Literature DB >> 21202125

2-(Benzotriazol-1-ylmethyl-amino)-benzoic acid.

Yao Wang1, Mai-Hua Yin, Guo-Fang Zhang.   

Abstract

The title compound, C(14)H(12)N(4)O(2), a new N,O,N'-tridentate ligand, is V-shaped with the mean plane through the benzotriazole system [planar to within 0.013 (2) Å] inclined by 67.7 (1)° to the mean plane through the benzene ring. In the mol-ecule there is an intra-molecular N-H⋯O hydrogen bond involving the amine H atom and the carbonyl O atom. In the crystal structure, symmtry-related mol-ecules are connected by inter-molecular O-H⋯N and C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

Entities:  

Year:  2008        PMID: 21202125      PMCID: PMC2960979          DOI: 10.1107/S160053680800740X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


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1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

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1.  1,1'-[(2,3,3a,4,5,6,7,7a-Octa-hydro-1H-1,3-benzimidazole-1,3-di-yl)bis-(methyl-ene)]bis-(1H-benzotriazole).

Authors:  Augusto Rivera; Dency José Pacheco; Jaime Ríos-Motta; Michaela Pojarová; Michal Dušek
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-10-29
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