Literature DB >> 21355550

Rh(NHC)-catalyzed direct and selective arylation of quinolines at the 8-position.

Jaesung Kwak1, Min Kim, Sukbok Chang.   

Abstract

A new catalytic protocol for the regioselective direct arylation of quinoline derivatives at the 8-position has been developed. The reaction is catalyzed by a Rh(NHC) system, and the choice of the NHC ligand was most important for achieving high reactivity and selectivity.

Entities:  

Year:  2011        PMID: 21355550     DOI: 10.1021/ja111670s

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  14 in total

1.  A general method for copper-catalyzed arene cross-dimerization.

Authors:  Hien-Quang Do; Olafs Daugulis
Journal:  J Am Chem Soc       Date:  2011-08-08       Impact factor: 15.419

2.  Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade.

Authors:  Yajing Lian; Joshua R Hummel; Robert G Bergman; Jonathan A Ellman
Journal:  J Am Chem Soc       Date:  2013-08-19       Impact factor: 15.419

3.  Experimental and mechanistic analysis of the palladium-catalyzed oxidative C8-selective C-H homocoupling of quinoline N-oxides.

Authors:  David E Stephens; Johant Lakey-Beitia; Gabriel Chavez; Carla Ilie; Hadi D Arman; Oleg V Larionov
Journal:  Chem Commun (Camb)       Date:  2015-06-11       Impact factor: 6.222

4.  Recent Advances in the C-H-Functionalization of the Distal Positions in Pyridines and Quinolines.

Authors:  David E Stephens; Oleg V Larionov
Journal:  Tetrahedron       Date:  2015-08-19       Impact factor: 2.457

Review 5.  N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

Authors:  Qun Zhao; Guangrong Meng; Steven P Nolan; Michal Szostak
Journal:  Chem Rev       Date:  2020-01-22       Impact factor: 60.622

6.  Overcoming the limitations of directed C-H functionalizations of heterocycles.

Authors:  Yue-Jin Liu; Hui Xu; Wei-Jun Kong; Ming Shang; Hui-Xiong Dai; Jin-Quan Yu
Journal:  Nature       Date:  2014-11-10       Impact factor: 49.962

7.  Palladium-Catalyzed C8-Selective C-H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric and Solvation Effects on the Site-Selectivity by Mechanistic and DFT Computational Studies.

Authors:  David E Stephens; Johant Lakey-Beitia; Abdurrahman C Atesin; Tülay A Ateşin; Gabriel Chavez; Hadi D Arman; Oleg V Larionov
Journal:  ACS Catal       Date:  2015-01-02       Impact factor: 13.084

8.  Rhodium-catalyzed C-H functionalization of heteroarenes using indoleBX hypervalent iodine reagents.

Authors:  Erwann Grenet; Ashis Das; Paola Caramenti; Jérôme Waser
Journal:  Beilstein J Org Chem       Date:  2018-05-25       Impact factor: 2.883

9.  The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium-to-Gold Transmetalation.

Authors:  Christophe Werlé; Richard Goddard; Alois Fürstner
Journal:  Angew Chem Int Ed Engl       Date:  2015-11-04       Impact factor: 15.336

10.  Pd(ii)-catalyzed remote regiodivergent ortho- and meta-C-H functionalizations of phenylethylamines.

Authors:  Shangda Li; Huafang Ji; Lei Cai; Gang Li
Journal:  Chem Sci       Date:  2015-06-25       Impact factor: 9.825

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