| Literature DB >> 21437316 |
Rina Soni1, Fung Kei Cheung, Guy C Clarkson, Jose E D Martins, Mark A Graham, Martin Wills.
Abstract
Ru(II) complexes of TsDPEN containing two alkyl groups on the non-tosylated nitrogen atom are poor catalysts for asymmetric transfer hydrogenation of ketones and imines; this observation provides direct evidence for the importance of the N-H interaction in the transition state for ketone reduction.Entities:
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Year: 2011 PMID： 21437316 DOI： 10.1039/c1ob05208j
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876