Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Studies in catalytic C-H amination involving nitrene C-H insertion.

Literature DB >> 20931128

Studies in catalytic C-H amination involving nitrene C-H insertion.

Florence Collet¹, Camille Lescot, Chungen Liang, Philippe Dauban.

Abstract

Stereoselective catalytic intermolecular C-H amination of complex molecules is reported. Site-selective functionalizations occur with very good yields up to 91% and excellent d.e.s up to 99%. However, the precise nature of the nitrene C-H insertion remains a matter of debate despite several physical organic experiments.

Entities: Chemical

Mesh：

Substances：

Year: 2010 PMID： 20931128 DOI： 10.1039/c0dt00283f

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

Keyword Cloud
Cited

22 in total

1. Selective intermolecular amination of C-H bonds at tertiary carbon centers.

Authors: Jennifer L Roizen; David N Zalatan; J Du Bois
Journal: Angew Chem Int Ed Engl Date: 2013-09-02 Impact factor: 15.336

2. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

Authors: Minsoo Ju; Cale D Weatherly; Ilia A Guzei; Jennifer M Schomaker
Journal: Angew Chem Int Ed Engl Date: 2017-07-12 Impact factor: 15.336

3. Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

Authors: Jun Pan; Mingjuan Su; Stephen L Buchwald
Journal: Angew Chem Int Ed Engl Date: 2011-08-02 Impact factor: 15.336

4. Total synthesis of (-)-N-methylwelwitindolinone C isothiocyanate.

Authors: Alexander D Huters; Kyle W Quasdorf; Evan D Styduhar; Neil K Garg
Journal: J Am Chem Soc Date: 2011-08-11 Impact factor: 15.419

5. Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts.

Authors: Xin Hong; Daniel A Bercovici; Zhongyue Yang; Nezar Al-Bataineh; Ramya Srinivasan; Ram C Dhakal; K N Houk; Matthias Brewer
Journal: J Am Chem Soc Date: 2015-07-07 Impact factor: 15.419

6. Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

Authors: Stephen P Lathrop; Mohammad Movassaghi
Journal: Chem Sci Date: 2014-01-01 Impact factor: 9.825

Studies in catalytic C-H amination involving nitrene C-H insertion.

1. Selective intermolecular amination of C-H bonds at tertiary carbon centers.

2. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

3. Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

4. Total synthesis of (-)-N-methylwelwitindolinone C isothiocyanate.

5. Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts.

6. Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

7. Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis.

8. Sulfamate Esters Guide Selective Radical-Mediated Chlorination of Aliphatic C-H Bonds.

9. Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.

10. Total synthesis of oxidized welwitindolinones and (-)-N-methylwelwitindolinone C isonitrile.