| Literature DB >> 21174417 |
Sergiy Levin1, Roger R Nani, Sarah E Reisman.
Abstract
An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.Entities:
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Year: 2011 PMID： 21174417 DOI： 10.1021/ja110192b
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419