Literature DB >> 21128649

Siloxane-triarylamine hybrids: discrete room temperature liquid triarylamines via the Piers-Rubinsztajn reaction.

Brett A Kamino1, John B Grande, Michael A Brook, Timothy P Bender.   

Abstract

A series of room temperature liquid siloxane-triarylamine hybrids were synthesized using the Piers-Rubinsztajn reaction. These materials displayed well behaved electrochemical oxidation and low T(g)'s and were free-flowing liquids. The interaction between the Lewis acidic tris(pentafluorophenyl)borane catalyst and the Lewis basic starting triarylamine substrate was also investigated by steady state UV-vis spectroscopy and (19)F NMR.

Entities:  

Year:  2010        PMID： 21128649     DOI： 10.1021/ol102607v

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.

Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Compatibilization of porphyrins for use as high permittivity fillers in low voltage actuating silicone dielectric elastomers.

Authors:  Cody B Gale; Michael A Brook; Anne Ladegaard Skov
Journal:  RSC Adv       Date:  2020-05-14       Impact factor: 3.361

Review 3.  Defunctionalisation catalysed by boron Lewis acids.

Authors:  Huaquan Fang; Martin Oestreich
Journal:  Chem Sci       Date:  2020-07-28       Impact factor: 9.825

4.  Remarkable Enhancement of the Hole Mobility in Several Organic Small-Molecules, Polymers, and Small-Molecule:Polymer Blend Transistors by Simple Admixing of the Lewis Acid p-Dopant B(C6F5)3.

Authors:  Julianna Panidi; Alexandra F Paterson; Dongyoon Khim; Zhuping Fei; Yang Han; Leonidas Tsetseris; George Vourlias; Panos A Patsalas; Martin Heeney; Thomas D Anthopoulos
Journal:  Adv Sci (Weinh)       Date:  2017-10-05       Impact factor: 16.806

5.  Supercooling of functional alkyl-π molecular liquids.

Authors:  Fengniu Lu; Keumhee Jang; Izabela Osica; Keita Hagiwara; Michito Yoshizawa; Masashi Ishii; Yoshiaki Chino; Kazuchika Ohta; Kinga Ludwichowska; Krzysztof Jan Kurzydłowski; Shinsuke Ishihara; Takashi Nakanishi
Journal:  Chem Sci       Date:  2018-07-17       Impact factor: 9.825
  5 in total

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