Literature DB >> 18956048

Copper-catalyzed asymmetric allylic substitution with aryl and ethyl Grignard reagents.

Khalid B Selim1, Ken-ichi Yamada, Kiyoshi Tomioka.   

Abstract

Phenyl- and ethyl-magnesium bromides undergo regioselective asymmetric allylic substitution with high enantioselectivity under the catalysis of chiral amidophosphane-copper(I) complexes.

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Year:  2008        PMID： 18956048     DOI： 10.1039/b809140d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

Review 1.  Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C-C Bonds.

Authors:  Alan H Cherney; Nathaniel T Kadunce; Sarah E Reisman
Journal:  Chem Rev       Date:  2015-08-13       Impact factor: 60.622

2.  Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution.

Authors:  Byunghyuck Jung; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2012-01-03       Impact factor: 15.419

3.  Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents.

Authors:  Fang Gao; James L Carr; Amir H Hoveyda
Journal:  Angew Chem Int Ed Engl       Date:  2012-05-25       Impact factor: 15.336

4.  Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides.

Authors:  Fang Gao; Yunmi Lee; Kyoko Mandai; Amir H Hoveyda
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-02       Impact factor: 15.336

5.  Enantiospecific, nickel-catalyzed cross-couplings of allylic pivalates and arylboroxines.

Authors:  Harathi D Srinivas; Qi Zhou; Mary P Watson
Journal:  Org Lett       Date:  2014-06-13       Impact factor: 6.005

6.  Nickel-catalyzed asymmetric reductive cross-coupling between vinyl and benzyl electrophiles.

Authors:  Alan H Cherney; Sarah E Reisman
Journal:  J Am Chem Soc       Date:  2014-10-01       Impact factor: 15.419
  6 in total

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