Literature DB >> 20597488

Palladium catalysts for dehydrogenation of ammonia borane with preferential B-H activation.

Sung-Kwan Kim1, Won-Sik Han, Tae-Jin Kim, Tae-Young Kim, Suk Woo Nam, Mariusz Mitoraj, Łukasz Piekoś, Artur Michalak, Son-Jong Hwang, Sang Ook Kang.   

Abstract

Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H(2) in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.

Entities:  

Year:  2010        PMID： 20597488     DOI： 10.1021/ja101685u

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Theoretical description of halogen bonding - an insight based on the natural orbitals for chemical valence combined with the extended-transition-state method (ETS-NOCV).

Authors:  Mariusz P Mitoraj; Artur Michalak
Journal:  J Mol Model       Date:  2012-06-06       Impact factor: 1.810

2.  Dehydrogenation of ammonia borane through the third equivalent of hydrogen.

Authors:  Xingyue Zhang; Lisa Kam; Travis J Williams
Journal:  Dalton Trans       Date:  2016-05-04       Impact factor: 4.390

3.  Applications of the ETS-NOCV method in descriptions of chemical reactions.

Authors:  Mariusz Paweł Mitoraj; Monika Parafiniuk; Monika Srebro; Michał Handzlik; Agnieszka Buczek; Artur Michalak
Journal:  J Mol Model       Date:  2011-03-29       Impact factor: 1.810

4.  A robust, air-stable, reusable ruthenium catalyst for dehydrogenation of ammonia borane.

Authors:  Brian L Conley; Denver Guess; Travis J Williams
Journal:  J Am Chem Soc       Date:  2011-08-18       Impact factor: 15.419

5.  A Three-Stage Mechanistic Model for Ammonia Borane Dehydrogenation by Shvo's Catalyst.

Authors:  Zhiyao Lu; Brian L Conley; Travis J Williams
Journal:  Organometallics       Date:  2012-08-30       Impact factor: 3.876

6.  Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane.

Authors:  Hassan A Kalviri; Felix Gärtner; Gang Ye; Ilia Korobkov; R Tom Baker
Journal:  Chem Sci       Date:  2014-10-30       Impact factor: 9.825

7.  Molybdenum catalyzed ammonia borane dehydrogenation: oxidation state specific mechanisms.

Authors:  Joshua A Buss; Guy A Edouard; Christine Cheng; Jade Shi; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2014-07-30       Impact factor: 15.419
  7 in total

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