| Literature DB >> 24205937 |
Susumu Oda1, Hisashi Yamamoto.
Abstract
Super silyl haloesters including chloro- and bromoacetate were synthesized and utilized for aldol reactions to give syn-β-hydroxy-α-haloacetates in good yields with high diastereoselectivities. β-Hydroxy-α-fluoroacetate was obtained by lithiation of super silyl bromofluoroacetate. Sequential Darzens reactions provided cis-glycidic esters in moderate yields.Entities:
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Year: 2013 PMID： 24205937 PMCID： PMC3946542 DOI： 10.1021/ol402928p
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005