Literature DB >> 20670021

Carbon dioxide as the C1 source for direct C-H functionalization of aromatic heterocycles.

Oleg Vechorkin1, Nathalie Hirt, Xile Hu.   

Abstract

A simple and straightforward method has been developed for the direct carboxylation of aromatic heterocycles such as oxazoles, thiazoles, and oxadiazoles using CO(2) as the C1 source. The reactions require no metal catalyst and only Cs(2)CO(3) as the base. A good functional group tolerance is achieved.

Entities:  

Year:  2010        PMID： 20670021     DOI： 10.1021/ol101450u

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  10 in total

1.  Copper- and copper-N-heterocyclic carbene-catalyzed C-H activating carboxylation of terminal alkynes with CO2 at ambient conditions.

Authors:  Dingyi Yu; Yugen Zhang
Journal:  Proc Natl Acad Sci U S A       Date:  2010-11-08       Impact factor: 11.205

2.  Carbon dioxide utilization via carbonate-promoted C-H carboxylation.

Authors:  Aanindeeta Banerjee; Graham R Dick; Tatsuhiko Yoshino; Matthew W Kanan
Journal:  Nature       Date:  2016-03-10       Impact factor: 49.962

3.  Milled Dry Ice as a C1 Source for the Carboxylation of Aryl Halides.

Authors:  Connor J O'Brien; David A Nicewicz
Journal:  Synlett       Date:  2021-02-04       Impact factor: 2.170

4.  Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide.

Authors:  Hung Tran-Vu; Olafs Daugulis
Journal:  ACS Catal       Date:  2013-10-04       Impact factor: 13.084

5.  The role of silver additives in gold-mediated C-H functionalisation.

Authors:  Scott R Patrick; Ine I F Boogaerts; Sylvain Gaillard; Alexandra M Z Slawin; Steven P Nolan
Journal:  Beilstein J Org Chem       Date:  2011-07-01       Impact factor: 2.883

6.  Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2.

Authors:  Si-Shun Yan; Lei Zhu; Jian-Heng Ye; Zhen Zhang; He Huang; Huiying Zeng; Chao-Jun Li; Yu Lan; Da-Gang Yu
Journal:  Chem Sci       Date:  2018-04-30       Impact factor: 9.825

7.  Photocarboxylation of Benzylic C-H Bonds.

Authors:  Qing-Yuan Meng; Tobias E Schirmer; Anna Lucia Berger; Karsten Donabauer; Burkhard König
Journal:  J Am Chem Soc       Date:  2019-07-11       Impact factor: 15.419

8.  Carboxylation of sodium arylsulfinates with CO2 over mesoporous K-Cu-20TiO2.

Authors:  Yanjiao Chen; Xuan Dai; Wenwei Zhang; Tao Wu; Lei Chen; Xinhua Peng
Journal:  RSC Adv       Date:  2021-12-24       Impact factor: 3.361

9.  Synthesis, Anti-Proliferative Activity Evaluation and 3D-QSAR Study of Naphthoquinone Derivatives as Potential Anti-Colorectal Cancer Agents.

Authors:  Julio Acuña; Jhoan Piermattey; Daneiva Caro; Sven Bannwitz; Luis Barrios; Jairo López; Yanet Ocampo; Ricardo Vivas-Reyes; Fabio Aristizábal; Ricardo Gaitán; Klaus Müller; Luis Franco
Journal:  Molecules       Date:  2018-01-17       Impact factor: 4.411

Review 10.  C-H Carboxylation of Aromatic Compounds through CO2 Fixation.

Authors:  Junfei Luo; Igor Larrosa
Journal:  ChemSusChem       Date:  2017-08-16       Impact factor: 8.928
  10 in total

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