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Literature DB >> 20617351

Structural change from doping the gold cluster.

Abstract

Doping gold clusters with a transition metal (M@Au(n)) causes structural change. To determine the mechanism by which these changes occur, the central gold atom of Au(5) was doped with its same row transition metals Pt, Ir, Os, Re, and W. Based on theoretical calculations, a similar trend was found in other gold clusters.

Entities: Chemical

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Year: 2010 PMID： 20617351 DOI： 10.1007/s00894-010-0793-6

Source DB: PubMed Journal: J Mol Model ISSN： 0948-5023 Impact factor: 1.810

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References

11 in total

1. Theoretical studies on reactions of transition-metal complexes.

Authors: S Niu; M B Hall
Journal: Chem Rev Date: 2000-02-09 Impact factor: 60.622

2. Periodic properties of force constants of small transition-metal and lanthanide clusters.

Authors: John R Lombardi; Benjamin Davis
Journal: Chem Rev Date: 2002-06 Impact factor: 60.622

3. The impact of nanoscience on heterogeneous catalysis.

Authors: Alexis T Bell
Journal: Science Date: 2003-03-14 Impact factor: 47.728

4. Element- and size-dependent electron delocalization in AuNX+ clusters (X = Sc, Ti, V, Cr, Mn, Fe, Co, Ni).

Authors: S Neukermans; E Janssens; H Tanaka; R E Silverans; P Lievens
Journal: Phys Rev Lett Date: 2003-01-24 Impact factor: 9.161

5. Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation.

Authors:
Journal: Phys Rev B Condens Matter Date: 1992-09-15

6. Icosahedral WAu12: a predicted closed-shell species, stabilized by aurophilic attraction and relativity and in accord with the 18-electron rule.

Authors: Pekka Pyykkö; Nino Runeberg
Journal: Angew Chem Int Ed Engl Date: 2002-06-17 Impact factor: 15.336

Structural change from doping the gold cluster.

1. Theoretical studies on reactions of transition-metal complexes.

2. Periodic properties of force constants of small transition-metal and lanthanide clusters.

3. The impact of nanoscience on heterogeneous catalysis.

4. Element- and size-dependent electron delocalization in AuNX+ clusters (X = Sc, Ti, V, Cr, Mn, Fe, Co, Ni).

5. Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation.

6. Icosahedral WAu12: a predicted closed-shell species, stabilized by aurophilic attraction and relativity and in accord with the 18-electron rule.

7. Covalent radii revisited.

8. Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties

9. Binary clusters AuPt and Au6Pt: structure and reactivity within density functional theory.

10. Magnetic properties in transition-metal-doped gold clusters: M@Au6 (M = Ti, V, Cr).