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Literature DB >> 21369574

Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand.

Emily Y Tsui¹, Jacob S Kanady, Michael W Day, Theodor Agapie.

Abstract

Trinuclear complexes of Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) were synthesized using a ligand architecture based upon a 1,3,5-triarylbenzene core decorated with six pyridines and three alkoxide moieties. Characterization via X-ray diffraction, NMR, and magnetism studies is discussed.

Entities: Chemical

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Year: 2011 PMID： 21369574 DOI： 10.1039/c0cc05608a

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

17 in total

1. Oxidative atom-transfer to a trimanganese complex to form Mn6(μ6-E) (E = O, N) clusters featuring interstitial oxide and nitride functionalities.

Authors: Alison R Fout; Qinliang Zhao; Dianne J Xiao; Theodore A Betley
Journal: J Am Chem Soc Date: 2011-09-30 Impact factor: 15.419

2. Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic Mn₃MO₄ Cubane and Fe₃MO(OH) and Mn₃MO(OH) Clusters.

Authors: Davide Lionetti; Sandy Suseno; Emily Y Tsui; Luo Lu; Troy A Stich; Kurtis M Carsch; Robert J Nielsen; William A Goddard; R David Britt; Theodor Agapie
Journal: Inorg Chem Date: 2019-02-07 Impact factor: 5.165

3. Nitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexes.

Authors: Graham de Ruiter; Niklas B Thompson; Davide Lionetti; Theodor Agapie
Journal: J Am Chem Soc Date: 2015-11-02 Impact factor: 15.419

4. A CaMn₄O₂ model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand.

Authors: Heui Beom Lee; Emily Y Tsui; Theodor Agapie
Journal: Chem Commun (Camb) Date: 2017-06-22 Impact factor: 6.222

5. Trigonal Mn3 and Co3 clusters supported by weak-field ligands: a structural, spectroscopic, magnetic, and computational investigation into the correlation of molecular and electronic structure.

Authors: Alison R Fout; Dianne J Xiao; Qinliang Zhao; T David Harris; Evan R King; Emily V Eames; Shao-Liang Zheng; Theodore A Betley
Journal: Inorg Chem Date: 2012-09-19 Impact factor: 5.165

Trinuclear first row transition metal complexes of a hexapyridyl, trialkoxy 1,3,5-triarylbenzene ligand.

1. Oxidative atom-transfer to a trimanganese complex to form Mn6(μ6-E) (E = O, N) clusters featuring interstitial oxide and nitride functionalities.

2. Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic Mn₃MO₄ Cubane and Fe₃MO(OH) and Mn₃MO(OH) Clusters.

3. Nitric oxide activation by distal redox modulation in tetranuclear iron nitrosyl complexes.

4. A CaMn₄O₂ model of the biological oxygen evolving complex: synthesis via cluster expansion on a low symmetry ligand.

5. Trigonal Mn3 and Co3 clusters supported by weak-field ligands: a structural, spectroscopic, magnetic, and computational investigation into the correlation of molecular and electronic structure.

6. Reversible halide-modulated nickel-nickel bond cleavage: metal-metal bonds as design elements for molecular devices.

Review 7. Lessons from Nature: A Bio-Inspired Approach to Molecular Design.

8. Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals.

9. Synthetic cluster models of biological and heterogeneous manganese catalysts for O2 evolution.

10. Metal-Templated Ligand Architectures for Trinuclear Chemistry: Tricopper Complexes and Their O₂ Reactivity.