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Literature DB >> 12570488

Element- and size-dependent electron delocalization in AuNX+ clusters (X = Sc, Ti, V, Cr, Mn, Fe, Co, Ni).

S Neukermans¹, E Janssens, H Tanaka, R E Silverans, P Lievens.

Abstract

We investigated the stability of gold clusters doped with open 3d-shell atoms (Sc, Ti, V, Cr, Mn, Fe, Co, Ni). Steps, peaks, and odd-even staggering in mass abundance spectra upon photofragmentation provide evidence for enhanced stability for specific cluster sizes. The observed magic numbers are explained in terms of size- and dopant-dependent modifications of the effective mean-field potential within a phenomenological shell-model approach. Element-dependent 3d electron delocalization and odd-even staggering amplitudes are related to the dopant-atom structure.

Entities: Chemical

Year: 2003 PMID： 12570488 DOI： 10.1103/PhysRevLett.90.033401

Source DB: PubMed Journal: Phys Rev Lett ISSN： 0031-9007 Impact factor: 9.161

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Cited

9 in total

1. Density functional study on size-dependent structures, stabilities, electronic and magnetic properties of Au(n)M (M = Al and Si, n = 1-9) clusters: comparison with pure gold clusters.

Authors: Yan-Fang Li; Ai-Jie Mao; Yang Li; Xiao-Yu Kuang
Journal: J Mol Model Date: 2011-12-14 Impact factor: 1.810

2. Structural change from doping the gold cluster.

Authors: Yiji Tang; Shu-Guang Wang; Jia Li
Journal: J Mol Model Date: 2010-07-09 Impact factor: 1.810

3. Cage structure formation of singly doped aluminum cluster cations Al(n)TM+ (TM = Ti, V, Cr).

Authors: Sandra M Lang; Pieterjan Claes; Sven Neukermans; Ewald Janssens
Journal: J Am Soc Mass Spectrom Date: 2011-06-25 Impact factor: 3.109

4. A DFT study on equilibrium geometries, stabilities, and electronic properties of small bimetallic Na-doped Au(n) (n = 1-9) clusters: comparison with pure gold clusters.

Authors: Yan-Fang Li; Xiao-Yu Kuang; Ai-Jie Mao; Yang Li; Ya-Ru Zhao
Journal: J Mol Model Date: 2011-04-27 Impact factor: 1.810

5. Structures and Stabilities of the Metal Doped Gold Nano-Clusters: M@Au₁₀ (M = W, Mo, Ru, Co).

Authors: Delwar Hossain; Charles U Pittman; Steven R Gwaltney
Journal: J Inorg Organomet Polym Mater Date: 2014-01-01 Impact factor: 3.543

6. Probing the structural and electronic properties of bimetallic chromium-gold clusters CrmAun(m+n≤6): comparison with pure chromium and gold clusters.

Authors: Peng Lu; Guang-Hua Liu; Xiao-Yu Kuang
Journal: J Mol Model Date: 2014-08-01 Impact factor: 1.810