| Literature DB >> 15070313 |
Barry B Snider1, Jeremy R Duvall.
Abstract
The radicals formed in Mn(III)-based oxidative free-radical cyclizations of beta-keto esters and malonate esters can be trapped with sodium azide and Mn(III) to give cyclic and bicyclic azides in 30-80% yield. Reduction of the azide gives bi- and tricyclic lactams. [reaction: see text]Entities:
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Year: 2004 PMID： 15070313 DOI： 10.1021/ol049805s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005