Excited-state reversible geminate recombination in two dimensions.

Excited-state reversible geminate recombination with two different lifetimes and quenching is investigated in two dimensions. From the exact Green function in the Laplace domain, analytic expressions of two-dimensional survival and binding probabilities are obtained at short and long times. We find that a new pattern of kinetic transition occurs in two dimensions. The long-time effective survival probabilities show a pattern of (ln t)(-1)-->constant-->e(t) depending on the rate constants while the effective binding probabilities show t(-1)(ln t)(-2)-->t(-1)-->e(t).