| Literature DB >> 21174431 |
Baishu Zheng1, Junfeng Bai, Jingui Duan, Lukasz Wojtas, Michael J Zaworotko.
Abstract
An rht-type metal-organic framework (MOF) prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(2)/N(2) in comparison with what was previously observed for an analogous MOF with alkyne groups.Entities:
Year: 2010 PMID: 21174431 DOI: 10.1021/ja110042b
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419