Literature DB >> 21344897

Aliphatic C-H to C-C conversion: synthesis of (-)-cameroonan-7α-ol.

Douglass F Taber1, Christopher G Nelson.   

Abstract

In the course of a synthesis of the tricyclic sesquiterpene (-)-cameroonan-7α-ol from the acyclic (+)-citronellal, seven aliphatic C-H bonds were converted to C-C bonds, and three rings and four new stereogenic centers were established.

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Year:  2011        PMID： 21344897      PMCID： PMC3074237          DOI： 10.1021/jo200075v

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  21 in total

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4.  Synthesis of (+)-sulcatine G.

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Journal:  J Org Chem       Date:  2005-08-05       Impact factor: 4.354

5.  Enantioselective synthesis of Bakuchiol using diazosulfonate C-H insertion to install the quaternary center.

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Journal:  Tetrahedron Lett       Date:  2009-12-16       Impact factor: 2.415

6.  Total synthesis of eudesmane terpenes by site-selective C-H oxidations.

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7.  C-H bond functionalization via hydride transfer: Lewis acid catalyzed alkylation reactions by direct intramolecular coupling of sp3 C-H bonds and reactive alkenyl oxocarbenium intermediates.

Authors:  Kevin M McQuaid; Dalibor Sames
Journal:  J Am Chem Soc       Date:  2009-01-21       Impact factor: 15.419

8.  Pd(II)-catalyzed cross-coupling of sp3 C-H Bonds with sp2 and sp3 boronic acids using air as the oxidant.

Authors:  Dong-Hui Wang; Masayuki Wasa; Ramesh Giri; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2008-05-14       Impact factor: 15.419

9.  Stereocontrolled photocyclization of 1,2-diketones: application of a 1,3-acetyl group transfer methodology to carbohydrates.

Authors:  Antonio J Herrera; María Rondón; Ernesto Suárez
Journal:  J Org Chem       Date:  2008-03-28       Impact factor: 4.354

10.  Synthesis of (-)-hamigeran B.

Authors:  Douglass F Taber; Weiwei Tian
Journal:  J Org Chem       Date:  2008-09-05       Impact factor: 4.354
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  2 in total

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