Literature DB >> 21494949

Carbene catalysts.

Jennifer L Moore, Tomislav Rovis.   

Abstract

The use of N-heterocyclic carbenes as catalysts for organic transformations has received increased attention in the past 10 years. A discussion of catalyst development and nucleophilic characteristics precedes a description of recent advancements and new reactions using N-heterocyclic carbenes in catalysis.

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Year:  2010        PMID: 21494949      PMCID: PMC3820033          DOI: 10.1007/978-3-642-02815-1_18

Source DB:  PubMed          Journal:  Top Curr Chem        ISSN: 0340-1022


  100 in total

1.  Stable Carbenes.

Authors:  Didier Bourissou; Olivier Guerret; François P. Gabbaï; Guy Bertrand
Journal:  Chem Rev       Date:  2000-01-12       Impact factor: 60.622

2.  Chiral N-heterocyclic carbene catalyzed, enantioselective oxodiene Diels-Alder reactions with low catalyst loadings.

Authors:  Ming He; Gerson J Uc; Jeffrey W Bode
Journal:  J Am Chem Soc       Date:  2006-11-29       Impact factor: 15.419

3.  Cyano-phosphorylation of aldehydes catalyzed by a nucleophilic N-heterocyclic carbene.

Authors:  Yoshimasa Fukuda; Yuka Maeda; Kazuhiro Kondo; Toyohiko Aoyama
Journal:  Chem Pharm Bull (Tokyo)       Date:  2006-03       Impact factor: 1.645

4.  An efficient nucleophilic carbene catalyst for the asymmetric benzoin condensation.

Authors:  Dieter Enders; Ulrike Kallfass
Journal:  Angew Chem Int Ed Engl       Date:  2002-05-17       Impact factor: 15.336

5.  Tandem oxidation of allylic and benzylic alcohols to esters catalyzed by N-heterocyclic carbenes.

Authors:  Brooks E Maki; Audrey Chan; Eric M Phillips; Karl A Scheidt
Journal:  Org Lett       Date:  2007-01-18       Impact factor: 6.005

6.  Synthesis of alpha-amido ketones via organic catalysis: thiazolium-catalyzed cross-coupling of aldehydes with acylimines.

Authors:  J A Murry; D E Frantz; A Soheili; R Tillyer; E J Grabowski; P J Reider
Journal:  J Am Chem Soc       Date:  2001-10-03       Impact factor: 15.419

7.  An N-heterocyclic carbene-catalyzed [8 + 3] annulation of tropone and enals via homoenolate.

Authors:  Vijay Nair; Manojkumar Poonoth; Sreekumar Vellalath; Eringathodi Suresh; Rajasekaran Thirumalai
Journal:  J Org Chem       Date:  2006-11-10       Impact factor: 4.354

8.  Catalytic intramolecular crossed aldehyde--ketone benzoin reactions: a novel synthesis of functionalized preanthraquinones.

Authors:  Yoshifumi Hachisu; Jeffrey W Bode; Keisuke Suzuki
Journal:  J Am Chem Soc       Date:  2003-07-16       Impact factor: 15.419

9.  Enantioselective synthesis of alpha,alpha-disubstituted cyclopentenes by an N-heterocyclic carbene-catalyzed desymmetrization of 1,3-diketones.

Authors:  Manabu Wadamoto; Eric M Phillips; Troy E Reynolds; Karl A Scheidt
Journal:  J Am Chem Soc       Date:  2007-07-31       Impact factor: 15.419

10.  N-heterocyclic carbene catalyzed aza-Morita-Baylis-Hillman reaction of cyclic enones with N-tosylarylimines.

Authors:  Lin He; Teng-Yue Jian; Song Ye
Journal:  J Org Chem       Date:  2007-08-18       Impact factor: 4.354

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  38 in total

1.  Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst.

Authors:  Daniel A DiRocco; Elizabeth L Noey; K N Houk; Tomislav Rovis
Journal:  Angew Chem Int Ed Engl       Date:  2012-01-26       Impact factor: 15.336

2.  Chiral N-heterocyclic carbene-catalyzed generation of ester enolate equivalents from {alpha},{beta}-unsaturated aldehydes for enantioselective Diels-Alder reactions.

Authors:  Juthanat Kaeobamrung; Marisa C Kozlowski; Jeffrey W Bode
Journal:  Proc Natl Acad Sci U S A       Date:  2010-10-25       Impact factor: 11.205

3.  Organocatalytic hydroacylation of unactivated alkenes.

Authors:  Daniel A DiRocco; Tomislav Rovis
Journal:  Angew Chem Int Ed Engl       Date:  2011-06-30       Impact factor: 15.336

4.  N-heterocyclic carbene-catalyzed rearrangements of vinyl sulfones.

Authors:  Roxanne L Atienza; Howard S Roth; Karl A Scheidt
Journal:  Chem Sci       Date:  2011-06-10       Impact factor: 9.825

5.  Scaffolding catalysts: highly enantioselective desymmetrization reactions.

Authors:  Xixi Sun; Amanda D Worthy; Kian L Tan
Journal:  Angew Chem Int Ed Engl       Date:  2011-07-07       Impact factor: 15.336

6.  Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives.

Authors:  Daniel A DiRocco; Tomislav Rovis
Journal:  J Am Chem Soc       Date:  2011-06-16       Impact factor: 15.419

Review 7.  The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.

Authors:  Mikail E Abbasov; Daniel Romo
Journal:  Nat Prod Rep       Date:  2014-10       Impact factor: 13.423

8.  Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis.

Authors:  Jean Bouffard; Benjamin K Keitz; Ralf Tonner; Vincent Lavallo; Gregorio Guisado-Barrios; Gernot Frenking; Robert H Grubbs; Guy Bertrand
Journal:  Organometallics       Date:  2011-03-09       Impact factor: 3.876

9.  Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes.

Authors:  Harit U Vora; Philip Wheeler; Tomislav Rovis
Journal:  Adv Synth Catal       Date:  2012-04-19       Impact factor: 5.837

10.  Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams.

Authors:  Nicholas A White; Daniel A DiRocco; Tomislav Rovis
Journal:  J Am Chem Soc       Date:  2013-05-28       Impact factor: 15.419

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