Literature DB >> 21438593

Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd.

Adam F Lee1, Christine V Ellis, James N Naughton, Mark A Newton, Christopher M A Parlett, Karen Wilson.   

Abstract

Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.

Entities:  

Year:  2011        PMID： 21438593     DOI： 10.1021/ja200684f

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Spatially orthogonal chemical functionalization of a hierarchical pore network for catalytic cascade reactions.

Authors:  Christopher M A Parlett; Mark A Isaacs; Simon K Beaumont; Laura M Bingham; Nicole S Hondow; Karen Wilson; Adam F Lee
Journal:  Nat Mater       Date:  2015-11-16       Impact factor: 43.841

2.  3D chemical imaging in the laboratory by hyperspectral X-ray computed tomography.

Authors:  C K Egan; S D M Jacques; M D Wilson; M C Veale; P Seller; A M Beale; R A D Pattrick; P J Withers; R J Cernik
Journal:  Sci Rep       Date:  2015-10-30       Impact factor: 4.379

3.  Restructuring and Hydrogen Evolution on Pt Nanoparticle.

Authors:  Guang-Feng Wei; Zhi-Pan Liu
Journal:  Chem Sci       Date:  2014-11-26       Impact factor: 9.825

4.  A silver NP-dispersed water extract of fly ash as a green and efficient medium for oxidant-free dehydrogenation of benzyl alcohols.

Authors:  Bishal Bhuyan; Arijita Paul; Meghali Devi; Siddhartha Sankar Dhar
Journal:  RSC Adv       Date:  2018-01-02       Impact factor: 3.361
  4 in total

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