Literature DB >> 20886589

Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.

Fang Gao1, Yunmi Lee, Kyoko Mandai, Amir H Hoveyda.   

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Year:  2010        PMID: 20886589      PMCID: PMC3498987          DOI: 10.1002/anie.201005124

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


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  30 in total

1.  Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Copper-Catalyzed Allylic Substitutions This research was supported by the National Institutes of Health (GM47480 and GM57212). Additional funds were provided by DuPont.

Authors:  Courtney A. Luchaco-Cullis; Hirotake Mizutani; Kerry E. Murphy; Amir H. Hoveyda
Journal:  Angew Chem Int Ed Engl       Date:  2001-04-17       Impact factor: 15.336

2.  Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: structure and activity of an air-stable chiral Cu complex.

Authors:  Andrew O Larsen; Wenhao Leu; Christina Nieto Oberhuber; John E Campbell; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2004-09-15       Impact factor: 15.419

3.  New general sulfinylating process for asymmetric synthesis of enantiopure sulfinates and sulfoxides.

Authors:  Bruce Z Lu; Fuqiang Jin; Yongda Zhang; Xinhe Wu; Stephen A Wald; Chris H Senanayake
Journal:  Org Lett       Date:  2005-04-14       Impact factor: 6.005

4.  Recent progress in asymmetric allylic substitutions catalyzed by chiral copper complexes.

Authors:  Hideki Yorimitsu; Koichiro Oshima
Journal:  Angew Chem Int Ed Engl       Date:  2005-07-18       Impact factor: 15.336

5.  All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene.

Authors:  M Kevin Brown; Tricia L May; Carl A Baxter; Amir H Hoveyda
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

6.  Efficient chiral N-heterocyclic carbene/copper(I)-catalyzed asymmetric allylic arylation with aryl Grignard reagents.

Authors:  Khalid B Selim; Yasumasa Matsumoto; Ken-ichi Yamada; Kiyoshi Tomioka
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

7.  Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters.

Authors:  Jeannette M O'Brien; Kang-sang Lee; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2010-08-11       Impact factor: 15.419

8.  Copper-catalyzed asymmetric allylic substitution with aryl and ethyl Grignard reagents.

Authors:  Khalid B Selim; Ken-ichi Yamada; Kiyoshi Tomioka
Journal:  Chem Commun (Camb)       Date:  2008-09-09       Impact factor: 6.222

9.  Enantioselective synthesis of allylsilanes bearing tertiary and quaternary Si-substituted carbons through Cu-catalyzed allylic alkylations with alkylzinc and arylzinc reagents.

Authors:  Monica A Kacprzynski; Tricia L May; Stephanie A Kazane; Amir H Hoveyda
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

10.  Enantioselective synthesis of alpha-alkyl-beta,gamma-unsaturated esters through efficient cu-catalyzed allylic alkylations.

Authors:  Kerry E Murphy; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2003-04-23       Impact factor: 15.419

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  20 in total

Review 1.  Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds.

Authors:  Alan H Cherney; Nathaniel T Kadunce; Sarah E Reisman
Journal:  Chem Rev       Date:  2015-08-13       Impact factor: 60.622

2.  Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.

Authors:  Byunghyuck Jung; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2012-01-03       Impact factor: 15.419

3.  Acyclic Quaternary Carbon Stereocenters via Enantioselective Transition Metal Catalysis.

Authors:  Jiajie Feng; Michael Holmes; Michael J Krische
Journal:  Chem Rev       Date:  2017-09-14       Impact factor: 60.622

4.  Stereospecific, Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of Allylic Pivalates To Deliver Quaternary Stereocenters.

Authors:  Kelsey M Cobb; Javon M Rabb-Lynch; Megan E Hoerrner; Alex Manders; Qi Zhou; Mary P Watson
Journal:  Org Lett       Date:  2017-08-07       Impact factor: 6.005

5.  Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.

Authors:  Ping Zhang; Hai Le; Robert E Kyne; James P Morken
Journal:  J Am Chem Soc       Date:  2011-06-07       Impact factor: 15.419

6.  Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents.

Authors:  Fang Gao; Kevin P McGrath; Yunmi Lee; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2010-10-13       Impact factor: 15.419

7.  Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers.

Authors:  Harshkumar H Patel; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2016-10-25       Impact factor: 15.419

8.  Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.

Authors:  Fang Gao; James L Carr; Amir H Hoveyda
Journal:  Angew Chem Int Ed Engl       Date:  2012-05-25       Impact factor: 15.336

9.  Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents.

Authors:  Jennifer A Dabrowski; Fang Gao; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2011-03-08       Impact factor: 15.419

10.  Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation.

Authors:  Samantha E Shockley; J Caleb Hethcox; Brian M Stoltz
Journal:  Angew Chem Int Ed Engl       Date:  2017-08-09       Impact factor: 15.336

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