| Literature DB >> 21522520 |
Shi-Jie Li, Dong-Liang Miao, Wen-Dong Song, Shao-Wei Tong, Jing-Bo An.
Abstract
In the title complex, [Co(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Co(II) cation is six-coordinated by two H(2)pimda(-) ligands (H(3)pimda is 2-propyl-1H-imidazole-4,5-carboxylic acid) and two water mol-ecules in a distorted octa-hedral environment. The crystal structures features a three-dimensional network stabilized by extensive O-H⋯O and N-H⋯O hydrogen bonds. The propyl groups of the ligands are disordered over two sets of sites with refined occupancies of 0.673 (8):0.327 (8) and 0.621 (17):0.379 (17). One of the water mol-ecules is located on a site with half-occupancy.Entities:
Year: 2010 PMID: 21522520 PMCID: PMC3050148 DOI: 10.1107/S1600536810052785
Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN: 1600-5368