dove
Journal: Angew Chem Int Ed Engl Date: 2015-07-01 Impact factor: 15.336

2. N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds.

Authors: Jiang He; Florian Rauch; Alexandra Friedrich; Daniel Sieh; Tatjana Ribbeck; Ivo Krummenacher; Holger Braunschweig; Maik Finze; Todd B Marder
Journal: Chemistry Date: 2019-09-26 Impact factor: 5.236

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin.

1. N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide).

2. N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds.

3. Isolation of an Arsenic Diradicaloid with a Cyclic C₂ As₂ -Core.

4. Kekulé diradicaloids derived from a classical N-heterocyclic carbene.

Review 5. Lewis Pair Catalysts in the Polymerization of Lactide and Related Cyclic Esters.

6. Stable Mesoionic N-Heterocyclic Olefins (mNHOs).

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin.

1. N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide).

2. N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds.

3. Isolation of an Arsenic Diradicaloid with a Cyclic C2 As2 -Core.

4. Kekulé diradicaloids derived from a classical N-heterocyclic carbene.

Review 5. Lewis Pair Catalysts in the Polymerization of Lactide and Related Cyclic Esters.

6. Stable Mesoionic N-Heterocyclic Olefins (mNHOs).

3. Isolation of an Arsenic Diradicaloid with a Cyclic C₂ As₂ -Core.