Literature DB >> 21452081

Hydrogen atom donors: recent developments.

Andreas Gansäuer1, Lei Shi, Matthias Otte, Inga Huth, Antonio Rosales, Iris Sancho-Sanz, Natalia M Padial, J Enrique Oltra.   

Abstract

This review highlights recent developments in the field of hydrogen atom transfer (HAT) reagents that circumvent the disadvantages of classical group 14 reagents, such as Bu₃SnH. Special emphasis is laid on the lowering of bond dissociation energies (BDEs) of molecules that could, as yet, not be used as HAT reagents and on the use of organometallic HAT reagents.

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Year:  2012        PMID： 21452081     DOI： 10.1007/128_2011_124

Source DB:  PubMed          Journal:  Top Curr Chem        ISSN： 0340-1022


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