Literature DB >> 20640037

Mechanisms of Mn(OAc)(3)-based oxidative free-radical additions and cyclizations.

Barry B Snider1.   

Abstract

The mechanistic details of Mn(OAc)(3)-based oxidative free-radical additions and cyclizations are reviewed. The mechanisms of electron transfer to generate radicals, electron transfer to convert the radicals to oxidized products, and further oxidation of the products are covered.

Entities:  

Year:  2009        PMID： 20640037      PMCID： PMC2902773          DOI： 10.1016/j.tet.2009.09.025

Source DB:  PubMed          Journal:  Tetrahedron        ISSN： 0040-4020            Impact factor:   2.457


  9 in total

1.  Manganese(III)-Based Oxidative Free-Radical Cyclizations.

Authors:  Barry B. Snider
Journal:  Chem Rev       Date:  1996-02-01       Impact factor: 60.622

2.  Cerium(IV) ammonium nitrate--a versatile single-electron oxidant.

Authors:  Vijay Nair; Ani Deepthi
Journal:  Chem Rev       Date:  2007-04-14       Impact factor: 60.622

3.  Mn(III)-Based Oxidative Free-Radical Cyclizations of Unsaturated Ketones.

Authors:  Bridget McCarthy Cole; Luning Han; Barry B. Snider
Journal:  J Org Chem       Date:  1996-11-01       Impact factor: 4.354

4.  Solvent-dependent oxidative coupling of 1-aryl-1,3-dicarbonyls and styrene.

Authors:  Brian M Casey; Cynthia A Eakin; Jingliang Jiao; Dhandapani V Sadasivam; Robert A Flowers
Journal:  Tetrahedron       Date:  2009-12-26       Impact factor: 2.457

5.  Synthesis of (+/-)-Gymnomitrol. Mn(OAc)(3)-Initiated Free-Radical Cyclization of Alkynyl Ketones.

Authors:  Steven V. O'Neil; Cheri A. Quickley; Barry B. Snider
Journal:  J Org Chem       Date:  1997-04-04       Impact factor: 4.354

6.  Termination of Mn(III)-based oxidative cyclizations by trapping with azide.

Authors:  Barry B Snider; Jeremy R Duvall
Journal:  Org Lett       Date:  2004-04-15       Impact factor: 6.005

7.  Mechanistic investigation of substrate oxidation by Ce(IV) reagents in acetonitrile.

Authors:  Yang Zhang; Robert A Flowers
Journal:  J Org Chem       Date:  2003-05-30       Impact factor: 4.354

8.  Solvent-dependent chemoselectivities in Ce(IV)-mediated oxidative coupling reactions.

Authors:  Yang Zhang; Andrew J Raines; Robert A Flowers
Journal:  Org Lett       Date:  2003-06-26       Impact factor: 6.005

9.  Mechanistic studies of Ce(IV)-mediated oxidation of beta-dicarbonyls: solvent-dependent behavior of radical cation intermediates.

Authors:  Jingliang Jiao; Yang Zhang; James J Devery; Luna Xu; Jennifer Deng; Robert A Flowers
Journal:  J Org Chem       Date:  2007-06-28       Impact factor: 4.354
  9 in total
  3 in total

1.  Photoredox-Catalyzed Oxidation of Anions for the Atom-Economical Hydro-, Amido-, and Dialkylation of Alkenes.

Authors:  Katherine C Forbes; Anne Marie Crooke; Yuri Lee; Masamu Kawada; Kian M Shamskhou; Rachel A Zhang; Jeffrey S Cannon
Journal:  J Org Chem       Date:  2022-02-08       Impact factor: 4.354

2.  A biomimetic route for construction of the [4+2] and [3+2] core skeletons of dimeric pyrrole-imidazole alkaloids and asymmetric synthesis of ageliferins.

Authors:  Xiao Wang; Xiaolei Wang; Xianghui Tan; Jianming Lu; Kevin W Cormier; Zhiqiang Ma; Chuo Chen
Journal:  J Am Chem Soc       Date:  2012-11-02       Impact factor: 15.419

Review 3.  Treasures old and new: what we can learn regarding the macrocyclic problem from past and present efforts in natural product total synthesis.

Authors:  Maryam Sadat Alehashem; Azhar Bin Ariffin; Paul B Savage; Wageeh Abdulhadi Yehya Dabdawb; Noel Francis Thomas
Journal:  RSC Adv       Date:  2020-03-17       Impact factor: 4.036
  3 in total

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