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Literature DB >> 21370348

Rapid total syntheses utilizing "supersilyl" chemistry.

Brian J Albert¹, Yousuke Yamaoka, Hisashi Yamamoto.

Abstract

Entities: Chemical Disease Gene Species

Mesh：

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Year: 2011 PMID： 21370348 PMCID： PMC3086072 DOI： 10.1002/anie.201007210

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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16 in total

1. A New Role for Polyketides.

Authors:
Journal: Angew Chem Int Ed Engl Date: 2000-08-18 Impact factor: 15.336

2. Tandem aldol-allylation and aldol-aldol reactions with ketone-derived enolsilanes: highly diastereoselective single-step synthesis of complex tertiary carbinols.

Authors: Xiaolun Wang; Qinglin Meng; Nicholas R Perl; Yue Xu; James L Leighton
Journal: J Am Chem Soc Date: 2005-09-21 Impact factor: 15.419

3. Tris(trimethylsilyl)silyl-governed aldehyde cross-aldol cascade reaction.

Authors: Matthew B Boxer; Hisashi Yamamoto
Journal: J Am Chem Soc Date: 2006-01-11 Impact factor: 15.419

4. Direct amino acid catalyzed asymmetric synthesis of polyketide sugars.

Authors: Jesús Casas; Magnus Engqvist; Ismail Ibrahem; Betul Kaynak; Armando Córdova
Journal: Angew Chem Int Ed Engl Date: 2005-02-18 Impact factor: 15.336

Review 5. Polyketide stereotetrads in natural products.

Authors: Ari M P Koskinen; Kaisa Karisalmi
Journal: Chem Soc Rev Date: 2005-04-25 Impact factor: 54.564

6. Redox economy in organic synthesis.

Authors: Noah Z Burns; Phil S Baran; Reinhard W Hoffmann
Journal: Angew Chem Int Ed Engl Date: 2009 Impact factor: 15.336

7. Super silyl stereo-directing groups for complete 1,5-syn and -anti stereoselectivities in the aldol reactions of beta-siloxy methyl ketones with aldehydes.

Authors: Yousuke Yamaoka; Hisashi Yamamoto
Journal: J Am Chem Soc Date: 2010-04-21 Impact factor: 15.419

8. Aluminum Bis(trifluoromethylsulfonyl)amides: New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions.

Authors:
Journal: Angew Chem Int Ed Engl Date: 2000-01 Impact factor: 15.336

9. Application of stereoselective ether transfer to the synthesis of isotactic polyethers.

Authors: Kai Liu; Joseph W Arico; Richard E Taylor
Journal: J Org Chem Date: 2010-06-18 Impact factor: 4.354

10. Anticancer agents from the Australian tropical rainforest: Spiroacetals EBC-23, 24, 25, 72, 73, 75 and 76.

Authors: Lin Dong; Heiko Schill; Rebecca L Grange; Achim Porzelle; Jenny P Johns; Peter G Parsons; Victoria A Gordon; Paul W Reddell; Craig M Williams
Journal: Chemistry Date: 2009-10-26 Impact factor: 5.236

10 in total

1. Rapid and stereochemically flexible synthesis of polypropionates: super-silyl-governed aldol cascades.

Authors: Patrick B Brady; Hisashi Yamamoto
Journal: Angew Chem Int Ed Engl Date: 2012-01-17 Impact factor: 15.336

2. The supersilyl group as a carboxylic acid protecting group: application to highly stereoselective aldol and Mannich reactions.

Authors: Jiajing Tan; Matsujiro Akakura; Hisashi Yamamoto
Journal: Angew Chem Int Ed Engl Date: 2013-05-29 Impact factor: 15.336

Rapid total syntheses utilizing "supersilyl" chemistry.

1. A New Role for Polyketides.

2. Tandem aldol-allylation and aldol-aldol reactions with ketone-derived enolsilanes: highly diastereoselective single-step synthesis of complex tertiary carbinols.

3. Tris(trimethylsilyl)silyl-governed aldehyde cross-aldol cascade reaction.

4. Direct amino acid catalyzed asymmetric synthesis of polyketide sugars.

Review 5. Polyketide stereotetrads in natural products.

6. Redox economy in organic synthesis.

7. Super silyl stereo-directing groups for complete 1,5-syn and -anti stereoselectivities in the aldol reactions of beta-siloxy methyl ketones with aldehydes.

8. Aluminum Bis(trifluoromethylsulfonyl)amides: New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions.

9. Application of stereoselective ether transfer to the synthesis of isotactic polyethers.

10. Anticancer agents from the Australian tropical rainforest: Spiroacetals EBC-23, 24, 25, 72, 73, 75 and 76.

1. Rapid and stereochemically flexible synthesis of polypropionates: super-silyl-governed aldol cascades.

2. The supersilyl group as a carboxylic acid protecting group: application to highly stereoselective aldol and Mannich reactions.

3. Rapid, one-pot synthesis of β-siloxy-α-haloaldehydes.

4. Synthesis of β-hydroxy-α-haloesters through super silyl ester directed syn-selective aldol reaction.

5. Generation of organolithium compounds bearing super silyl ester and their application to Matteson rearrangement.

6. β-Siloxy-α-haloketones through highly diastereoselective single and double mukaiyama aldol reactions.

7. Enantioselective Total Synthesis of (+)-EBC-23, a Potent Anticancer Agent from the Australian Rainforest.

Review 8. Bioinspired iterative synthesis of polyketides.

9. Stereodivergent approach to the avermectins based on "super silyl" directed aldol reactions.

10. A highly diastereoselective "super silyl" governed aldol reaction: synthesis of α,β-dioxyaldehydes and 1,2,3-triols.