Literature DB >> 20574594

Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes.

Christine M Thomas1, J Wesley Napoline, Gerard T Rowe, Bruce M Foxman.   

Abstract

The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I(2) and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and eta(2)-coordination to Zr. Addition of H(2) leads to both oxidative addition across the M-M bond and P-N bond cleavage.

Entities:  

Year:  2010        PMID： 20574594     DOI： 10.1039/c0cc01272f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

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  6 in total

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