Literature DB >> 20668747

Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands.

Guofu Zi1, Furen Zhang, Haibin Song.   

Abstract

A highly enantioselective group 5 metal amide catalyst system is reported for the hydroaminoalkylation of secondary amines to give chiral amines in good yields with excellent ee values (up to 93%) by loading of 5% precatalyst.

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Year:  2010        PMID： 20668747     DOI： 10.1039/c0cc01265c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Ruthenium catalyzed hydroaminoalkylation of isoprene via transfer hydrogenation: byproduct-free prenylation of hydantoins.

Authors:  Daniel C Schmitt; Jungyong Lee; Anne-Marie R Dechert-Schmitt; Eiji Yamaguchi; Michael J Krische
Journal:  Chem Commun (Camb)       Date:  2013-07-11       Impact factor: 6.222

2.  Regio-, Diastereo-, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis.

Authors:  Jun Zheng; Nana Tang; Hui Xie; Bernhard Breit
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-16       Impact factor: 16.823

3.  Intermolecular Hydroaminoalkylation of Propadiene.

Authors:  Tobias Kaper; Malte Fischer; Michael Warsitz; René Zimmering; Ruediger Beckhaus; Sven Doye
Journal:  Chemistry       Date:  2020-10-01       Impact factor: 5.236
  3 in total

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