catena-Poly[[diaqua-dipyridine-zinc(II)]-μ-succinato].

In the title compound, [Zn(C(4)H(4)O(4))(C(5)H(5)N)(2)(H(2)O)(2)](n), the Zn(II) ion (site symmetry ) is coordinated in an octahedral geometry by two pyridine mol-ecules, two water mol-ecules and two bridging centrosymmetric O-monodentate succinate dianions to create one-dimensional polymeric chains. The chains are cross-linked by O-H⋯O hydrogen bonds, forming sheets.

Related literature

For a related structure containing fumarate ions, see: Ohmura et al. (2003 ▶).

Experimental

Crystal data

[Zn(C4H4O4)(C5H5N)2(H2O)2]

M = 375.67

Orthorhombic,

a = 11.8142 (8) Å

b = 8.9111 (7) Å

c = 14.9705 (10) Å

V = 1576.06 (19) Å3

Z = 4

Mo Kα radiation

μ = 1.59 mm−1

T = 273 (2) K

0.08 × 0.08 × 0.04 mm

Data collection

Bruker–Nonius APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 2007 ▶) T min = 0.804, T max = 0.931

9256 measured reflections

1814 independent reflections

1200 reflections with I > 2σ(I)

R int = 0.067

Refinement

R[F 2 > 2σ(F 2)] = 0.065

wR(F 2) = 0.107

S = 1.13

1814 reflections

138 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.55 e Å−3

Δρmin = −0.46 e Å−3

Data collection: COLLECT (Hooft, 1998 ▶); cell refinement: DENZO (Otwinowski and Minor, 1997 ▶) and COLLECT; data reduction: DENZO and COLLECT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: Mercury (Macrae et al., 2006 ▶); software used to prepare material for publication: Mercury and local program.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808006764/hb2701sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808006764/hb2701Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Zn(C4H4O4)(C5H5N)2(H2O)2]	F000 = 776
Mr = 375.67	Dx = 1.583 Mg m−3
Orthorhombic, Pbca	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 2052 reflections
a = 11.8142 (8) Å	θ = 2.9–27.5º
b = 8.9111 (7) Å	µ = 1.59 mm−1
c = 14.9705 (10) Å	T = 273 (2) K
V = 1576.06 (19) Å3	Block, colourless
Z = 4	0.08 × 0.08 × 0.04 mm

Bruker–Nonious APEXII CCD camera on κ-goniostat diffractometer	1814 independent reflections
Radiation source: fine-focus sealed tube	1200 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.067
Detector resolution: 4096x4096pixels / 62x62mm pixels mm-1	θmax = 27.6º
T = 273(2) K	θmin = 3.2º
φ and ω scans	h = −15→15
Absorption correction: multi-scan(SADABS; Sheldrick, 2007)	k = −11→10
Tmin = 0.804, Tmax = 0.931	l = −19→17
9256 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: difmap and geom
R[F2 > 2σ(F2)] = 0.065	H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.108	w = 1/[σ2(Fo2) + 9.8897P] where P = (Fo2 + 2Fc2)/3
S = 1.13	(Δ/σ)max < 0.001
1814 reflections	Δρmax = 0.55 e Å−3
138 parameters	Δρmin = −0.45 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

	x	y	z	Uiso*/Ueq
Zn1	0.5000	0.0000	0.5000	0.0147 (2)
O3	0.6625 (3)	0.0017 (4)	0.4416 (2)	0.0186 (7)
H3A	0.6910	0.0850	0.4477	0.028*
O2	0.5136 (3)	0.2237 (4)	0.5340 (2)	0.0179 (7)
O1	0.6873 (3)	0.2905 (4)	0.4901 (2)	0.0229 (8)
C3	0.3411 (5)	0.1656 (6)	0.2097 (4)	0.0290 (13)
C2	0.4391 (5)	0.2285 (6)	0.2438 (4)	0.0254 (12)
C5	0.3356 (4)	0.0065 (7)	0.3386 (3)	0.0206 (10)
C6	0.5888 (4)	0.3201 (5)	0.5168 (3)	0.0172 (10)
N1	0.4308 (3)	0.0673 (4)	0.3719 (3)	0.0156 (8)
C1	0.4810 (4)	0.1762 (6)	0.3235 (3)	0.0199 (11)
C7	0.5529 (4)	0.4835 (6)	0.5275 (4)	0.0224 (11)
C4	0.2892 (5)	0.0528 (7)	0.2586 (4)	0.0279 (13)
H4	0.224 (5)	0.010 (6)	0.243 (3)	0.025 (15)*
H1	0.549 (4)	0.205 (6)	0.345 (3)	0.018 (13)*
H3	0.308 (5)	0.199 (7)	0.154 (4)	0.035 (17)*
H5	0.304 (4)	−0.066 (6)	0.376 (4)	0.026 (15)*
H2	0.476 (5)	0.295 (6)	0.209 (4)	0.028 (16)*
H7A	0.540 (4)	0.492 (6)	0.591 (4)	0.018 (13)*
H7	0.616 (4)	0.549 (5)	0.514 (3)	0.014 (13)*
H3B	0.694 (5)	−0.064 (7)	0.459 (4)	0.04 (2)*

	U11	U22	U33	U12	U13	U23
Zn1	0.0146 (3)	0.0125 (3)	0.0169 (4)	0.0005 (4)	0.0010 (3)	0.0002 (4)
O3	0.0190 (16)	0.0113 (16)	0.0254 (18)	0.0048 (18)	0.0012 (13)	0.0012 (17)
O2	0.0192 (16)	0.0116 (16)	0.0229 (16)	−0.0006 (14)	0.0033 (14)	0.0022 (14)
O1	0.0160 (15)	0.0137 (18)	0.039 (2)	−0.0010 (17)	0.0048 (15)	0.0000 (13)
C3	0.041 (3)	0.026 (3)	0.020 (3)	0.004 (2)	−0.012 (2)	0.001 (3)
C2	0.036 (3)	0.021 (3)	0.019 (3)	0.000 (2)	0.004 (2)	−0.006 (2)
C5	0.019 (2)	0.022 (3)	0.021 (2)	0.000 (3)	0.0002 (18)	0.001 (2)
C6	0.019 (2)	0.015 (2)	0.018 (3)	0.003 (2)	−0.0046 (18)	0.0011 (19)
N1	0.0181 (19)	0.012 (2)	0.017 (2)	0.0011 (17)	0.0012 (16)	0.0016 (17)
C1	0.020 (3)	0.018 (3)	0.022 (3)	−0.001 (2)	−0.002 (2)	−0.001 (2)
C7	0.020 (2)	0.014 (3)	0.034 (3)	−0.001 (2)	−0.005 (2)	−0.003 (2)
C4	0.028 (3)	0.026 (3)	0.029 (3)	0.003 (3)	−0.007 (2)	−0.005 (3)

Zn1—O2	2.064 (3)	C2—C1	1.374 (7)
Zn1—O2i	2.064 (3)	C2—H2	0.90 (6)
Zn1—O3i	2.110 (3)	C5—N1	1.345 (6)
Zn1—O3	2.110 (3)	C5—C4	1.379 (7)
Zn1—N1i	2.170 (4)	C5—H5	0.93 (6)
Zn1—N1	2.170 (4)	C6—C7	1.525 (7)
O3—H3A	0.8200	N1—C1	1.348 (6)
O3—H3B	0.74 (6)	C1—H1	0.90 (5)
O2—C6	1.263 (6)	C7—C7ii	1.526 (9)
O1—C6	1.258 (5)	C7—H7A	0.97 (5)
C3—C2	1.383 (8)	C7—H7	0.97 (5)
C3—C4	1.387 (8)	C4—H4	0.89 (6)
C3—H3	0.96 (6)
O2—Zn1—O2i	180.0	C1—C2—H2	123 (4)
O2—Zn1—O3i	88.60 (13)	C3—C2—H2	118 (4)
O2i—Zn1—O3i	91.40 (13)	N1—C5—C4	122.2 (5)
O2—Zn1—O3	91.40 (13)	N1—C5—H5	113 (3)
O2i—Zn1—O3	88.60 (13)	C4—C5—H5	125 (3)
O3i—Zn1—O3	180.0	O1—C6—O2	124.9 (4)
O2—Zn1—N1i	91.12 (14)	O1—C6—C7	119.4 (4)
O2i—Zn1—N1i	88.88 (14)	O2—C6—C7	115.7 (4)
O3i—Zn1—N1i	88.53 (14)	C5—N1—C1	117.3 (4)
O3—Zn1—N1i	91.47 (14)	C5—N1—Zn1	122.1 (3)
O2—Zn1—N1	88.88 (14)	C1—N1—Zn1	120.5 (3)
O2i—Zn1—N1	91.12 (14)	N1—C1—C2	123.5 (5)
O3i—Zn1—N1	91.47 (14)	N1—C1—H1	114 (3)
O3—Zn1—N1	88.53 (14)	C2—C1—H1	122 (3)
N1i—Zn1—N1	180	C6—C7—C7ii	110.8 (5)
Zn1—O3—H3A	109.5	C6—C7—H7A	103 (3)
Zn1—O3—H3B	108 (5)	C7ii—C7—H7A	112 (3)
H3A—O3—H3B	118.2	C6—C7—H7	110 (3)
C6—O2—Zn1	131.5 (3)	C7ii—C7—H7	114 (3)
C2—C3—C4	118.0 (5)	H7A—C7—H7	106 (4)
C2—C3—H3	122 (3)	C5—C4—C3	120.0 (5)
C4—C3—H3	120 (3)	C5—C4—H4	116 (3)
C1—C2—C3	118.9 (5)	C3—C4—H4	124 (4)
O3i—Zn1—O2—C6	−174.6 (4)	O3—Zn1—N1—C5	137.5 (4)
O3—Zn1—O2—C6	5.4 (4)	O2—Zn1—N1—C1	47.0 (4)
N1i—Zn1—O2—C6	96.9 (4)	O2i—Zn1—N1—C1	−133.0 (4)
N1—Zn1—O2—C6	−83.1 (4)	O3i—Zn1—N1—C1	135.6 (4)
C4—C3—C2—C1	0.5 (8)	O3—Zn1—N1—C1	−44.4 (4)
Zn1—O2—C6—O1	−16.8 (7)	C5—N1—C1—C2	1.0 (7)
Zn1—O2—C6—C7	161.3 (3)	Zn1—N1—C1—C2	−177.2 (4)
C4—C5—N1—C1	−0.5 (7)	C3—C2—C1—N1	−1.0 (8)
C4—C5—N1—Zn1	177.6 (4)	O1—C6—C7—C7ii	123.7 (6)
O2—Zn1—N1—C5	−131.1 (4)	O2—C6—C7—C7ii	−54.5 (7)
O2i—Zn1—N1—C5	48.9 (4)	N1—C5—C4—C3	0.1 (9)
O3i—Zn1—N1—C5	−42.5 (4)	C2—C3—C4—C5	−0.1 (9)

D—H···A	D—H	H···A	D···A	D—H···A
O3—H3A···O1	0.82	1.94	2.690 (5)	152
O3—H3B···O1iii	0.74 (6)	1.97 (6)	2.687 (5)	164 (5)

Zn1—O2	2.064 (3)
Zn1—O3	2.110 (3)
Zn1—N1	2.170 (4)

O2i—Zn1—N1i

88.88 (14)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O3—H3A⋯O1	0.82	1.94	2.690 (5)	152
O3—H3B⋯O1ii	0.74 (6)	1.97 (6)	2.687 (5)	164 (5)

Symmetry code: (ii) .