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Literature DB >> 21201605

Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) dihydrate.

Wen-Yan Liu, Hu Zhou, Ji-Xi Guo, Ai-Hua Yuan.

Abstract

The title complex, [Ni(II)(C(2)H(8)N(2))(3)](2)[Mo(IV)(CN)(8)]·2H(2)O, crystallized from a mixture of ethane-1,2-diamine (en), octa-cyano-molybdate(IV), [Mo(CN)(8)](4-), and the transition metal ion Ni(2+). In the crystal structure, the Mo polyhedron has a square-anti-prismatic shape, while the geometry around the Ni atom is distorted octa-hedral. The complex ions and water mol-ecules are linked by hydrogen bonds.

Entities: CellLine Chemical Disease Species

Year: 2008 PMID： 21201605 PMCID： PMC2960526 DOI： 10.1107/S1600536808024963

Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN： 1600-5368

3 in total

1. Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Delta,Lambda-MII(en)3][cis-MII(en)2(OH2)][MIV(CN)8].2H2O and [cis-MII(en)2(OH2)]2[(mu-NC)2MIV(CN)6].4H2O (MII = Mn, Co, Ni; MIV = Mo, W).

Authors: Jeffrey R Withers; Chad Ruschmann; Pasano Bojang; Sean Parkin; Stephen M Holmes
Journal: Inorg Chem Date: 2005-01-24 Impact factor: 5.165

2. A short history of SHELX.

Authors: George M Sheldrick
Journal: Acta Crystallogr A Date: 2007-12-21 Impact factor: 2.290

3. Crystal structures and magnetic properties of two low-dimensional materials constructed from [Mn(III)(salen)H2O]+ and [M(CN)8](3-/4-) (M = Mo or W) precursors.

Authors: Paweł Przychodzeń; Krzysztof Lewiński; Maria Bałanda; Robert Pełka; Michał Rams; Tadeusz Wasiutyński; Carine Guyard-Duhayon; Barbara Sieklucka
Journal: Inorg Chem Date: 2004-05-03 Impact factor: 5.165

3 in total

Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) dihydrate.

1. Synthesis and structural characterization of bi- and trimetallic octacyanometalate(IV) complexes: [Delta,Lambda-MII(en)3][cis-MII(en)2(OH2)][MIV(CN)8].2H2O and [cis-MII(en)2(OH2)]2[(mu-NC)2MIV(CN)6].4H2O (MII = Mn, Co, Ni; MIV = Mo, W).

2. A short history of SHELX.

3. Crystal structures and magnetic properties of two low-dimensional materials constructed from [Mn(III)(salen)H2O]+ and [M(CN)8](3-/4-) (M = Mo or W) precursors.

1. Tris(2,2'-bipyridine-κN,N')cobalt(III) octa-cyanido-tungstate(V).

2. Bis[tris-(ethane-1,2-diamine)nickel(II)] octa-cyanidomolybdate(IV) penta-hydrate.

3. Diaqua-(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-deca-ne)nickel(II) tetra-cyanidonickelate(II).