4,4'-Methyl-enedianilinium bis-(3-carb-oxy-4-hydroxy-benzene-sulfonate) monohydrate.

Co-crystallization of 4,4'-methyl-enediphenyl-amine (MDA) and 5-sulfosalicylic acid (5-H(2)SSA) yields the title salt, C(13)H(16)N(2) (2+)·2C(7)H(5)O(6)S(-)·H(2)O. The asymmetric unit is comprised of one dication, two anions and one water mol-ecule. In the crystal structure, the components of the salt are linked by a combination of inter-molecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds into a three-dimensional framework. In addition, two weak π-π inter-actions [with centroid-centroid distances of 3.8734 (15) and 3.7465 (15) Å] and one C-H⋯π inter-action further stabilize the crystal structure.

Related literature

For related structures, see: Smith (2005 ▶); Smith et al. (2005a ▶,b ▶, 2006 ▶). For background information, see: Wang et al. (2008 ▶).

Experimental

Crystal data

C13H16N2 2+·2C7H5O6S−·H2O

M = 652.63

Monoclinic,

a = 5.8769 (1) Å

b = 18.8659 (3) Å

c = 12.9864 (2) Å

β = 94.668 (1)°

V = 1435.06 (4) Å3

Z = 2

Mo Kα radiation

μ = 0.26 mm−1

T = 296 (2) K

0.40 × 0.30 × 0.04 mm

Data collection

Bruker SMART APEX CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.894, T max = 0.990

16262 measured reflections

6379 independent reflections

5671 reflections with I > 2σ(I)

R int = 0.023

Refinement

R[F 2 > 2σ(F 2)] = 0.040

wR(F 2) = 0.106

S = 1.09

6379 reflections

433 parameters

1 restraint

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.33 e Å−3

Δρmin = −0.17 e Å−3

Absolute structure: Flack (1983 ▶), 3009 Friedel pairs

Flack parameter: 0.05 (6)

Data collection: SMART (Bruker, 2007 ▶); cell refinement: SAINT-Plus (Bruker, 2007 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: PLATON (Spek, 2003 ▶); software used to prepare material for publication: PLATON.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808029115/lh2691sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808029115/lh2691Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C13H16N22+·2C7H5O6S−·H2O	F(000) = 680
Mr = 652.63	Dx = 1.510 Mg m−3
Monoclinic, P21	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2yb	Cell parameters from 7439 reflections
a = 5.8769 (1) Å	θ = 2.7–27.0°
b = 18.8659 (3) Å	µ = 0.26 mm−1
c = 12.9864 (2) Å	T = 296 K
β = 94.668 (1)°	Plate, colorless
V = 1435.06 (4) Å3	0.40 × 0.30 × 0.04 mm
Z = 2

Bruker SMART APEX CCD area-detector diffractometer	6379 independent reflections
Radiation source: fine focus sealed Siemens Mo tube	5671 reflections with I > 2σ(I)
graphite	Rint = 0.023
0.3° wide ω exposures scans	θmax = 27.5°, θmin = 1.6°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −7→7
Tmin = 0.894, Tmax = 0.990	k = −24→24
16262 measured reflections	l = −16→16

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.040	H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.106	w = 1/[σ2(Fo2) + (0.0586P)2 + 0.1606P] where P = (Fo2 + 2Fc2)/3
S = 1.09	(Δ/σ)max < 0.001
6379 reflections	Δρmax = 0.33 e Å−3
433 parameters	Δρmin = −0.17 e Å−3
1 restraint	Absolute structure: Flack (1983), 3009 Friedel pairs
Primary atom site location: structure-invariant direct methods	Flack parameter: 0.05 (6)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.9685 (4)	0.25024 (11)	0.7833 (2)	0.0379 (5)
C2	1.1742 (5)	0.28453 (14)	0.8000 (2)	0.0466 (6)
H2	1.2839	0.2684	0.8502	0.056*
C3	1.2157 (5)	0.34335 (14)	0.7412 (3)	0.0490 (7)
H3	1.3549	0.3667	0.7521	0.059*
C4	1.0543 (5)	0.36826 (13)	0.6662 (2)	0.0430 (6)
C5	0.8515 (5)	0.33235 (15)	0.6504 (2)	0.0491 (7)
H5	0.7427	0.3477	0.5993	0.059*
C6	0.8060 (5)	0.27345 (14)	0.7097 (2)	0.0477 (6)
H6	0.6667	0.2501	0.6993	0.057*
C7	1.0939 (6)	0.43468 (15)	0.6053 (2)	0.0537 (7)
H7A	1.0142	0.4309	0.5371	0.064*
H7B	1.2556	0.4397	0.5969	0.064*
C8	1.0094 (5)	0.49994 (13)	0.6599 (2)	0.0419 (6)
C9	1.1433 (5)	0.53092 (14)	0.7404 (2)	0.0464 (6)
H9	1.2875	0.5125	0.7594	0.056*
C10	1.0668 (5)	0.58854 (14)	0.7929 (2)	0.0451 (6)
H10	1.1597	0.6096	0.8456	0.054*
C11	0.8526 (4)	0.61432 (12)	0.7664 (2)	0.0398 (5)
C12	0.7149 (4)	0.58484 (15)	0.6869 (2)	0.0442 (6)
H12	0.5702	0.6031	0.6689	0.053*
C13	0.7954 (5)	0.52752 (15)	0.6342 (2)	0.0486 (6)
H13	0.7032	0.5073	0.5805	0.058*
N1	0.9214 (5)	0.18836 (12)	0.8458 (2)	0.0443 (5)
H1B	0.804 (6)	0.1679 (19)	0.824 (3)	0.053*
H1A	0.928 (5)	0.1973 (18)	0.914 (3)	0.053*
H1C	1.040 (6)	0.1513 (18)	0.845 (3)	0.053*
N2	0.7665 (5)	0.67217 (14)	0.8262 (2)	0.0515 (6)
H2A	0.861 (6)	0.703 (2)	0.841 (3)	0.062*
H2B	0.665 (6)	0.696 (2)	0.793 (3)	0.062*
H2C	0.692 (6)	0.6611 (19)	0.888 (3)	0.062*
C14	0.5812 (4)	0.96279 (12)	0.95964 (18)	0.0340 (5)
C15	0.4353 (4)	0.99410 (13)	1.02603 (19)	0.0365 (5)
C16	0.2674 (5)	0.95376 (14)	1.0667 (2)	0.0445 (6)
H16	0.1755	0.9739	1.1138	0.053*
C17	0.2356 (5)	0.88431 (13)	1.0379 (2)	0.0407 (6)
H17	0.1199	0.8579	1.0643	0.049*
C18	0.3759 (4)	0.85330 (11)	0.96958 (19)	0.0347 (5)
C19	0.5485 (4)	0.89143 (12)	0.93132 (19)	0.0351 (5)
H19	0.6439	0.8701	0.8867	0.042*
C20	0.7674 (4)	1.00540 (13)	0.91927 (19)	0.0379 (5)
O1	0.7991 (3)	1.06703 (9)	0.94503 (16)	0.0494 (5)
O2	0.8919 (4)	0.97200 (11)	0.85615 (17)	0.0505 (5)
H2D	0.967 (7)	1.001 (2)	0.831 (3)	0.076*
O3	0.4490 (4)	1.06391 (9)	1.05113 (16)	0.0493 (5)
H3A	0.565 (7)	1.079 (2)	1.021 (3)	0.074*
O4	0.0960 (4)	0.74792 (10)	0.94941 (17)	0.0548 (5)
O5	0.4898 (4)	0.72016 (10)	0.99028 (16)	0.0533 (5)
O6	0.3678 (3)	0.76210 (11)	0.82021 (14)	0.0492 (4)
S1	0.32980 (11)	0.76440 (3)	0.92902 (5)	0.03782 (15)
C21	0.0913 (5)	0.20452 (12)	0.48434 (19)	0.0384 (5)
C22	−0.1231 (5)	0.17470 (14)	0.4583 (2)	0.0420 (6)
C23	−0.1983 (4)	0.11873 (15)	0.5176 (2)	0.0440 (6)
H23	−0.3442	0.1004	0.5028	0.053*
C24	−0.0591 (4)	0.09056 (13)	0.5976 (2)	0.0400 (5)
H24	−0.1094	0.0527	0.6355	0.048*
C25	0.1583 (4)	0.11918 (13)	0.62162 (18)	0.0368 (5)
C26	0.2297 (4)	0.17632 (13)	0.56590 (19)	0.0373 (5)
H26	0.3726	0.1962	0.5833	0.045*
C27	0.1761 (5)	0.26283 (15)	0.4210 (2)	0.0466 (6)
O7	0.0906 (5)	0.27667 (13)	0.33542 (18)	0.0716 (7)
O8	0.3540 (4)	0.29627 (12)	0.46501 (18)	0.0578 (6)
H8A	0.407 (7)	0.328 (3)	0.424 (3)	0.087*
O9	−0.2667 (4)	0.19688 (13)	0.37804 (16)	0.0554 (5)
H9A	−0.206 (7)	0.231 (2)	0.348 (3)	0.083*
O10	0.4348 (4)	0.01754 (12)	0.6798 (2)	0.0732 (7)
O11	0.2003 (3)	0.06836 (11)	0.80492 (16)	0.0520 (5)
O12	0.5149 (4)	0.13324 (13)	0.74758 (17)	0.0589 (5)
S2	0.34239 (10)	0.08090 (3)	0.72033 (5)	0.03813 (15)
O13	0.4004 (7)	0.87302 (16)	0.6497 (3)	0.0986 (11)
H13A	0.404 (11)	0.917 (4)	0.657 (5)	0.148*
H13B	0.314 (12)	0.857 (4)	0.698 (5)	0.148*

	U11	U22	U33	U12	U13	U23
C1	0.0465 (14)	0.0255 (11)	0.0430 (13)	0.0029 (9)	0.0114 (11)	0.0018 (9)
C2	0.0433 (15)	0.0386 (13)	0.0572 (17)	0.0012 (11)	−0.0001 (12)	−0.0006 (12)
C3	0.0386 (14)	0.0371 (13)	0.072 (2)	−0.0061 (11)	0.0098 (13)	0.0020 (13)
C4	0.0540 (16)	0.0288 (11)	0.0487 (15)	0.0009 (11)	0.0189 (13)	−0.0001 (10)
C5	0.0567 (17)	0.0378 (13)	0.0515 (17)	−0.0028 (12)	−0.0034 (13)	0.0017 (12)
C6	0.0461 (15)	0.0360 (13)	0.0604 (17)	−0.0075 (11)	0.0012 (12)	−0.0022 (12)
C7	0.074 (2)	0.0380 (14)	0.0532 (17)	−0.0042 (13)	0.0280 (16)	0.0007 (12)
C8	0.0533 (16)	0.0303 (11)	0.0443 (14)	−0.0045 (11)	0.0166 (12)	0.0069 (10)
C9	0.0385 (14)	0.0394 (14)	0.0615 (17)	0.0006 (11)	0.0053 (12)	0.0073 (12)
C10	0.0426 (13)	0.0405 (13)	0.0516 (15)	−0.0040 (11)	−0.0003 (11)	−0.0008 (12)
C11	0.0439 (14)	0.0317 (11)	0.0450 (14)	−0.0026 (10)	0.0110 (11)	0.0057 (10)
C12	0.0395 (13)	0.0438 (13)	0.0489 (15)	−0.0009 (12)	0.0006 (11)	0.0020 (13)
C13	0.0526 (16)	0.0453 (14)	0.0476 (16)	−0.0092 (12)	0.0011 (12)	−0.0004 (12)
N1	0.0522 (14)	0.0327 (11)	0.0493 (14)	−0.0007 (10)	0.0109 (11)	0.0053 (10)
N2	0.0526 (16)	0.0430 (13)	0.0598 (17)	−0.0009 (11)	0.0102 (13)	−0.0071 (11)
C14	0.0373 (12)	0.0294 (10)	0.0354 (12)	−0.0008 (9)	0.0033 (10)	0.0028 (9)
C15	0.0399 (13)	0.0297 (10)	0.0399 (13)	−0.0018 (9)	0.0024 (10)	−0.0014 (10)
C16	0.0502 (15)	0.0355 (12)	0.0506 (16)	0.0006 (11)	0.0204 (12)	−0.0063 (11)
C17	0.0437 (14)	0.0350 (12)	0.0452 (14)	−0.0063 (10)	0.0155 (11)	−0.0015 (11)
C18	0.0416 (14)	0.0255 (10)	0.0373 (13)	−0.0028 (9)	0.0050 (10)	−0.0019 (9)
C19	0.0395 (13)	0.0295 (10)	0.0369 (13)	−0.0001 (9)	0.0076 (10)	−0.0003 (9)
C20	0.0408 (13)	0.0352 (12)	0.0378 (13)	−0.0018 (10)	0.0042 (10)	0.0072 (10)
O1	0.0584 (11)	0.0307 (9)	0.0610 (12)	−0.0109 (8)	0.0165 (9)	0.0016 (8)
O2	0.0503 (12)	0.0434 (10)	0.0609 (12)	−0.0058 (8)	0.0237 (9)	0.0028 (9)
O3	0.0632 (12)	0.0300 (9)	0.0572 (12)	−0.0089 (8)	0.0202 (10)	−0.0088 (8)
O4	0.0591 (12)	0.0426 (11)	0.0648 (13)	−0.0178 (9)	0.0169 (10)	−0.0127 (9)
O5	0.0722 (14)	0.0328 (9)	0.0542 (12)	0.0043 (9)	0.0013 (10)	0.0003 (8)
O6	0.0616 (12)	0.0444 (9)	0.0418 (10)	−0.0044 (9)	0.0053 (8)	−0.0081 (9)
S1	0.0465 (3)	0.0268 (2)	0.0410 (3)	−0.0056 (2)	0.0090 (2)	−0.0048 (2)
C21	0.0487 (14)	0.0309 (11)	0.0366 (12)	0.0026 (10)	0.0093 (11)	−0.0031 (10)
C22	0.0445 (14)	0.0435 (13)	0.0382 (13)	0.0094 (11)	0.0041 (11)	−0.0046 (11)
C23	0.0355 (13)	0.0548 (15)	0.0425 (14)	−0.0062 (11)	0.0078 (11)	−0.0064 (12)
C24	0.0403 (13)	0.0396 (12)	0.0415 (13)	−0.0027 (11)	0.0108 (10)	0.0017 (11)
C25	0.0403 (13)	0.0353 (12)	0.0352 (13)	0.0007 (10)	0.0063 (10)	−0.0040 (10)
C26	0.0375 (12)	0.0355 (11)	0.0398 (13)	−0.0009 (10)	0.0077 (10)	−0.0025 (10)
C27	0.0587 (16)	0.0359 (12)	0.0461 (15)	0.0022 (13)	0.0098 (12)	0.0003 (13)
O7	0.0983 (19)	0.0600 (15)	0.0541 (14)	−0.0140 (12)	−0.0090 (13)	0.0217 (11)
O8	0.0705 (14)	0.0522 (12)	0.0510 (13)	−0.0155 (10)	0.0072 (11)	0.0091 (10)
O9	0.0532 (12)	0.0598 (13)	0.0519 (12)	0.0058 (10)	−0.0041 (9)	0.0067 (10)
O10	0.0848 (17)	0.0520 (12)	0.0842 (17)	0.0241 (12)	0.0150 (14)	0.0013 (12)
O11	0.0452 (10)	0.0580 (12)	0.0537 (11)	−0.0025 (9)	0.0091 (8)	0.0180 (9)
O12	0.0511 (12)	0.0624 (13)	0.0609 (13)	−0.0159 (10)	−0.0087 (10)	0.0176 (10)
S2	0.0342 (3)	0.0355 (3)	0.0456 (3)	0.0013 (2)	0.0084 (2)	0.0066 (3)
O13	0.136 (3)	0.0565 (15)	0.112 (3)	0.0003 (17)	0.058 (2)	−0.0240 (16)

C1—C6	1.368 (4)	C16—C17	1.371 (3)
C1—C2	1.373 (4)	C16—H16	0.9300
C1—N1	1.461 (3)	C17—C18	1.389 (3)
C2—C3	1.381 (4)	C17—H17	0.9300
C2—H2	0.9300	C18—C19	1.370 (3)
C3—C4	1.384 (4)	C18—S1	1.772 (2)
C3—H3	0.9300	C19—H19	0.9300
C4—C5	1.372 (4)	C20—O1	1.220 (3)
C4—C7	1.510 (4)	C20—O2	1.305 (3)
C5—C6	1.390 (4)	O2—H2D	0.80 (4)
C5—H5	0.9300	O3—H3A	0.86 (4)
C6—H6	0.9300	O4—S1	1.454 (2)
C7—C8	1.524 (4)	O5—S1	1.446 (2)
C7—H7A	0.9700	O6—S1	1.4490 (19)
C7—H7B	0.9700	O6—O13	3.064 (4)
C8—C13	1.377 (4)	C21—C26	1.388 (4)
C8—C9	1.386 (4)	C21—C22	1.396 (4)
C9—C10	1.378 (4)	C21—C27	1.484 (4)
C9—H9	0.9300	C22—O9	1.353 (3)
C10—C11	1.367 (4)	C22—C23	1.400 (4)
C10—H10	0.9300	C23—C24	1.375 (4)
C11—C12	1.376 (4)	C23—H23	0.9300
C11—N2	1.454 (3)	C24—C25	1.399 (4)
C12—C13	1.384 (4)	C24—H24	0.9300
C12—H12	0.9300	C25—C26	1.382 (3)
C13—H13	0.9300	C25—S2	1.763 (3)
N1—H1B	0.82 (4)	C26—H26	0.9300
N1—H1A	0.90 (4)	C27—O7	1.211 (4)
N1—H1C	0.99 (4)	C27—O8	1.311 (4)
N2—H2A	0.82 (4)	O8—H8A	0.87 (5)
N2—H2B	0.84 (4)	O9—H9A	0.86 (5)
N2—H2C	0.97 (4)	O10—S2	1.431 (2)
C14—C15	1.396 (3)	O11—S2	1.4526 (19)
C14—C19	1.405 (3)	O12—S2	1.439 (2)
C14—C20	1.487 (3)	O13—H13A	0.83 (8)
C15—O3	1.357 (3)	O13—H13B	0.89 (7)
C15—C16	1.384 (4)
C6—C1—C2	121.0 (2)	C16—C15—C14	119.7 (2)
C6—C1—N1	119.4 (2)	C17—C16—C15	120.5 (2)
C2—C1—N1	119.5 (2)	C17—C16—H16	119.8
C1—C2—C3	119.0 (3)	C15—C16—H16	119.8
C1—C2—H2	120.5	C16—C17—C18	120.1 (2)
C3—C2—H2	120.5	C16—C17—H17	119.9
C2—C3—C4	121.4 (3)	C18—C17—H17	119.9
C2—C3—H3	119.3	C19—C18—C17	120.4 (2)
C4—C3—H3	119.3	C19—C18—S1	119.29 (18)
C5—C4—C3	118.3 (2)	C17—C18—S1	120.28 (18)
C5—C4—C7	120.0 (3)	C18—C19—C14	119.9 (2)
C3—C4—C7	121.6 (3)	C18—C19—H19	120.1
C4—C5—C6	121.1 (3)	C14—C19—H19	120.1
C4—C5—H5	119.5	O1—C20—O2	123.5 (2)
C6—C5—H5	119.5	O1—C20—C14	121.3 (2)
C1—C6—C5	119.2 (3)	O2—C20—C14	115.3 (2)
C1—C6—H6	120.4	C20—O2—H2D	106 (3)
C5—C6—H6	120.4	C15—O3—H3A	104 (3)
C4—C7—C8	110.9 (2)	S1—O6—H2B	111.3 (10)
C4—C7—H7A	109.5	S1—O6—O13	135.06 (12)
C8—C7—H7A	109.5	H2B—O6—O13	99.8 (10)
C4—C7—H7B	109.5	O5—S1—O6	111.97 (12)
C8—C7—H7B	109.5	O5—S1—O4	110.99 (13)
H7A—C7—H7B	108.1	O6—S1—O4	113.21 (12)
C13—C8—C9	118.4 (2)	O5—S1—C18	107.80 (12)
C13—C8—C7	121.2 (3)	O6—S1—C18	106.63 (12)
C9—C8—C7	120.4 (3)	O4—S1—C18	105.80 (11)
C10—C9—C8	121.2 (3)	C26—C21—C22	119.5 (2)
C10—C9—H9	119.4	C26—C21—C27	120.3 (2)
C8—C9—H9	119.4	C22—C21—C27	120.1 (2)
C11—C10—C9	119.2 (3)	O9—C22—C21	123.8 (2)
C11—C10—H10	120.4	O9—C22—C23	116.9 (2)
C9—C10—H10	120.4	C21—C22—C23	119.3 (2)
C10—C11—C12	121.2 (2)	C24—C23—C22	120.8 (2)
C10—C11—N2	119.1 (3)	C24—C23—H23	119.6
C12—C11—N2	119.7 (2)	C22—C23—H23	119.6
C11—C12—C13	118.9 (2)	C23—C24—C25	119.7 (2)
C11—C12—H12	120.6	C23—C24—H24	120.1
C13—C12—H12	120.6	C25—C24—H24	120.1
C8—C13—C12	121.2 (3)	C26—C25—C24	119.7 (2)
C8—C13—H13	119.4	C26—C25—S2	120.4 (2)
C12—C13—H13	119.4	C24—C25—S2	119.95 (19)
C1—N1—H1B	112 (2)	C25—C26—C21	120.9 (2)
C1—N1—H1A	114 (2)	C25—C26—H26	119.5
H1B—N1—H1A	114 (3)	C21—C26—H26	119.5
C1—N1—H1C	113.3 (19)	O7—C27—O8	123.6 (3)
H1B—N1—H1C	103 (3)	O7—C27—C21	122.4 (3)
H1A—N1—H1C	100 (3)	O8—C27—C21	114.0 (2)
C11—N2—H2A	114 (3)	C27—O8—H8A	112 (3)
C11—N2—H2B	113 (2)	C22—O9—H9A	109 (3)
H2A—N2—H2B	100 (4)	O10—S2—O12	112.51 (15)
C11—N2—H2C	119 (2)	O10—S2—O11	113.65 (14)
H2A—N2—H2C	107 (3)	O12—S2—O11	111.27 (13)
H2B—N2—H2C	102 (3)	O10—S2—C25	107.66 (14)
C15—C14—C19	119.3 (2)	O12—S2—C25	106.02 (12)
C15—C14—C20	119.7 (2)	O11—S2—C25	105.07 (11)
C19—C14—C20	121.0 (2)	O6—O13—H13A	127 (5)
O3—C15—C16	118.2 (2)	H13A—O13—H13B	106 (6)
O3—C15—C14	122.1 (2)
C6—C1—C2—C3	0.1 (4)	C19—C14—C20—O1	−178.7 (3)
N1—C1—C2—C3	−179.4 (3)	C15—C14—C20—O2	−178.7 (2)
C1—C2—C3—C4	0.1 (4)	C19—C14—C20—O2	0.8 (4)
C2—C3—C4—C5	−0.9 (4)	H2B—O6—S1—O5	−2.9 (10)
C2—C3—C4—C7	176.9 (3)	O13—O6—S1—O5	−133.47 (18)
C3—C4—C5—C6	1.5 (4)	H2B—O6—S1—O4	−129.3 (10)
C7—C4—C5—C6	−176.3 (3)	O13—O6—S1—O4	100.15 (19)
C2—C1—C6—C5	0.5 (4)	H2B—O6—S1—C18	114.8 (10)
N1—C1—C6—C5	180.0 (3)	O13—O6—S1—C18	−15.8 (2)
C4—C5—C6—C1	−1.4 (4)	C19—C18—S1—O5	82.1 (2)
C5—C4—C7—C8	88.5 (3)	C17—C18—S1—O5	−99.1 (2)
C3—C4—C7—C8	−89.3 (3)	C19—C18—S1—O6	−38.3 (2)
C4—C7—C8—C13	−95.7 (3)	C17—C18—S1—O6	140.5 (2)
C4—C7—C8—C9	81.2 (3)	C19—C18—S1—O4	−159.1 (2)
C13—C8—C9—C10	−0.9 (4)	C17—C18—S1—O4	19.7 (3)
C7—C8—C9—C10	−177.9 (2)	C26—C21—C22—O9	−177.7 (2)
C8—C9—C10—C11	1.6 (4)	C27—C21—C22—O9	−1.6 (4)
C9—C10—C11—C12	−1.6 (4)	C26—C21—C22—C23	2.6 (4)
C9—C10—C11—N2	176.1 (2)	C27—C21—C22—C23	178.7 (2)
C10—C11—C12—C13	0.8 (4)	O9—C22—C23—C24	176.9 (2)
N2—C11—C12—C13	−176.8 (3)	C21—C22—C23—C24	−3.4 (4)
C9—C8—C13—C12	0.1 (4)	C22—C23—C24—C25	1.5 (4)
C7—C8—C13—C12	177.1 (2)	C23—C24—C25—C26	1.1 (4)
C11—C12—C13—C8	−0.1 (4)	C23—C24—C25—S2	−177.24 (19)
C19—C14—C15—O3	−175.8 (2)	C24—C25—C26—C21	−1.9 (4)
C20—C14—C15—O3	3.7 (4)	S2—C25—C26—C21	176.48 (18)
C19—C14—C15—C16	2.9 (4)	C22—C21—C26—C25	0.0 (4)
C20—C14—C15—C16	−177.6 (2)	C27—C21—C26—C25	−176.1 (2)
O3—C15—C16—C17	175.3 (3)	C26—C21—C27—O7	160.4 (3)
C14—C15—C16—C17	−3.5 (4)	C22—C21—C27—O7	−15.6 (4)
C15—C16—C17—C18	1.6 (4)	C26—C21—C27—O8	−17.9 (3)
C16—C17—C18—C19	0.8 (4)	C22—C21—C27—O8	166.1 (2)
C16—C17—C18—S1	−178.0 (2)	C26—C25—S2—O10	−101.6 (2)
C17—C18—C19—C14	−1.3 (4)	C24—C25—S2—O10	76.8 (2)
S1—C18—C19—C14	177.48 (19)	C26—C25—S2—O12	19.1 (2)
C15—C14—C19—C18	−0.5 (4)	C24—C25—S2—O12	−162.6 (2)
C20—C14—C19—C18	180.0 (2)	C26—C25—S2—O11	137.0 (2)
C15—C14—C20—O1	1.8 (4)	C24—C25—S2—O11	−44.7 (2)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1A···O4i	0.90 (4)	2.03 (4)	2.896 (4)	161 (3)
N1—H1B···O1ii	0.82 (4)	2.47 (3)	2.751 (3)	101 (3)
N1—H1B···O12	0.82 (4)	2.01 (4)	2.814 (4)	168 (3)
N1—H1C···O11iii	0.99 (4)	1.92 (4)	2.870 (3)	161 (3)
N2—H2A···O4iii	0.82 (4)	2.07 (4)	2.801 (4)	149 (3)
N2—H2C···O5	0.97 (4)	2.16 (4)	2.927 (4)	135 (3)
N2—H2B···O6	0.84 (4)	2.20 (4)	2.889 (4)	139 (3)
N2—H2C···O3i	0.97 (4)	2.19 (4)	2.940 (3)	134 (3)
O2—H2D···O11iv	0.80 (4)	1.91 (4)	2.688 (3)	164 (4)
O3—H3A···O1	0.86 (4)	1.77 (4)	2.569 (3)	153 (4)
O8—H8A···O13v	0.87 (5)	1.76 (5)	2.598 (4)	160 (4)
O9—H9A···O7	0.86 (5)	1.96 (4)	2.678 (3)	141 (4)
O9—H9A···O6vi	0.86 (5)	2.38 (4)	2.872 (3)	117 (3)
O13—H13A···O10vii	0.83 (8)	1.93 (8)	2.759 (4)	176 (7)
O13—H13B···O6	0.89 (7)	2.39 (7)	3.064 (4)	132 (6)
C2—H2···O5viii	0.93	2.54	3.452 (4)	168.
C6—H6···O12	0.93	2.48	3.210 (3)	136.
C12—H12···O9ix	0.93	2.55	3.428 (4)	158.
C16—H16···Cgx	0.93	2.85	3.727 (3)	157

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1—H1A⋯O4i	0.90 (4)	2.03 (4)	2.896 (4)	161 (3)
N1—H1B⋯O1ii	0.82 (4)	2.47 (3)	2.751 (3)	101 (3)
N1—H1B⋯O12	0.82 (4)	2.01 (4)	2.814 (4)	168 (3)
N1—H1C⋯O11iii	0.99 (4)	1.92 (4)	2.870 (3)	161 (3)
N2—H2A⋯O4iii	0.82 (4)	2.07 (4)	2.801 (4)	149 (3)
N2—H2C⋯O5	0.97 (4)	2.16 (4)	2.927 (4)	135 (3)
N2—H2B⋯O6	0.84 (4)	2.20 (4)	2.889 (4)	139 (3)
N2—H2C⋯O3i	0.97 (4)	2.19 (4)	2.940 (3)	134 (3)
O2—H2D⋯O11iv	0.80 (4)	1.91 (4)	2.688 (3)	164 (4)
O3—H3A⋯O1	0.86 (4)	1.77 (4)	2.569 (3)	153 (4)
O8—H8A⋯O13v	0.87 (5)	1.76 (5)	2.598 (4)	160 (4)
O9—H9A⋯O7	0.86 (5)	1.96 (4)	2.678 (3)	141 (4)
O9—H9A⋯O6vi	0.86 (5)	2.38 (4)	2.872 (3)	117 (3)
O13—H13A⋯O10vii	0.83 (8)	1.93 (8)	2.759 (4)	176 (7)
O13—H13B⋯O6	0.89 (7)	2.39 (7)	3.064 (4)	132 (6)
C2—H2⋯O5viii	0.93	2.54	3.452 (4)	168
C6—H6⋯O12	0.93	2.48	3.210 (3)	136
C12—H12⋯O9ix	0.93	2.55	3.428 (4)	158
C16—H16⋯Cgx	0.93	2.85	3.727 (3)	157

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) ; (vi) ; (vii) ; (viii) ; (ix) ; (x) . Cg is the centroid of the C8–C13 ring.